CSTA  Vol.8 No.1 , February 2019
Preparation, Crystal Structure and Spectroscopy Characterization of Vanadium(V) Complex, 2-Amino-4-Picolinium, 2-Methylimidazolium Decavanadate Hydrate (C4N2H7)4(C6N2H10)V10O28·2H2O
Abstract: A new decavanadate, (C4N2H7)4(C6N2H10)V10O28·2H2O, was synthesized by slow evaporation at room temperature and characterized by single crystal X-ray diffraction, IR and UV-Vis spectroscopies. The compound crystallizes in the triclinic system, P-1 space group with the cell parameters: a = 11.200(5) Å, b = 12.056(9) Å, c =20.511(7) Å, α = 73.40(4), β = 84.67(3), γ = 63.51(5), Z = 2 and volume V = 2373.7(1) Å3. The formula unit is composed of one decavanadate [V10O28]6- anion, four 2-methylimidazolium (C4N2H7)+ cations, one 2-amino-4-picolinium (C6N2H10)2+ cation and two water molecules. In the crystal, the layers of decavanadate groups, organic cations and water molecules stack up parallel to the (011) plane. The cohesion is provided by N-H···O, O-H···O hydrogen bonds and Van der Waals interactions leads to a three-dimensional structure. The absorbance spectrum measurement shows an optical band gap of 3.27 eV which allows us to conclude that this compound is a semiconductor material.
Cite this paper: Louati, M. , Ksiksi, R. , Jouffret, L. , Zid, M. (2019) Preparation, Crystal Structure and Spectroscopy Characterization of Vanadium(V) Complex, 2-Amino-4-Picolinium, 2-Methylimidazolium Decavanadate Hydrate (C4N2H7)4(C6N2H10)V10O28·2H2O. Crystal Structure Theory and Applications, 8, 1-11. doi: 10.4236/csta.2019.81001.

[1]   Bregeault, J.M., Vennat, M., Salles, L., Piquemal, J.Y., Mahha, Y., Briot, E., Bakala, P.C., Atlamsani, A. and Thouvenot, R. (2006) From Polyoxometalates to Polyoxoperoxometalates and Back Again; Potential Applications. Journal of Molecular Catalysis A, 250, 177-181.

[2]   Coronado, E. and Day, P. (2004) Magnetic Molecular Conductors. Chemical Reviews, 104, 5419-5448.

[3]   Huang, X., Li, J., Shen, G., Xin, N., Lin, Z., Chi, Y., Dou, J., Li, D. and Hu, C. (2017) Three Pd-Decavanadates with a Controllable Molar Ratio of Pd to Decavanadate and Their Heterogeneous Aerobic Oxidation of Benzylic C-H Bonds. Dalton Transactions, 47, 726-733.

[4]   Wang, C., Chen, Z., Yao, X., Chao, Y., Xun, S., Xiong, J., Fan, L., Zhu, W. and Li, H. (2018) Decavanadates Anchored into Micropores of Graphene-Like Boron Nitride: Efficient Heterogeneous Catalysts for Aerobic Oxidative Desulfurization. Fuel, 230, 104-112.

[5]   Aureliano, M. (2014) Decavanadate Contribution to Vanadium Biochemistry: In Vitro and in Vivo Studies. Inorganica Chimica Acta, 420, 4-7.

[6]   Aureliano, M. and Ohlin, C.A. (2014) Decavanadate in Vitro and in Vivo Effects: Facts and Opinions. Journal of Inorganic Biochemistry, 137, 123-130.

[7]   Galani, A., Tsitsias, V., Stellas, D., Psycharis, V., Raptopoulou, C.P. and Karaliota, A. (2015) Two Novel Compounds of Vanadium and Molybdenum with Carnitine Exhibiting Potential Pharmacological Use. Journal of Inorganic Biochemistry, 142, 109-117.

[8]   Trevino, S., Sánchez-Lara, E., Sarmiento-Ortega, V., Sánchez-Lombardo, I., Flores-Hernández, J., Pérez-Benítez, A., Brambila-Colombres, E. and González-Vergara, E. (2015) Hypoglycemic, Lipid-Lowering and Metabolic Regulation Activities of Metforminium Decavanadate (H2Metf)3[V10O28]·8H2O Using Hypercaloric-Induced Carbohydrate and Lipid Deregulation in Wistar Rats as Biological Model. Journal of Inorganic Biochemistry, 147, 85-92.

[9]   Choi, H., Chang, Y.Y., Kwon, Y.U. and Han, O.H. (2003) Incorporation of Decavanadate Ions into Silica Gels and Mesostructured Silica Walls. Chemistry of Materials, 15, 3261-3267.

[10]   Martín-Caballero, J., Wéry, A.S.J., Reinoso, S., Artetxe, B., Felices, L.S., Bakkali, B.E., Trautwein, G., Alcaniz-Monge, J., Vilas, J.L. and Gutiérrez-Zorrilla, J.M. (2016) A Robust Open Framework Formed by Decavanadate Clusters and Copper(II) Complexes of Macrocyclic Polyamines: Permanent Microporosity and Catalytic Oxidation of Cycloalkanes. Inorganic Chemistry, 55, 4970-4979.

[11]   Baruah, B., Roden, J.M., Sedgwick, M., Correa, N.M., Crans, D.C. and Levinger, N.E. (2006) When Is Water Not Water? Exploring Water Confined in Large Reverse Micelles Using a Highly Charged Inorganic Molecular Probe. Journal of the American Chemical Society, 128, 12758-12765.

[12]   Nomiya, K., Torii, H., Hasegawa, T., Nemoto, Y., Nomura, K., Hashino, K., Uchida, M., Kato, Y., Shimizu, K. and Oda, M. (2001) Insulin Mimetic Effect of a Tungstate Cluster. Effect of Oral Administration of Homo-Polyoxotungstates and Vanadium-Substituted Polyoxotungstates on Blood Glucose Level of STZ Mice. Journal of Inorganic Biochemistry, 86, 657-667.

[13]   Wang, M., Sun, W., Pang, H., Ma, H., Yu, J., Zhang, Z., Niu, Y. and Yin, M. (2016) Tuning the Microstructures of Decavanadate-Based Supramolecular Hybrids via Regularly Changing the Spacers of Bis(triazole) Ligands. Journal of Solid State Chemistry, 235, 175-182.

[14]   Ma, H., Meng, X., Sha, J., Pang, H. and Wu, L. (2011) Synthesis, Crystal Structure and Properties of a New Bi-Dentate Decavanadate [Cu(en)2H2O]2[H2V10O28]·12H2O. Solid State Sciences, 13, 850-854.

[15]   Li, S., Sun, W., Wang, K., Ma, H., Pang, H., Liu, H. and Zhang, J. (2014) Turn Helical Motifs from Pair to Single Entangled Double Helixes in a Cobalt-Vanadate System via Introduction of a V-Shaped Ligand. Inorganic Chemistry, 53, 4541-4547.

[16]   Klistincová, L., Rakovsky, E. and Schwendt, P. (2008) Decavanadate Ion as Bridging Ligand. Synthesis and Crystal Structure of (NH4)2[Cu2(NH3CH2CH2COO)4- (V10O28)]·10H2O. Inorganic Chemistry Communications, 11, 1140-1142.

[17]   Putrevu, N.R., Doedens, R.J. and Khan, M.I. (2013) Decavanadate with a Novel Coordination Complex: Synthesis and Characterization of (NH4)2[Ni(H2O)5(NH3)]2- (V10O28)·4H2O. Inorganic Chemistry Communications, 38, 5-7.

[18]   Chatkon, A., Barres, A., Samart, N., Boyle, S.E., Haller, K.J. and Crans, D.C. (2014) Guanylurea Metformium Double Salt of Decavanadate, (HGU+)4(HMet+)2(V10O286-)·2H2O. Inorganica Chimica Acta, 420, 85-95.

[19]   Truflandier, L.A., Boucher, F., Payen, C., Hajjar, R., Millot, Y., Bonhomme, C. and Steunon, N. (2010) DFT-NMR Investigation and 51V 3QMAS Experiments for Probing Surface OH Ligands and the Hydrogen-Bond Network in a Polyoxovanadate Cluster: The Case of Cs4[H2V10O28]·4H2O. Journal of the American Chemical Society, 132, 4653-4668.

[20]   Kodama, S., Taya, N. and Ishii, Y. (2014) A Novel Octanuclear Vanadium(V) Oxide Cluster Complex Having an Unprecedented Neutral V8O20 Core Functionalized with 4,4’-Di-tert-butyl-2,2’-bipyridine. Inorganic Chemistry, 53, 2754-2756.

[21]   Graia, M., Ksiksi, R. and Driss, A. (2009) Nonapiperidinium Monohydrogen Deca-Vanadate Tetra-Nitrate. Acta Crystallographica E, 65, m953-m954.

[22]   Rakovsky, E. and Krivosudsky, L. (2014) Tetrakis(2,6-di-methyl-pyridinium) Di- Hydrogen Deca-Vanadate Dehydrate. Acta Crystallographica E, 70, m225-m226.

[23]   Fernadez de Luis, R., Urtiaga, M.K., Mesa, J.L. and Arriortua, M.I. (2010) Tris[4,4’- (ethene-1,2-di-yl)dipyridinium] Deca-Vanadate Dehydrate. Acta Crystallographica E, 66, m323-m324.

[24]   Omri, I., Mhiri, T. and Graia, M. (2016) A New Monohydrogendecavanadate (V)-Dihydrogendecavanadate (V) with Dibutylammonium Cations [C8NH20]9- [H2V10O28][HV10O28].2.13H2O: Synthesis, Crystal Structure, Vibrational and Optical Properties. Journal of Molecular Structure, 1108, 334-340.

[25]   Sheldrick, G.M. (2008) A Short History of SHELX. Acta Crystallographica A, 64, 112-122.

[26]   Sheldrick, G.M. (2015) Crystal Structure Refinement with SHELXL. Acta Crystallographica C, 71, 3-8.

[27]   Brandenburg, K. (2001) DIAMOND Version 2.1e Crystal Impact GbR Bonn Germany.

[28]   Microcal Origin Version 8.0 (1991-2009). Microcal Software Inc. One, Northampton.

[29]   Momma, K. and Izumi, F. (2011) VESTA 3 for Three-Dimensional Visualization of Crystal, Volumetric and Morphology Data. Journal of Applied Crystallography, 44, 1272-1276.

[30]   Baur, W.H. (1974) The Geometry of Polyhedral Distortions. Predictive Relationships for the Phosphate Group. Acta Crystallographica B, 30, 1195-1215.

[31]   Brown, I.D. (1992) Chemical and Steric Constraints in Inorganic Solids. Acta Crystallographica B, 48, 553-572.

[32]   Bresse, N.E. and O’Keeffe, M. (1991) Bond-Valence Parameters for Solids. Acta Crystallographica B, 47, 192-197.

[33]   Siddiqi, Z.A., Sharma, P.K., Shahid, M., Kalid, M., Siddique, A. and Kumar, S. (2012) Novel Decavanadate Cluster Complexes [H2V10O28][LH]4·nH2O (L = Imidazole, n = 2 or 2-Methylimidazole, n = 0): Preparation, Characterization and Genotoxic Studies. Journal of Molecular Structure, 1029, 86-91.

[34]   Yan, J., Zhao, H., Li, Z., Xing, Y., Zeng, X., Ge, M. and Niu, S. (2009) A Self-Assembled 3D Hydrogen Bonded Network Constructed from Polyoxovanadate and Protonated Organic Substrate with a Solvent Hydrolysis Reaction. Journal of Cluster Science, 20, 717-724.

[35]   Brown, I.D. (1976) On the Geometry of O-H...O Hydrogen Bonds. Acta Crystallographica A, 32, 24-31.