JEP  Vol.2 No.10 , December 2011
Variability in Road Runoff Pollution by Polycyclic Aromatic Hydrocarbons (PAHs) in the Urbanized Area Adjacent to Biscayne Bay, Florida
ABSTRACT
Polycyclic aromatic hydrocarbons (PAHs) were consistently documented in the sediments of the canals draining into Biscayne Bay. The study examines the contribution of urban runoff to PAHs discharges. Subtropical climatic conditions associated with prolonged dry seasons often exacerbate the problem of PAHs pollution as the initial storms of the wet season wash off pollutants accumulated over time. Road runoff samples were collected at two sites with different levels of traffic at the end and at the beginning of the wet season. Storm-event mass first flush was found to occur inconsistently. Higher levels of PAH pollution were found at both sites after an extended dry season. The Kendall’s tau test used to measure the association between antecedent dry days and flow-weighted PAH concentrations was found to be statistically significant. The correlation between traffic intensity and PAHs levels in road runoff was found not to be statistically significant. High-molecular-weight PAHs originating in vehicle exhaust emissions appeared to dominate PAH concentrations in road runoff. The Friedman’s test showed overall similarity in PAHs composition profiles between seasons with the exception of low-molecular weight PAHs.

Cite this paper
nullD. Mitsova, J. Vos, P. Gardinali and I. Stafeychuk, "Variability in Road Runoff Pollution by Polycyclic Aromatic Hydrocarbons (PAHs) in the Urbanized Area Adjacent to Biscayne Bay, Florida," Journal of Environmental Protection, Vol. 2 No. 10, 2011, pp. 1317-1330. doi: 10.4236/jep.2011.210152.
References
[1]   I. D. Bossert and R. Bartha, “Structure-Biodegradability Relationships of Polycyclic Aromatic Hydrocarbons in Soil,” Bulletin of Environmental Contamination and Toxicology, Vol. 37, No. 1, 1986, pp. 490-495. doi:10.1007/BF01607793

[2]   M. Kayhanian and M. K. Stenstrom, “First-Flush Charac- terization for Stormwater Treatment,” Stormwater, 2008. http://www.stormh2o.com/march-april-2008/pollutants-run-off.aspx

[3]   L. H. Kim, M. Kayhanian, K.-D. Zoh and M. K. Stenstrom, “Modeling of Highway Stormwater Runoff,” Science of the Total Environment, Vol. 348, No. 1-3, 2005, pp. 1-18. doi:10.1016/j.scitotenv.2004.12.063

[4]   J. Soller, J. Stephenson, K. Olivieri, J. Downing and A. W. Olivieri, “Evaluation of the Seasonal Scale First Flush Pollutant Loading and Implications for Urban Runoff Ma- nagement,” Journal of Environmental Management, Vol. 76, 2005, pp. 309-318.

[5]   E. D. Stein, L. L. Toefenthaler and K. Schiff, “Watershed-Based Sources of Polycyclic Aromatic Hydrocarbons in Urban Stormwater,” Environmental Toxicology and Chemistry, Vol. 25, No. 2, 2006, pp. 373-385.

[6]   W. Zhang, S. Zhang, D. Yue, C. Wan, Y. Ye and X. Wang, “Characterization and Loading Estimation of Polycyclic Aromatic Hydrocarbons in Road Runoff from Urban Regions of Beijing, China,” Environmental Toxicology and Chemistry, Vol. 27, No. 1, pp. 31-37. doi:10.1897/07-030.1

[7]   C. M. Teaf, D. J. Covert and S. R. Kothur, “Urban Polycyclic Aromatic Hydrocarbons (PAHS): A Florida Perspective,” Proceedings of the Annual International Con- ference on Soils, Sediment, Water and Energy, Vol. 13, No. 1, 2008, Article 23.

[8]   D. J. McKenzie and G. A. Irwin, “Water-Quality Assessment of Stormwater Runoff from a Heavily Used Urban Highway Bridge in Miami, Florida,” USGS Water Resources Investigations 83-4153 (FHWA/FL/BMR-84- 270), 1983.

[9]   E. F. Corcoran, M. S. Brown, F. R. Baddour, S. A. Chasens and A. D. Freay, “Biscayne Bay Hydrocarbon Stu- dy,” NOAA Technical Memorandum NOS NCCOS 9, University of Miami RSMAS TR 2005-01, Coastal and Estuarine Data Archeology and Rescue Program, 1983.

[10]   K. H. Haag, R. L. Miller, L. A. Bradner and D. S. Mc- Culloch, “Water-Quality Assessment of Southern Florida: An Overview of Available Information on Surface and Ground-Water Quality and Ecology,” US Geological Survey, Water-Resources Investigations Report 96-4177, Tallahassee, 1996.

[11]   A. Y. Cantillo, G. G. Lauenstein and T. P O’Connor, “Mollusc and Sediment Contaminant Levels and Trends in South Florida Coastal Waters,” Marine Pollution Bulletin, Vol. 34, No. 7, 1997, pp. 511-521. doi:10.1016/S0025-326X(96)00152-X

[12]   V. G. Caccia and J. N. Boyer, “Spatial Patterning of Water Quality in Biscayne Bay, Florida as a Function of Land Use and Water Management,” Marine Pollution Bulletin, Vol. 50, No. 11, 2005, pp. 1416-1429. doi:10.1016/j.marpolbul.2005.08.002

[13]   T. L. Seal, F. D. Calder, G. M. Sloane, S. J. Schropp and H. L. Windom, “Florida Coastal Sediment Contaminants Atlas,” Florida Department of Environmental Protection, Tallahassee, 1994.

[14]   E. R. Long, G. Sloane, G. Scott, B. Thompson, R. S. Carr, J. Biedenbach, T. Wade, B. Presley, K. Scott, C. Mueller, G. Breken-Fols, B. Albrecht, J. W. Anderson and G. T. Chandler, “Magnitude and Extent of Chemical Contamination and Toxicity in Sediments of Biscayne Bay and Vicinity,” NOAA Technical Memorandum 141, 2000.

[15]   E. R. Long, M. J. Hameedi, G. M. Sloane and L. B. Read, “Chemical Contamination, Toxicity, and Benthic Community Indices in Sediments of the Lower Miami River and Adjoining Portions of Biscayne Bay, Florida,” Estuaries, Vol. 25, No. 4A, 2002, pp. 622-637. doi:10.1007/BF02804895

[16]   M. K. Stenstrom and M. Kayhanian, “First Flush Phenomenon Characterization,” CTSW-RT-05-73-02.6, Prepared for the California Department of Transportation Division of Environmental Analysis, 2005.

[17]   A. Krein and M. Schorer, “Road Runoff Pollution by Polycyclic Aromatic Hydrocarbons and Its Contribution to River Sediments,” Water Research, Vol. 34, No. 16, 2000, pp. 4110-4115.

[18]   E. J. Hoffman, G. L. Mills, J. S. Latimer and J. G. Quinn, “Urban Runoff as a Source of Polycyclic Aromatic Hydrocarbons to Coastal Waters,” Environmental Science and Technology, Vol. 18, No. 8, 1984, pp. 580-587. doi:10.1021/es00126a003

[19]   B. Ngabe, T. F. Bidleman and G. I. Scott, “Polycyclic Aromatic Hydrocarbons in Storm Runoff from Urban and coastal South Carolina,” The Science of the Total Environment, Vol. 255, No. 1-3, 2000, pp. 1-9. doi:10.1016/S0048-9697(00)00422-8

[20]   C. A. Menzie, S. S. Hoeppner, J. J. Cura, J. S. Freshman and E. N. LaFrey, “Urban and Suburban Storm Water Runoff as a Source of Polycyclic Aromatic Hydrocarbons (PAHs) to Massachusetts Estuarine and Coastal Environments,” Estuaries, Vol. 25, No. 2, 2002, pp. 165-176. doi:10.1007/BF02691305

[21]   H. M. Hwang and G. D. Foster, “Characterization of Polycyclic Aromatic Hydrocarbons in Urban Stormwater Runoff Flowing into the Tidal Anacostia River,” Environmental Pollution, Vol. 140, No. 3, 2006, pp. 416-426. doi:10.1016/j.envpol.2005.08.003

[22]   K. A. S. Pathiratne, O. C. P. de Silva, D. Hehemann, I. Atkinson and R. Wei, “Occurrence and Distribution of Polycyclic Aromatic Hydrocarbons (PAHs) in Bolgoda and Beira Lakes, Sri Lanka,” Bulletin of Environmental Contamination and Toxicology, Vol. 79, No. 2, 2007, pp. 135-140. doi:10.1007/s00128-007-9092-z

[23]   E. J. Hoffman, J. S. Latimer, C. D. Hunt, G. L. Mills and J. G. Quinn, “Stormwater Runoff from Highways,” Water, Air, and Soil Pollution, Vol. 25, No. 4, 1985, pp. 349- 364. doi:10.1007/BF00283788

[24]   E. Hong, E. A. Seagren and A. P. Davis, “Sustainable Oil and Grease Removal from Synthetic Stromwater Runoff Using Bench-Scale Bio-Retention Studies,” Water Environment Research, Vol. 78, No. 2, 2006, pp. 141-155. doi:10.2175/106143005X89607

[25]   J. J. Sansalone and S. G. Buchberger, “Partitioning and First Flush of Metals in Urban Roadway Stormwater,” Journal of Environmental Engineering, Vol. 123, No. 2, 1997, pp. 134-143. doi:10.1061/(ASCE)0733-9372(1997)123:2(134)

[26]   J.-L. Bertrand-Krajewski, G. Chebbo and A. Saget, “Distribution of Pollutant Mass vs Volume in Stormwater Discharges and the First Flush Phenomenon,” Water Research, Vol. 32, No. 8, 1998, pp. 2341-2356. doi:10.1016/S0043-1354(97)00420-X

[27]   A. Deletic, “The First Flush Load of Urban Surface Runoff,” Water Research, Vol. 32, No. 8, pp. 2462-2470. doi:10.1016/S0043-1354(97)00470-3

[28]   M. Kayhanian, A. Singh, C. Suverkropp and S. Borrum, “Impact of Annual Average Daily Traffic on Highway Pollutant Concentrations,” Journal of Environmental Engineering, Vol. 129, No. 11, 2003, pp. 975-990. doi:10.1061/(ASCE)0733-9372(2003)129:11(975)

[29]   J. H. Lee and K. W. Bang, “Characterization of Urban Stormwater Runoff,” Water Research, Vol. 34, No. 6, 2000, pp. 1773-1780. doi:10.1016/S0043-1354(99)00325-5

[30]   B. Suderman and N. H. Marcus, “The Effects of Orimulsion and Fuel Oil #6 on the Hatching Success of Copepod Resting Eggs in the Seabed of Tampa Bay, Florida,” Environmental Pollution, Vol. 120, No. 3, 2002, pp. 787- 795.

[31]   J. Obeysekera, J. Browder, L. Horning and M. A. Harwell, “The Natural South Florida System I: Climate, Geology, and Hydrology,” Urban Ecosystems, Vol. 3, No. 3-4, 1999, pp. 223-244. doi:10.1023/A:1009552500448

[32]   National Oceanic and Atmospheric Administration—Na- tional Weather Service (NOAA-NWS), “Duration of Sum- mer Season in South Florida,” Miami-South Florida Wea- ther Forecast Office, Miami, 2010. http://www.srh.noaa.gov/mfl/summer_season

[33]   Florida Department of Transportation FDOT, “Geographic Information System (GIS): GIS Shapefiles,” 2010. http://www.dot.state.fl.us/planning/statistics/gis/trafficdata.shtm

[34]   US Environmental Protection Agency (USEPA), “NPDES Storm Water Sampling Guidance Document,” EPA 833-8- 92-001, Office of Water, Washington DC, 1992.

[35]   J. H. Lee, S. L. Lau, M. Kayhanian and M. K. Stenstrom, “Seasonal First Flush Phenomenon of Urban Stormwater Discharges,” Water Research, Vol. 38, No. 19, 2004, pp. 4153-4163. doi:10.1016/j.watres.2004.07.012

[36]   P. Leftwich, D. Zierden and M. Griffin, “Monthly Climate Summaries for Florida,” Florida Climate Center, Office of the State Climatologist, Florida State University, Tallahassee, 2009-2011.

[37]   J. H. Lee, K. W. Bang, L. H. Ketchum, J. S. Choe and M. J. Yu, “First Flush Analysis of Urban Storm Runoff,” Science of the Total Environment, Vol. 293, No. 1-3, 2002, pp. 163-175. doi:10.1016/S0048-9697(02)00006-2

[38]   E. D. Stein, L. L. Tiefenthaler and K. C. Schiff, “Comparison of Stromwater Pollutant Loading by Land Use Type,” Southern California Coastal Water Research Project, AR08-015-027, 2008. http://www.sccwrp.org/Documents/AnnualReports/BrowseAllAnnualReports/2008AnnualReport.aspx.

[39]   M. K. Stenstrom, G. S. Silverman and T. A. Bursztynsky, “Oil and Grease in Urban Stormwaters,” ASCE Journal of the Environmental Engineering Division, Vol. 110, No. 1, 1984, pp. 58-72. doi:10.1061/(ASCE)0733-9372(1984)110:1(58)

[40]   S. Jonsson, Y. Persson, S. Frankki, B. van Bavel, S. Lundstedt, P. Haglund and M. Tysklind, “Degradation of Polycyclic Aromatic Hydrocarbons (PAHs) in Contaminated Soils by Fenton’s Reagent: A Multivariate Evaluation of the Importance of Soil Characteristics and PAH Properties,” Journal of Hazardous Materials, Vol. 149, No. 1, 2007, pp. 86-96.

 
 
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