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 AJPS  Vol.9 No.12 , November 2018
Ecofriendly Remediation of Pulp and Paper Industry Wastewater by Electrocoagulation and Its Application in Agriculture
Abstract: In the present study pulp and paper industry effluent was treated with the help of aluminum electrode using electrocoagulation (EC) process with feasible sludge management. The influences of pH, time, current density and electrolytes dose were investigated and optimum conditions were established to reduce the maximum amount of Chemical Oxygen Demand (COD) and color. At optimum conditions 70% of COD and 98% of color were removed. Additionally, the behavior of electrolytes (NaCl and Na2SO4) was determined; it has shown that Na2SO4 results in the generation of less secondary pollutants than that NaCl and thereby could be used as better replacement in paper industries for electrocoagulation mediated treatment of wastewater. The residual amount of operational parameters in EC treated water was compared to the World Health Organization (WHO) and Central Pollution Control Board (CPCB) of India. It was found to be safe for utilization in irrigation. Furthermore, sludge produced during the EC process has been analyzed for physicochemical characteristics. To understand the physical and elemental phases of sludge, the analytical technique such as field emission electron microscope coupled with energy dispersive spectroscopy has been used to find out the possible management alternative.
Cite this paper: Kumar, D. , Gaurav, V. and Sharma, C. (2018) Ecofriendly Remediation of Pulp and Paper Industry Wastewater by Electrocoagulation and Its Application in Agriculture. American Journal of Plant Sciences, 9, 2462-2479. doi: 10.4236/ajps.2018.912178.
References

[1]   Anushree, A., Kumar, S. and Sharma, C. (2016) Ce1-xCoxOy Nanocatalysts: Synthesis, Characterization and Environmental Application. Catalysis Science & Technology, 6, 2101-2111.

[2]   Pokhrel, D. and Viraraghavan, T. (2004) Treatment of Pulp and Paper Mill Wastewater—A Review. Science of the Total Environment, 333, 37-58.
https://doi.org/10.1016/j.scitotenv.2004.05.017

[3]   Peck, V. and Daley, R. (1994) Towards a “Greener” Pulp and Paper Industry. Environmental Science & Technology, 28, 524A-527A.

[4]   Karrasch, B., et al. (2006) Effects of Pulp and Paper Mill Effluents on the Microplankton and Microbial Self-Purification Capabilities of the Biobío River, Chile. Science of the Total Environment, 359, 194-208.
https://doi.org/10.1016/j.scitotenv.2005.03.029

[5]   Thompson, G., Swain, J., Kay, M. and Forster, C. (2001) The Treatment of Pulp and Paper Mill Effluent: A Review. Bioresource Technology, 77, 275-286.
https://doi.org/10.1016/S0960-8524(00)00060-2

[6]   Berryman, D., Houde, F., DeBlois, C. and O’Shea, M. (2004) Nonylphenolic Compounds in Drinking and Surface Waters Downstream of Treated Textile and Pulp and Paper Effluents: A Survey and Preliminary Assessment of Their Potential Effects on Public Health and Aquatic Life. Chemosphere, 56, 247-255.
https://doi.org/10.1016/j.chemosphere.2004.02.030

[7]   Simonic, M. and Vnucec, D. (2012) Coagulation and UF Treatment of Pulp and Paper Mill Wastewater in Comparison. Central European Journal of Chemistry, 10, 127-136.
https://doi.org/10.2478/s11532-011-0121-8

[8]   Mahesh, S., et al. (2016) Continuous Electrocoagulation Treatment of Pulp and Paper Mill Wastewater: Operating Cost and Sludge Study. RSC Advances, 6, 16223-16233.
https://doi.org/10.1039/C5RA27486A

[9]   Li, J., Hu, H., Song, Y. and Chai, X.-S. (2015) New Evidence for the Role of the Borohydride Pretreatment on the Hydrogen Peroxide Bleaching of Kraft Pulp. RSC Advances, 5, 98067-98074.
https://doi.org/10.1039/C5RA17964E

[10]   CPCB (2016) Final Document on Revised Classification of Industrial Sectors Central Pollution Control Board Delhi.

[11]   Sharma, J., Mishra, I.M., Dionysiou, D.D. and Kumar, V. (2015) Oxidative Removal of Bisphenol A by UV-C/Peroxymonosulfate (PMS): Kinetics, Influence of Co-Existing Chemicals and Degradation Pathway. Chemical Engineering Journal, 276, 193-204.
https://doi.org/10.1016/j.cej.2015.04.021

[12]   Ciputra, S., Antony, A., Phillips, R., Richardson, D. and Leslie, G. (2010) Comparison of Treatment Options for Removal of Recalcitrant Dissolved Organic Matter from Paper Mill Effluent. Chemosphere, 81, 86-91.
https://doi.org/10.1016/j.chemosphere.2010.06.060

[13]   Singh, R., Prakash, A. and Balagurumurthy, B. (2015) Hydrothermal Liquefaction of Agricultural and Forest Biomass Residue: Comparative Study. Journal of Material Cycles and Waste Management, 17, 442-452.
https://doi.org/10.1007/s10163-014-0277-3

[14]   Rana, R.S., Singh, P., Kandari, V., Singh, R., Dobhal, R. and Gupta, S. (2017) A Review on Characterization and Bioremediation of Pharmaceutical Industries’ Wastewater: An Indian Perspective. Applied Water Science, 7, 1-12.
https://doi.org/10.1007/s13201-014-0225-3

[15]   Rajni, S., Satish, K. and Chhaya, S. (2011) Tertiary Treatment Option for Pulp and Paper Mill Wastewater to Achieve Effluent Recycling Tertiary Treatment Option for Pulp and Paper Mill Wastewater to Achieve Effluent Recycling. IPPTA, 23, 155-159.

[16]   Sharma, R., Kumar, S. and Sharma, C. (2013) Influence of Operational Parameters on Electro Coagulation Process in Pulp and Paper Mill Effluent Treatment. Environmental Engineering and Management Journal, 13, 289-296.
https://doi.org/10.30638/eemj.2014.033

[17]   Ali, M. and Sreekrishnan, T.R. (2001) Aquatic Toxicity from Pulp and Paper Mill Effluents: A Review. Advances in Environmental Research, 5, 175-196.
https://doi.org/10.1016/S1093-0191(00)00055-1

[18]   Leiviskä, T., Nurmesniemi, H., Pöykiö, R., Rämö, J., Kuokkanen, T. and Pellinen, J. (2008) Effect of Biological Wastewater Treatment on the Molecular Weight Distribution of Soluble Organic Compounds and on the Reduction of BOD, COD and P in Pulp and Paper Mill Effluent. Water Research, 42, 3952-3960.
https://doi.org/10.1016/j.watres.2008.06.016

[19]   Chen, G. (2004) Electrochemical Technologies in Wastewater Treatment. Separation and Purification Technology, 38, 11-41.

[20]   Motoc, S., Manea, F., Pop, A., Pode, R. and Teodosiu, C. (2012) Electrochemical Degradation of Pharmaceutical Effluents on Carbon-Based Electrodes. Environmental Engineering and Management Journal, 11, 627-634.

[21]   Daneshvar, N., Oladegaragoze, A. and Djafarzadeh, N. (2006) Decolorization of Basic Dye Solutions by Electrocoagulation: An Investigation of the Effect of Operational Parameters. Journal of Hazardous Materials, 129, 116-122.
https://doi.org/10.1016/j.jhazmat.2005.08.033

[22]   Kobya, M., Can, O.T. and Bayramoglu, M. (2003) Treatment of Textile Wastewaters by Electrocoagulation Using Iron and Aluminum Electrodes. Journal of Hazardous Materials, 100, 163-178.
https://doi.org/10.1016/S0304-3894(03)00102-X

[23]   Zaleschi, L., Teodosiu, C., Cretescu, I. and Andres Rodrigo, M. (2012) A Comparative Study of Electrocoagulation and Chemical Coagulation Processes Applied for Wastewater Treatment. Environmental Engineering and Management Journal, 11, 1517-1525.

[24]   Garg, K.K. and Prasad, B. (2015) Electrochemical Treatment of Benzoic Acid (BA) from Aqueous Solution and Optimization of Parameters by Response Surface Methodology (RSM). Journal of the Taiwan Institute of Chemical Engineers, 56, 122-130.
https://doi.org/10.1016/j.jtice.2015.04.005

[25]   Bani-Melhem, K. and Smith, E. (2012) Grey Water Treatment by a Continuous Process of an Electrocoagulation Unit and a Submerged Membrane Bioreactor System. Chemical Engineering Journal, 198-199, 201-210.
https://doi.org/10.1016/j.cej.2012.05.065

[26]   Bas, D. and Boyaci, I.H. (2007) Modeling and Optimization I: Usability of Response Surface Methodology. Journal of Food Engineering, 78, 836-845.
https://doi.org/10.1016/j.jfoodeng.2005.11.024

[27]   Ghosh, D., Solanki, H. and Purkait, M.K. (2008) Removal of Fe(II) from Tap Water by Electrocoagulation Technique. Journal of Hazardous Materials, 155, 135-143.
https://doi.org/10.1016/j.jhazmat.2007.11.042

[28]   Mollah, M.Y.A., Morkovsky, P., Gomes, J.A.G., Kesmez, M., Parga, J. and Cocke, D.L. (2004) Fundamentals, Present and Future Perspectives of Electrocoagulation.

[29]   Ugurlua, M., Gürses, A., Dogar, Ç. and Yalçin, M. (2008) The Removal of Lignin and Phenol from Paper Mill Effluents by Electrocoagulation. Journal of Environmental Management, 87, 420-428.
https://doi.org/10.1016/j.jenvman.2007.01.007

[30]   El-Naas, M.H., Al-Zuhair, S., Al-Lobaney, A. and Makhlouf, S. (2009) Assessment of Electrocoagulation for the Treatment of Petroleum Refinery Wastewater. Journal of Environmental Management, 91, 180-185.
https://doi.org/10.1016/j.jenvman.2009.08.003

[31]   Faubert, P., Barnabé, S., Bouchard, S., Côté, R. and Villeneuve, C. (2016) Pulp and Paper Mill Sludge Management Practices: What Are the Challenges to Assess the Impacts on Greenhouse Gas Emissions? Resources, Conservation and Recycling, 108, 107-133.
https://doi.org/10.1016/j.resconrec.2016.01.007

[32]   Zodi, S., Potier, O. and Leclerc, J. (2009) Treatment of the Textile Wastewaters by Electrocoagulation: Effect of Operating Parameters on the Sludge Settling Characteristics. Separation and Purification Technology, 69, 29-36.
https://doi.org/10.1016/j.seppur.2009.06.028

[33]   Drouiche, N., Aoudj, S., Hecini, M., Ghaffour, N., Lounici, H. and Mameri, N. (2009) Study on the Treatment of Photovoltaic Wastewater Using Electrocoagulation: Fluoride Removal with Aluminium Electrodes—Characteristics of Products. Journal of Hazardous Materials, 169, 65-69.

[34]   Kim, D., et al. (2016) Characterization of Sludge Generated by Electrocoagulation for the Removal of Heavy Metals. Desalination and Water Treatment, 52.

[35]   APHA (1998) Standard Methods for the Examination of Water and Wastewater. 20th Edition, American Public Health Association, American Water Works Association and Water Environmental Federation, Washington DC.

[36]   Srivastava, S.P. and Srivastava, S.P. (2013) Solar Energy and Its Future Role in Indian Economy. International Journal of Environmental Science: Development and Monitoring, 4, 81-88.

[37]   Zhang, S., Zhang, J., Wang, W., Li, F. and Cheng, X. (2013) Solar Energy Materials & Solar Cells Removal of Phosphate from Landscape Water Using an Electrocoagulation Process Powered Directly by Photovoltaic Solar Modules. Solar Energy Materials and Solar Cells, 117, 73-80.
https://doi.org/10.1016/j.solmat.2013.05.027

[38]   Ortiz, J.M., Expósito, E., Gallud, F., García-García, V., Montiel, V. and Aldaz, A. (2006) Photovoltaic Electrodialysis System for Brackish Water Desalination: Modeling of Global Process. Journal of Membrane Science, 274, 138-149.
https://doi.org/10.1016/j.memsci.2005.08.006

[39]   Montiel, V., Aldaz, A., Valero, D., Ortiz, J.M. and Expo, E. (2008) Electrocoagulation of a Synthetic Textile Effluent Powered by Photovoltaic Energy without Batteries: Direct Connection Behaviour. Solar Energy Materials and Solar Cells, 92, 291-297.

[40]   Park, H., Hoffmann, M.R., et al. (2008) Solar-Powered Production of Molecular Hydrogen from Water Coupled with Organic Compound Oxidation. The Journal of Physical Chemistry C, 112, 885-889.

[41]   Al Suleimani, Z. and Nair, V.R. (2000) Desalination by Solar-Powered Reverse Osmosis in a Remote Area of the Sultanate of Oman. Applied Energy, 65, 367-380.
https://doi.org/10.1016/S0306-2619(99)00100-2

[42]   Valero, D., Ortiz, J.M., Exposito, E., Montiel, V. and Aldaz, A. (2010) Electrochemical Wastewater Treatment Directly Powered by Photovoltaic Panels: Electrooxidation of a Dye-Containing Wastewater. Environmental Science & Technology, 44, 5182-5187.

[43]   Mahesh, S., Prasad, B., Mall, I.D. and Mishra, I.M. (2006) Electrochemical Degradation of Pulp and Paper Mill Wastewater. Part 1. COD and Color Removal. Industrial & Engineering Chemistry Research, 45, 2830-2839.

[44]   Chen, X., Chen, G. and Yue, P.L. (2000) Separation of Pollutants from Restaurant Wastewater by Electrocoagulation. Separation and Purification Technology, 19, 65-76.
https://doi.org/10.1016/S1383-5866(99)00072-6

[45]   Do, J.-S. and Chen, M.-L. (1994) Decolourization of Dye-Containing Solutions by Electrocoagulation. Journal of Applied Electrochemistry, 24, 785-790.
https://doi.org/10.1007/BF00578095

[46]   Zaied, M. and Bellakhal, N. (2009) Electrocoagulation Treatment of Black Liquor from Paper Industry. Journal of Hazardous Materials, 163, 995-1000.

[47]   Vik, E.A., Carlson, D.A., Eikum, A.S. and Gjessing, E.T. (1984) Electrocoagulation of Potable Water. Water Research, 18, 1355-1360.
https://doi.org/10.1016/0043-1354(84)90003-4

[48]   Adhoum, N., Monser, L., Bellakhal, N. and Belgaied, J.-E. (2004) Treatment of Electroplating Wastewater Containing Cu2+, Zn2+ and Cr(VI) by Electrocoagulation. Journal of Hazardous Materials, 112, 207-213.
https://doi.org/10.1016/j.jhazmat.2004.04.018

[49]   Kapalka, A., Fóti, G. and Comninellis, C. (2010) Basic Principles of the Electro-Chemical Mineralization of Organic Pollutants for Wastewater Treatment. In: Comninellis, Christos and Chen, Eds., Electrochemistry for the Environment, Springer New York, New York, 1-23.

[50]   Khansorthong, S. and Hunsom, M. (2009) Remediation of Wastewater from Pulp and Paper Mill Industry by the Electrochemical Technique. Chemical Engineering Journal, 151, 228-234.
https://doi.org/10.1016/j.cej.2009.02.038

[51]   Sridhar, R., Sivakumar, V., Prince Immanuel, V. and Prakash Maran, J. (2011) Treatment of Pulp and Paper Industry Bleaching Effluent by Electrocoagulant Process. Journal of Hazardous Materials, 186, 1495-1502.
https://doi.org/10.1016/j.jhazmat.2010.12.028

[52]   Inan, H., Dimoglo, A., Simsek, H. and Karpuzcu, M. (2004) Olive Oil Mill Wastewater Treatment by Means of Electro-Coagulation. Separation and Purification Technology, 36, 23-31.
https://doi.org/10.1016/S1383-5866(03)00148-5

[53]   Marmanis, D., Dermentzis, K., Christoforidis, A., Ouzounis, K. and Moumtzakis, A. (2014) Electrochemical Treatment of Actual Dye House Effluents Using Electrocoagulation Process Directly Powered by Photovoltaic Energy. Desalination and Water Treatment, 56, 2988-2993.

[54]   Un, U.T., Topal, S. and Ates, F. (2017) Electrocoagulation of Tissue Paper Wastewater and an Evaluation of Sludge for Pyrolysis. Desalination and Water Treatment, 57, 28724-28733.

[55]   Kalyani, K.S.P., Balasubramanian, N. and Srinivasakannan, C. (2009) Decolorization and COD Reduction of Paper Industrial Effluent Using Electro-Coagulation. Chemical Engineering Journal, 151, 97-104.
https://doi.org/10.1016/j.cej.2009.01.050

[56]   Bockris, J.O., Conway, B.E., Yeager, E. and White, R.E. (1981) Comprehensive Treatise of Electrochemistry: Electrochemical Processing. Springer, Berlin.

[57]   Nassar, M.M., Fadaly, O.A. and Sedahmed, G.H. (1983) A New Electrochemical Technique for Bleaching Cellulose Pulp. Journal of Applied Electrochemistry, 13, 663-667.
https://doi.org/10.1007/BF00617824

[58]   Alverez-Gallegos, A. and Pletcher, D. (1999) The Removal of Low Level Organics via Hydrogen Peroxide Formed in a Reticulated Vitreous Carbon Cathode Cell. Part 2: The Removal of Phenols and Related Compounds from Aqueous Effluents. Electrochimica Acta, 44, 2483-2492.
https://doi.org/10.1016/S0013-4686(98)00371-5

[59]   Aboulhassan, M.A., Souabi, S. and Yaacoubi, A. (2008) Pollution Reduction and Biodegradability Index Improvement of Tannery Effluents. International Journal of Environmental Science and Technology, 5, 11-16.
https://doi.org/10.1007/BF03325992

[60]   Vigneswaran, S. and Sundaravadivel, M. (2004) Recycle and Reuse of Domestic Wastewater: Wastewater Recycle, Reuse, and Reclamation. Encyclopedia of Life Support Systems (EOLSS), Developed under the Auspices of the UNESCO, Eolss Publishers, Oxford.
http://www.eolss.net

[61]   Feldkirchner, D.C., Wang, C., Gower, S.T., Kruger, E.L. and Ferris, J. (2003) Effects of Nutrient and Paper Mill Biosolids Amendments on the Growth and Nutrient Status of Hardwood Forests. Forest Ecology and Management, 177, 95-116.
https://doi.org/10.1016/S0378-1127(02)00318-3

[62]   Abdullah, R., et al. (2015) Characterization and Feasibility Assessment of Recycled Paper Mill Sludges for Land Application in Relation to the Environment. International Journal of Environmental Research and Public Health, 12, 9314-9329.
https://doi.org/10.3390/ijerph120809314

[63]   Correia, A., et al. (2005) Municipal Wastewater Treatment with Anodizing Solid Waste. Desalination, 185, 341-350.

 
 
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