Ismailia is one of the most important Egyptian’s governorates where it represents the eastern gate to Asia and some Arab countries. The western part of Ismailia (the study area) is a desert land, except for the northern narrow green belt overlooking Ismailia Canal. Great efforts were made by the Egyptian governments and private sectors since the early 1960s to reclaim this desert land. Several agricultural and industrial projects have been accomplished, aiming to help overcome the problems of the high increase in population, unemployment and food deficiency in Egypt. The agricultural and industrial activities are expected to increase during the next years, and consequently, the need to ground water resources will increase.
The Quaternary aquifer in west Ismailia area is the main resource for ground water supply. Previous investigations, such as  -  indicated that the quality of the ground water in many parts of the aquifer is influenced by the executed reclamation activities, intensive pumping, and natural hydrogeochemical processes. Moreover, the ground water in the western part of the study area is the more vulnerable to contaminations with heavy metals due to the recharge by infiltration from liquid industrial and domestic wastes of the oxidation ponds found in the tenth of Ramadan City.
As the Quaternary aquifer represents the main aquifer in the studied area, a hydrologic re-evaluation for the aquifer should be made periodically. Rational management of the aquifer is necessary to meet increased agricultural, industrial and domestic demands. It requires good understanding of the various components of the aquifer hydrologic system.
Therefore, this paper presents more detailed knowledge about the ground water hydrology of the Quaternary aquifer in the study area. It describes the occurrence, flow and hydraulic gradient, recharge and discharge of ground water as well as the interaction with surface water streams. It presents an estimation of the hydraulic parameters (porosity, horizontal and vertical hydraulic conductivities, anisotropy and transmissivity) and sheds light on the characteristics of the aqueous environment of the aquifer. Findings of this work are very important to ascertain the best methods of the aquifer development. They are of great importance in case of conducting solute transport models and water budgets in the area.
2. Materials and Methods
2.1. Physiographic and Geologic Setting
The study area, west of Ismailia, is situated at the northern part of the Eastern Desert of Egypt, between latitudes 30.3˚ and 30.57˚N and longitudes 31.6˚ and 32.3˚E (Figure 1). It occupies an area of about 1150 km2. The area has a desert climate with hot summers and mild winters. The average annual temperature and precipitation are 21.3˚C and 26 mm  . The evaporation rate is high ranging from 6 mm/day to 12 mm/day  . The area is bounded from the north by Ismailia Canal, from east by the Suez Canal and Bitter Lakes, from the west by the 10th of Ramadan City and from the south by Cairo-Ismailia Desert Road.
Topographically, the area slopes northwards with altitudes ranging from 250 m above mean sea level (amsl) in the southern part of the area to 9 m (amsl) in the northern part. Its surface is subdivided into three geomorphologic units, the Belbies-El Tell El Kabeir-El Salhyia plains, Wadi El Tumilat depression, and Ankabia?Aweibid structural plain (Figure 2)    . A brief physiographic overview is presented hereinafter.
Belbies-El Tell El Kabeir-El Salhyia plains comprise the flats lying to the south of Ismailia Canal and extend to the Suez Canal. The surface is mainly covered by typical sands and gravels of Pleistocene age. Wadi El Tumilat depression is an E-W elongated depression extending parallel to Ismailia Canal with an average width and length reaching 7 km and 52 km, respectively. Its surface is covered by the Quaternary stabilized sand dunes. Ankabia-Aweibid structural plain is represented by a series of an E-W elongated structurally controlled ridges. The surface is covered by a variety of sediments (sand, gravel, sandstone and basaltic extrusions) belonging to the Tertiary age. The forelands of the structural ridges are dissected by a number of shallow and deep drainage lines that terminate northwards and eastwards.
Geologically, west Ismailia area is underlain by sedimentary rocks of Quaternary and Tertiary age (Figure 3). The Quaternary sediments underlie the northern and central parts of the study area. They are represented by the Holocene-aeolian sand and silt (~40 m thick) and the Pleistocene-sand and gravel with clay lenses (~352 m thick). They overlie unconformably the Miocene deposits in the north and south of Wadi El-Tumilat  .
The Tertiary sediments underlie the southern parts of the study area (south of the latitude 21˚00'N). The surface and subsurface stratigraphic succession of the Tertiary rock is investigated by many authors, such as      . The Pliocene rocks are represented by Hagif Formation formed of shallow marine limestone and marl (~190 m thick). The Miocene rocks are represented by Hagul Formation (~220 m thick) that is mostly composed of alternations of sandy limestone and clay layers. Such rocks are well exposed at the Tenth of Ramadan City and flat-lying areas in the southern mountain places. The Oligocene rocks are represented by Gebel Ahmer Formation (~260 m thick) formed of colored sands, quartz and gravels that are capped, in some places, by basaltic extrusion. The Eocene Rocks are represented by Maadi Formation and Mokatam Group, which are made of shallow marine shale and limestone intercalated with sands and clay layers (~430 m thick).
From the structure point of view, west Ismailia area falls within the unstable shelf dominating the northern part of Egypt  . The regional geologic structure
Figure 1. Location map of West Ismailia area, Egypt, showing the sampling points (production wells and main surface water bodies), source of maps is Google Earth, map data, 2017.
Figure 2. Geomorphologic map of west Ismailia area, Egypt (slightly modified after  ).
Figure 3. Geologic map of west Ismailia area, Egypt, after  .
is a low northward dipping homocline, which controls the thicknesses of some aquifers. For instance, the thickness of the Quaternary aquifer increases northwards by the rate 3 m/km  . The detected faults in the area are of normal type striking in an E-W, NW-SE and NE-SW directions. Faulting has a pronounced effect on the terrains and hydrogeology of the area.
2.2. Ground Water Measurements
Field campaign was achieved in west Ismailia area in January 2017 with the aim of collecting hydrologic data. Information about depths, diameters, and heads of 21 wells tapping the Quaternary aquifer were collected. The water levels inside these wells were measured, where possible, using a water level meter; model kurt, MIGGGE, Gm.b. H, 69 Heidelberg 1. The coordinates and elevations with respect to mean sea level of all water points were determined by a global positioning system device, eTrex, Personal Navigator.
Field measurements were made for ground water phsico-chemical parameters using Manta 2, Water-Quality Multiprobe, Model Sub 3, USA. They included ground water temperature, pH, total dissolved solid (TDS), specific conductance (SPC), dissolved oxygen (DO) and oxidation reduction potential (ORP). The same parameters were conducted also for three main surface water bodies (Ismailia Canal, El-Mahsama drain and El Manaief canal) in the area. The measured field ORP values for ground water and surface water samples were converted into redox potential (Eh) by adding the known half-cell potential of the reference electrode  :
For the used Manta 2 device, the actual ORP sensor is the 1 mm silver and the reference electrolyte is the KCl saturated with silver chloride. According to the temperature degrees measured for the water samples, the used half-cell potential values are 199 mV (at 25˚C) and 194 mV at (25˚C)  .
2.3. Grain Size Analysis for Estimating Aquifer Parameters
Drill cuttings (41 samples) representing different horizons of the Quaternary aquifer materials were obtained and analyzed for grain size using an analytical sieve shaker, model; Retch, D-42759, HAAN-Germany. The analyses were conducted at the Hydrogeological Lab., Egyptian Nuclear and Radiological Regulatory Authority. The aquifer material samples were tested using a series of sorted sieves ranging from 4 mm to 0.045 mm. An example showing the method of calculation of grain size parameters is presented in Table 1. The test results, comprising the grain size (in mm) and the percentage passing (%), were plotted on a semi-logarithmic graph to obtain the grain-size distribution curve for the sample as shown in Figure 4. From the distribution curve, the diameters of soil particles at 10% and 60% cumulative weight were determined, and then the coefficient of grain uniformity (u) was calculated.
The aquifer parameters were estimated based on the obtained grain size distribution data. The porosity of the aquifer was determined by applying the common equation presented by  . The hydraulic conductivity of each horizon (depth interval) was estimated using Kozeny equation  in  . The horizontal and vertical hydraulic conductivities (Kh and Kv) of the aquifer were estimated by applying the equations given by  , using the obtained Kozeny hydraulic conductivities and the thickness of the tested aquifer horizons. Anisotropy of the aquifer hydraulic conductivity was determined from the relation (Kh/Kv) given by  . The transmissivity of the aquifer was determined from the obtained vertical hydraulic conductivity and average aquifer thickness. Finally, recharge rate to the aquifer and specific discharge was determined using Darcy equation  .
3. Results and Discussion
3.1. The Quaternary Water Bearing Sediments
The Quaternary aquifer in the study area consists of unconsolidated fluviatile sediments (sands and gravels interbedded with clay lenses) (Figure 5). The lithofacies of the aquifer materials changes laterally and vertically. The content of gravels increases at the base of the aquifer. Intercalations of clay and calcareous materials are found to increase in the northeastern part of the study area. West of the longitude 32.1˚E, the area (about 2 - 7 km in width) overlooking
Figure 4. Grain size distribution curve, well No. 2, depth interval from 10 m to 18 m (below mean sea level).
Figure 5. Hydrogeological cross section A-A/cutting the study area in an NE-SW direction (direction of the cross section is shown in Figure 1).
Table 1. The results of particle size distribution test, well No. 2, depth interval from −10 m to −18 m below mean sea level.
Ismailia Canal is overlain by the semi permeable Holocene silty and sandy clay layer acting as an aquiclude, rendering the ground water under semi-confining conditions. In the rest of the area, the aquifer is overlain by sands and gravels, which render the ground water under un-confining conditions. The Quaternary aquifer unconformably overlies the Miocene aquifer formed essentially of alternation of calcareous sands and clays layers. The thickness of the aquifer increases northwards, averaging about 100 m   .
3.2. Aquifer Parameters
The Quaternary aquifer hydraulic parameters are estimated based on the analysis of the grain size distribution data of some continuous aquifer horizons (Table 2). They include the porosity (Φ), hydraulic conductivity obtained using Kozeny formula (Kkozeny), horizontal and vertical aquifer hydraulic conductivities (Kh and Kv), anisotropy (Kh/Kv), and transmissivity. Also included are the lithic descriptions of each tested horizon. The lithology of the aquifer is dominated by medium to coarse grained sand with few amounts of clay and gravel fractions.
3.2.1. Total Porosity
The total porosity (Φ) is the void space of the unconsolidated sedimentary materials and has a direct relation with the amount of water that can be stored in an aquifer. The (Φ) of the Quaternary aquifer is estimated by applying the following equation of  :
where the D10 and D60 are the grain sizes parameters corresponding to 10% and 60%, respectively, by weight passing (mm).
The results of grain size analysis (Table 2) show that all samples have medium uniformity coefficients values (2.5 < u < 10), which indicates that the samples are of medium uniform grain deposits. The porosity values of the studied aquifer horizons (from +10 m, msl, to −50 m, msl) range from 29% to 41%. These values reflect the nature of aquifer materials, which are dominated by sand fractions. Figure 6 shows the distribution of the average porosity in the Quaternary aquifer. The average porosity values (from 36% to 40.6%) are generally high and increase northwestwards. The increase in the porosity values could be attributed to the dominance fine grained sand and clay content. The high porosity values refer to the high storage capacity of the Quaternary aquifer.
3.2.2. Hydraulic Conductivity
The hydraulic conductivity (K) expresses the ease with which the ground water porous media. The K parameter of geologic units is essential for better ground water development, management and conservation. Knowing (K) is also required for modeling the movement of water in unsaturated and saturated zones and transportation of water soluble contaminants   .
Table 2. Porosity, hydraulic conductivity and anisotropy estimated for the Quaternary aquifer from grain size distribution data.
*Sd: sand f.: fine m.: medium c.: coarse v.c.: very coarse. gvl.: gravel u = uniformity coefficient Φ = porosity. Kh: horizontal hydraulic conductivity Kv: vertical hydraulic conductivity T: transmissivity.
Figure 6. Contour map showing the distribution of average porosity, the Quaternary aquifer, west Ismailia area, Egypt.
1) Kozeny-Hydraulic Conductivity (KKozeny)
In this work, the hydraulic conductivity (K) values of the aquifer horizons of each well were determined indirectly from grain size distribution by applying Kozeny equation  in  . Both the porosity function (Φ) and the effective size parameter (D10) are considered in the equation:
The hydraulic conductivity (KKozeny) estimated for each horizon varies greatly with depth. It ranges from 2.61 m/day (depth interval from 5 m to 0.0 m, msl, well 3) to 106.6 m/day (depth interval from −40 m to −50 m, msl, well no. 5) (Table 2). For each well, the average hydraulic conductivity of all horizons is calculated. The average K(Kozeny) varies between 18.70 m/day and 65.49 m/day, with an average value of about 46.86 m/day.
2) Effective Horizontal Hydraulic Conductivity (Kh)
The effective horizontal hydraulic conductivity (Kh) of the Quaternary was estimated using the following equations  :
where mi is thickness of the tested interval (i), Ki is the hydraulic conductivity of ith interval.
The calculated horizontal hydraulic conductivity (Kh) values are listed in Table 2 and their distribution through the Quaternary aquifer is shown in Figure 7. The Kh of the investigated aquifer varies between 18.71 m/day in well no.15 and 63.95 m/day in well no. 7 with an average value of about 46.6 m/day. It decreases due northeast with increasing the amount of fine grained clay and calcareous materials (see the cross section, Figure 4). The Kh positively correlates with the average porosity (r = 0.73). In other words, the increase in the porosity of the aquifer materials leads to increasing the horizontal hydraulic conductivity. To a great extent, there is a consistency between the distribution of both the Kh and Φ as shown in Figure 6 and Figure 7.
Figure 7. Contour map showing the distribution of the horizontal hydraulic conductivity of the Quaternary aquifer, west Ismailia area, Egypt.
3) Effective Vertical Hydraulic Conductivity (Kv)
The effective vertical hydraulic conductivity (Kv) of the Quaternary aquifer was determined by applying the following equation  :
The calculated vertical hydraulic conductivity (Kv) of the concerned aquifer ranges from 8.94 m/day in well no. 3 to 61.6 m/day in well no. 20 (Table 2), with an average value of about 35.98 m/day. The distribution of Kv values of the aquifer is shown in Figure 8. The maximum Kv values are recorded in the area located between the longitudes 31.8˚ and 32˚E, while the minimum values are recorded in the areas located due the west and east. The decrease in Kv values is most probably due to the presence of the sedimentary horizons formed of fine grained clay mixed with sand, especially in the northeastern part of the area.
3.2.3. Anisotropy (Kh/Kv)
Study of the anisotropy of an aquifer is of great importance to reveal the homogeneity of aquifer materials and sedimentlogical manner. Anisotropy of the Quaternary-aquifer hydraulic conductivity was determined by dividing Kh by Kv  :
Inspection in Table 2 reveals that the Kh values are generally higher than Kv ones, and this is imparted on the values of the anisotropy (Kh/Kv) of the aquifer hydraulic conductivity. The Kh/Kv values ranges from 1.01 to 4.27 (Table 2). For well nos. 3, 5 and 11, the particle size analysis yields anisotropies such that the Kh is typically about 3 to 4 times that of Kv. For the rest of wells a slight difference between Kh and Kv values is recorded. The anisotropy values decrease in the central part of the area and generally increase gradually eastwards and westwards (Figure 9).
Generally speaking, the recorded anisotropy values for the Quaternary aquifer are small. This is due to the absence of the bedding planes within the deposits of the aquifer and/or missing the smaller scale lithofacies such as very thin silt and clay beds having lower hydraulic conductivity values. The anisotropy values show that the Quaternary aquifer is heterogeneous and anisotropic.
3.2.4. Transmissivity (T)
Transmissivity (T) of an aquifer is important evidence about its productivity. The higher the transmissivity the more the ground water an aquifer can produce. The transmissivity of the Quaternary aquifer is estimated based on the average hydraulic conductivity values (Kkozeny) and the average saturated thickness (H) of the aquifer (100 m). The transmissivity is expressed by the following equation:
The T values of the investigated aquifer horizons range from 1870 m2/day (well no. 15) to 6549 m2/day (well no. 17) as shown in Table 2. The average T value of the aquifer reaches 4686 m2/day. According to  classification, the majority of the T values shows that the Quaternary aquifer is characterized by
Figure 8. Contour map showing the distribution of the vertical hydraulic conductivity of the Quaternary aquifer, west Ismailia area, Egypt.
Figure 9. Contour map showing the distribution of the anisotropy (Kh/Kv) of the Quaternary aquifer-hydraulic conductivity, west Ismailia area, Egypt.
high potential (T > 500 m2/day). The T values estimated based on the grain size analysis are, to some extent; in agree with those obtained from pumping tests  . Figure 10 shows the spatial distribution of T values in the Quaternary aquifer. The T generally decreases northeastwards due to the increase in clay and calcareous material content.
3.3. Depth to Water Level
Depths to water levels from ground surface in wells tapping the Quaternary aquifer are shown in Table 3. They vary greatly from site to another site according to the topographic elevations. They range from less than 5.0 m (shallow ground water) in the northern cultivated part of the area to about 70 m (deep ground water) in the southern desert area (Figure 11). The decrease in ground elevation is generally associated with a decrease in the depth to water level. Information dealing with depth to water map plays an important role in case of drilling new wells in new sites in the study area.
Figure 10. Contour map showing the distribution of the transmissivity (T) of the Quaternary aquifer, west Ismailia area, Egypt.
Figure 11. Contour map showing the depth to water level, the Quaternary aquifer, west Ismailia area.
Table 3. Coordinates, elevations and ground water level data, the Quaternary aquifer, west Ismailia area, Egypt.
*: Well tapping the Quaternary and Miocene aquifers.
3.4. Ground Water Flow
The ground water altitudes of the Quaternary aquifer (Table 3) are graraphically represented as a potentiometric surface contour map (Figure 12). All ground water levels measured for the aquifer are found above mean sea level. They range from less than 7.0 m at the northern part of the area to less than 15 m at the southeast.
The Quaternary aquifer is characterized by a multiple and divergent water flow paths that seems to be the product of the structural setting, heterogeneity and anisotropy. The ground water generally flows from the recharge areas to the discharge ones. The directions of flow lines refer to the recharge from the Miocene aquifer and occasional flash flood in the south and from Ismailia and El Manaief canals in the north and east. The ground water depressions (sites A and B in Figure 12) are the discharge areas. Site A (El Mahsama lake) is a natural discharge area for the groundwater, while site B is adown cone originated due to heavy pumping as has been observed during the field works.
The hydraulic gradient (I) as a factor controlling the ground water movement is calculated from the differences in hydraulic heads (dh) per unit length (dI) over the lengths of the flow paths. It is irregular and, generally, decreases westwards and increases eastward (Figure 12). The hydraulic gradient in the eastern part of the study area (east of the longitude 32.1˚E) is very steep, ranging from 0.001 to 0.0066 and average about 0.0034, while in the area between the longitudes 31.9˚ and 32.1˚E it is relatively steep ranging from 0.0004 to 0.00055 and average about 0.00438. In the western part (west of the longitude 31.9˚E), the hydraulic gradient is relatively flat, ranging from 0.00025 to 0.00020 with an average value of about 0.00022.
The flat and steep hydraulic gradients in the western and eastern parts of the study area could be attributed to the difference in discharge rates. The withdrawal from the aquifer in western area became very low in recent years because this area has been provided with freshwater from Ismailia canal through subsurface pipelines. And on the contrary of that, the need to the ground water in eastern area has been increased, and consequently a large number of discharging wells have been completed.
Figure 12. Contour map showing the potentiometric surface and ground water flow (Jan. 2017), the Quaternary aquifer, west Ismailia area, Egypt.
3.5. Recharge of the Quaternary Aquifer and Darcy Velocity
The potentiometric surface contour map (Figure 12) shows that the Quaternary aquifer is recharged from the area located at the south; indeed this is besides the recharge from the surface water canals in the north and northeast. Herein, the recharge from the southern area is considered, and it is estimated according to Darcy equation  :
where Q is the amount of recharge to the Quaternary aquifer (m3/day) calculated from Darcy law, K is the average horizontal hydraulic conductivity (46.6 m/day), L is the length of the front to recharge area (60 km), B is the average aquifer thickness (100 m) and I is the average hydraulic gradient (0.00438). Accordingly, the aquifer in the study area is recharged from the south by an amount of water that attains 1.22 × 106 m3/day (447 × 106 m3/year).
Darcy velocity, V (Darcy flux or specific discharge) of ground water of the Quaternary aquifer in the study area is estimated using the following Darcy’s equation:
The estimated Darcy’s velocity of the ground water in the Quaternary aquifer is 0.203 m/day, on average.
3.6. Change in the Hydrologic Setting
To examine the change in the hydrologic setting of the Quaternary aquifer in the study area during the period of 1992-2017, the water table contour maps constructed for the year 1992  (Figure 13), for the year 2005  (Figure 14) and for the year 2017 (the present work) are compared. The comparison process reveals that:
Figure 13. Water table contour map (Dec., 1992)  .
Figure 14. Water table contour map (Dec., 2005)  .
1) During the period of 1992-2005, a great change in the hydrology of ground water is occurred, where a great number of production wells have been completed in the northeastern part of the area. As a result of that the down cone area (B) is displaced towards the north.
2) In the year 1992, the flow of ground water was from the north (Ismailia Canal) and east to the west (site B in Figure 13), while in the year 2005 the ground water flow was from the north and south to the discharge area (site B in Figure 14).
3) From the period 2005 to 2017 years, there is no observed change in the hydrologic situation of the area, where the arrangement of water table contour lines and the place of the down cone area (site B) is nearly the same as shown in Figure 12 and Figure 14. During that period, Ismailia and El Manaief canal act as influent streams, i.e. they represent a recharge sources to the Quaternary aquifer.
3.7. Aqueous Environment of the Quaternary Aquifer
The phsico-chemical parameters that have been measured in situe for the ground water samples of the Quaternary aquifer and surface water samples of the main canals are listed in Table 4. They are described as follows:
3.7.1. Temperature and pH
Water temperature and pH affect many physical, chemical and biological properties of water systems  . The measured temperature of the ground water of the Quaternary aquifer does not vary considerably. They range between 25.33˚C and 28.36˚C, with an average value of about 26.69˚C. The surface water temperature (26.28˚C - 28.41˚C) has slightly influence on the ground water one, because most of the ground water is not shallow.
Table 4. Physico-chemical parameters of the Quaternary ground water and surface water samples, west Ismailia area, Egypt.
T: Temperature degrees DO: dissolved oxygen ORP: oxidation reduction potential. Eh: redox potential TDS: total dissolved solids Sp. Cond.: specific conductivity.
The Quaternary aquifer has pH values ranging from 5.28 to 7.41 standard units, showing that the ground water ranges from acid to slightly alkaline. No obvious trend as regard the distribution manner of the pH in the aquifer (Figure 15). However, in the eastern part of the area, the pH is found to increase north-eastwards to attain 6.96 (well no. 15), which is greatly similar to that of the El Manaief canal-recharge source (pH = 7.13 standard units). Furthermore, the occurrence of more acidic ground water in some places (well nos. 8, 14, 18 and 20) with pH less than 6 standard units may reflect: 1) the recharge from acidic surface water bodies, especially those found in the western industrial area, 2) release of hydrogen ions due to oxidation of pyrite mineral that usually found in the alluvial sediments, 3) escape of carbon dioxide to shallow groundwater, which forms carbonic acid that may dissociate into bicarbonate and hydrogen ions, and consequently decrease the pH of ground water, and 4) Infiltration of acidic precipitation to ground water, especially in the southern part of the area.
The Egyptian High Committee of Water  recommends a pH range from 6.5 to 8.5 standard units for public supply. About 29% of ground water samples are within this range. The rest of samples (71%) of the ground water samples are out of the recommended range where the measured pH values are less than 6.5 standard units.
3.7.2. Specific Conductance and Salinity
The specific conductance reflects the quantity of materials dissolved in water. The water of some wells (nos. 3, 13, 15, 17 and 20) and surface water of Ismailia and El Manaief canals in the investigated area are largely dilute water where the measured specific conductance values are less than1000 μS/cm (Table 4). This reflects low degree of chemical evolution. El Mahsama drain water has relatively higher specific conductance value (2647 μS/cm) than the fresh water canals. The rest of wells produce brackish to saline water, where the specific conductance values range from 2950 μS/cm to11530 μS/cm. This reflects the local variation in hydrogeologic characteristics and recharge sources. Generally, the specific conductance of ground water is typically one and half times the total dissolved solids, in mg/l.
Salinity (as total dissolved solids, TDS) of the Quaternary aquifer in the concerned area ranges from 322 mg/l (well no. 17) in the north to 7383 mg/l (well no. 14) in the south, and the average value is 2881 mg/l. There is a wide variation in the concentration of total dissolved solids in the aquifer as shown in Figure 16. Close to Ismailia and El Manaief canals, a stretcher of fresh water extends in the east-west direction. This may be due to increase in feeding velocity with fresh water from Ismailia and El Manaief canals having low salinity (271 < TDS < 285). The salinity increases gradually southwards to attain its maximum value (TDS > 7000 mg/l) close to Cairo-Ismailia Desert Road, which might be evidence of more evolved water due to the effect of hydrogeochemical processes and continuous recharge from the Miocene aquifer having high saline water  . The salinity distribution map (Figure 16) is with conformable with the potentiometric surface contour map (Figure 12) where the salinity decreases with decreasing the ground water level altitudes. The recommended maximum level of TDS value for public supply is 1000 mg/l  . Over 75% of ground water samples show TDS values exceeding the recommended level and the rest of samples show TDS values that are less than that level.
3.7.3. Dissolved Oxygen and Redox Potential
The solubility of oxygen in ground water is limited and directly related to the atmospheric pressure and inversely related to hydrostatic pressure  . The
Figure 15. Contour map showing the distribution of pH in standard units in the Quaternary aquifer, west Ismailia area, Egypt.
Figure 16. Contour map showing the distribution of total dissolved solids in m/l in the Quaternary aquifer, west Ismailia area, Egypt.
fresh surface water bodies (Ismailia and El Manaief canals) have higher dissolved oxygen (DO) than in the ground water, the average being 8.95 mg/l. Concentrations of DO in the Quaternary aquifer typically are between 2.13 mg/l (well no. 15) and 8.4 mg/l (well no. 17), with an average value of about 4.82 mg/l. The presence of DO in appreciable amounts (>1 mg/l) in ground water probably indicates the transportation of oxygen from the surface and unsaturated zones to the aquifer and/or the effect of microbial reduction of DO is limited  .
The distribution of the DO in the aquifer varies (Figure 17), and does not follow any pattern, which may reflect the recharge with different degrees from the fresh water canals. In some localized areas there are high content of DO, for instance well no. 17 in the north (see Figure 1) where the DO value attains 8.4 mg/l, which may indicate the significant recharge from surface water of Ismailia Canal. Also, the high concentration of DO (7.46 mg/l) recorded for well no. 9 in the south may indicate the recharge to the concerned aquifer from the occasional flash flood at the south. In conclusion, the high concentration of DO in the aquifer indicates the high velocity of water circulation.
Figure 17. Contour map showing the distribution of dissolved oxygen in mg/l in the Quaternary aquifer, west Ismailia area, Egypt.
Redox potential (Eh, in mV) is of great value for explaining how oxidations and reductions occurs in a water bearing formation. In the present work the Eh values are determined for the ground water samples based on the oxidation reduction potential measurements (ORP, in mV) (Table 4). The Eh values vary greatly with location, ranging from 185 mV (well no. 13) to 836 mV (well no. 17); the average is 406 mV. Figure 18 shows that there is a general increase in the Eh values towards the north in the area located between the longitudes of 32˚ and 32.1˚E, which is also the direction of DO increase. The Eh and DO are positively correlated (r = 0.53) (Figure 19(a)), suggesting that the geochemical controls on the Eh and DO parameters are to some extent similar. Moreover, there are no significant correlations between Eh and DO and the others physico-chemical parameters.
The ground water samples are plotted on the Eh-pH diagram  for aqueous environment (Figure 19(b)), which shows the reactions and products at electrochemical equilibrium. As shown in this diagram, the ground water samples are located in the region corresponding to oxidizing (alkaline) environment. The increase in Eh value, especially in the area of well no. 17 (Eh = 836 mV) suggests that the ground water of Quaternary aquifer system in this area is more oxidizing (more electron losses), and therefore, metal dissolution is favored.
The conclusions of this study are as follows:
1) The Quaternary aquifer, representing the main source of ground water in west Ismailia area, comprises heterogeneous and anisotropic section of fluviatile sand and gravel. The ground water is shallow at the north and deep at the south, and exists under semi-confined to unconfined conditions.
2) Analysis of grain size distribution reveals that the aquifer hydraulic parameters (total porosity, horizontal and vertical and hydraulic conductivities, anisotropy, and transmissivity) are high indicating the high productivity of the aquifer.
Figure 18. Contour map showing the distribution of redox potential in mV in the Quaternary aquifer, west Ismailia area, Egypt.
Figure 19. Relationships between the measured physicochemical parameter; (a) Eh-DO diagram and (b) Eh-pH diagram, the diagonal lines in (b) define the upper and lower stability limits for water at 25˚C and 1 bar of pressure.
Such parameters generally decrease eastwards as revealed from the spatial distribution maps.
3) Analysis of ground water altitudes indicates that the aquifer receives recharge from the fresh water canals due the north and northeast and from the Miocene aquifer and occasional flash flood due the south. The recharge rate from the southern area attains 1.22 × 106 m3/day.
4) The hydrologic situation of the aquifer changed during the last 25 years, as revealed from the comparison of potentiometric surface contour map prepared by the present work with those constructed for the years 1992 and 2005.
5) Results of physico-chemical analysis indicate the influence of recharge sources and geological conditions on the quality of aqueous environment of the aquifer. The salinity of ground water is high at the south (TDS = 7383 mg/l), and decreases gradually to attain its minimum value (TDS = 322 mg/l) at the north. The constructed pH-Eh diagram shows the oxidizing environment of the aquifer.
Conflicts of Interest
The authors declare no conflicts of interest regarding the publication of this paper.