IJOC  Vol.7 No.4 , December 2017
Direct Mass Spectroscopy Analysis and Comparison of Middle Eastern and Texas Crude Oils
Abstract: We analyzed two types of crude oil samples: Middle Eastern crude oil and Texas crude oil by using a residual gas analyzer (RGA) based on the linear quadrupole principle. This portable mass analyzer is capable of measuring hydrocarbons with masses of up to 300 atomic mass units (amu) as well as low mass targets, such as methane and carbon dioxide at ppm level concentrations. The generated mass spectra revealed differences in the composition and signal intensity of hydrocarbons of Middle Eastern and Texas crude oil samples. Even if RGA 300 is manufactured to be served as a detailed gas analysis of vacuum systems, we have shown that it is sensitively capable of detection of hydrocarbons and it enables one to qualitative and quantitative analysis of the composition of the crude oils.
Cite this paper: Kaya, G. , Kaya, N. , Amani, M. , Rahman, A. , Kolomenskii, A. and Schuessler, H. (2017) Direct Mass Spectroscopy Analysis and Comparison of Middle Eastern and Texas Crude Oils. International Journal of Organic Chemistry, 7, 312-318. doi: 10.4236/ijoc.2017.74025.

[1]   Shadravan, A. and Amani, M. (2012) HPHT 101-What Petroleum Engineers and Geoscientists Should Know about High Pressure High Temperature Wells Environment. Energy Science and Technology, 4, 36-60.

[2]   Cotter, R.J., Fancher, C. and Cornish, T.J. (1999) Miniaturized Time-of-Flight Mass Spectrometer for Peptide and Oligonucleotide Analysis. Journal of Mass Spectrometry, 34, 1368-1372.<1368::AID-JMS905>3.0.CO;2-S

[3]   Ouyang, Z., Wu, G., Song, Y., Li, H., Plass, W.R. and Cooks, R.G. (2004) Rectilinear Ion Trap: Concepts, Calculations, and Analytical Performance of a New Mass Analyzer. Analytical Chemistry, 76, 4595-4605.

[4]   Sinha, M.P. and Tomassian, A.D. (1991) Development of a Miniaturized, Light-Weight Magnetic Sector for a Field-Portable Mass Spectrograph. Review of Scientific Instruments, 62, 2618-2620.

[5]   Freidhoff, C.B., et al. (1999) Chemical Sensing Using Non-Optical Microelectromechanical Systems. Journal of Vacuum Science & Technology A, 17, 2300-2307.

[6]   Badman, E.R. and Cooks, R.G. (2000) Miniature Mass Analyzers. Journal of Mass Spectrometry, 35, 659-671.<659::AID-JMS5>3.0.CO;2-V

[7]   Brkic, B., France, N., Clare, A.T., Sutcliffe, C.J., Chalker, P.R. and Taylor, S. (2011) Development of Quadrupole Mass Spectrometers Using Rapid Prototyping Technology. Journal of the American Society for Mass Spectrometry, 20, 1359-1365.

[8]   Cheng, C.N., Lai, J.H., Huang, M.Z., Oung, J.N. and Shiea, J. (2012) Analysis of Polar Components in Crude Oil by Ambient Mass Spectrometry. In: El-Sayed Abdul-Raouf, M., Ed., Crude Oil Emulsions, Composition Stability and Characterization, InTech, 107-120.

[9]   Flego, C. and Zannoni, C. (2010) Direct Insertion Probe-Mass Spectrometry: A Useful Tool for Characterization of Asphaltenes. Energy & Fuels, 24, 6041-6053.

[10]   Hsu, C.S. and Green, M. (2001) Fragment-Free Accurate Mass Measurement of Complex Mixture Components by Gas Chromatography/Field Ionization-Orthogonal Acceleration Time-of-Flight Mass Spectrometry: An Unprecedented Capability for Mixture Analysis. Rapid Communications in Mass Spectrometry, 15, 236-239.<236::AID-RCM197>3.0.CO;2-B

[11]   Stanford, L.A., Kim, S., Klein, G.C., Smith, D.F., Rodgers, R.P. and Marshall, A.G. (2007) Identification of Water-Soluble Heavy Crude Oil Organic-Acids, Bases, and Neutrals by Electrospray Ionization and Field Desorption Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Environmental Science & Technology, 41, 2696-2702.

[12]   Snyder, A.P., McClennen, W.H., Dworzanski, J.P. and Meuzelaar, H.L.C. (1990) Characterization of Underivatized Lipid Biomarkers from Microorganisms with Pyrolysis Short-Column Gas Chromatography/Ion Trap Mass Spectrometry. Analytical Chemistry, 62, 2565-2573.

[13]   Robins, C. and Limbach, P.A. (2003) The Use of Nonpolar Matrices for Matrix-Assisted Laser Desorption/Ionization Mass Spectrometric Analysis of High Boiling Crude Oil Fractions. Rapid Communications in Mass Spectrometry, 17, 2839-2845.

[14]   Zhan, D. and Fenn, J.B. (2000) Electrospray Mass Spectrometry of Fossil Fuels. International Journal of Mass Spectrometry, 194, 197-208.

[15]   Purcell, J.M., Hendrickson, C.L., Rodgers, R.P. and Marshall, A.G. (2006) Atmospheric Pressure Photoionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry for Complex Mixture Analysis. Analytical Chemistry, 78, 5906-5912.

[16]   Brkic, B., France, N. and Taylor, S. (2011) Oil-in-Water Monitoring Using Membrane Inlet Mass Spectrometry. Analytical Chemistry, 83, 6230-6236.