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 NJGC  Vol.1 No.3 , October 2011
Compressive Strength and Electron Paramagnetic Resonance Studies on Waste Glass Admixtured Cement
Abstract: The present work reports the effect of waste glass (WG) on the properties of Portland cement through Electron Para- magnetic Resonance (EPR) study. Cement pastes containing 0, 10, and 30% replacement of waste glass with cement and in a water to cement ratio of 0.4 have been prepared. The g factors of Fe(III) and Mn(II) impurities at different hydration ages have been calculated. The decreased gFe values and simultaneous increase in gMn values with increase in replacement % of WG are explained due to retardation of cement hydration.
Cite this paper: nullR. Gopalakrishnan and D. Govindarajan, "Compressive Strength and Electron Paramagnetic Resonance Studies onWaste Glass Admixtured Cement," New Journal of Glass and Ceramics, Vol. 1 No. 3, 2011, pp. 119-124. doi: 10.4236/njgc.2011.13017.
References

[1]   L. P. Aldridge, “Accuracy and Precision of Phase Analysis in Portland Cement by Bogue, Microscopic and X-ray Dif-fraction Methods,’’ Cement Concrete Research, Vol. 12, 1982, pp. 381-398. doi:10.1016/0008-8846(82)90087-4

[2]   M. F. Rojas, “Study of Hydrated Phases Present in a MK-Lime System Cured at 60?C and 60 Months of Reac- tion,” Cement Concrete Research, Vol. 36, 2006, pp. 827-831. doi:10.1016/j.cemconres.2006.01.001

[3]   M. Oriol and J. Pera, “Pozzolanic Activity of Metakaolin Under Microwave Treatment,” Cement Concrete Research, Vol. 25, No. 2, 1995, pp. 265-270. doi:10.1016/0008-8846(95)00007-0

[4]   N. J. Coleman and W. R Mcwhinnie, “The Solid State Chemistry of Metakaolin Blended Ordinary Portland Ce- ment,” Journal of Materials Science, Vol. 35, 2000, pp. 2701-2710. doi:10.1023/A:1004753926277

[5]   C. A. Love, I. G. Richardson and A. R. Brough, “Compo-sition and Structure of C-S-H in White Portland Cement- 20% Metakaolin Pastes Hydrated at 25?C,” Cement Con- crete Reseasrch, Vol. 37, No. 2, 2007, pp. 109-117.

[6]   S. Barathan, D. Govindarajan, G. Sivakumar and K. Raghu, “Microwave Study of Hydration of Cement with Different Waters,” Indian Journal of Pure and Applied Physics, Vol. 44, 2006, pp. 334-338.

[7]   W. W. J. Chan and C. M. L. Wu, “Durability of Concrete with High Cement Replacement,” Cement Concrete Re- search, Vol. 30, No. 6, 2000, pp. 865-879. doi:10.1016/S0008-8846(00)00253-2

[8]   S. Goberis and V. Antonovich, “Influence of Sodium Silicate Amount on the Setting Time and Exo Temperature of a Complex Binder Consisting of High Alumina Cement, Liquid Glass and Metallurgical Slag,” Cement Concrete Research, Vol. 34, 2004, pp. 1939-1941. doi:10.1016/j.cemconres.2004.01.004

[9]   K. Sobolev, P. Turker, S. S. leva and G. Iscioglu, “Utili-zation of Waste Glass in Eco Cement: Strength Properties and Microstructural Observation,” Waste Management, Vol. 27, No. 7, 2007, pp. 971-976. doi:10.1016/j.wasman.2006.07.014

[10]   J. Mohamad Terro, “Properties of Concrete Made with Recycled Crushed Glass at Elevated Temperature,” Building and Environment, Vol. 41, No. 5, 2006, pp. 633-639. doi:10.1016/j.buildenv.2005.02.018

[11]   S. B. Park and B. C. Lee, “Studies on Expansion Proper-ties in Mortar Containing Waste Glass and Fibres,” Ce-ment Concrete Research, Vol. 34, No. 7, 2004, pp. 1145- 1152.

[12]   I. B. Topcu and M. Canbaz, “Properties Containing Waste Galss,” Cement Concrete Research, Vol. 34, No. 2, 2004, pp. 267-274. doi:10.1016/j.cemconres.2003.07.003

[13]   R. L Sharma and S. P. Pandey, “Influence of Mineral Additives on the Hydration Characteristics of Ordinary Portland Cement,” Cement Concrete Research, Vol. 29, No. 9, 1999, pp. 1525-1529. doi:10.1016/S0008-8846(99)00104-0

[14]   A. Bruckner, R. Luck, W. Wieker, A. Winkler, C. Andreae and H. Mehner, “Investigation of Redox Reactions Proceeding During the Hardening Process of Sulfide Containing Cement,” Cement Concrete Research, Vol. 22, 1992, pp. 1116-1169. doi:10.1016/0008-8846(92)90045-W

[15]   Jr. L. Lapcik and Z. Simek, “Electroparamagnetic Re-sonance Study of Dry Cements,” Cement Roncrete Re-search, Vol. 26, No. 2, 1996, pp. 237-242. doi:10.1016/0008-8846(95)00216-2

[16]   N. Voglis, G. Kakali, S. Chaniotaki and S. Tsivilis, “Portland-Limestone Cements: Their Properties and Hy-dration Compared to Those of Other Composite Cements,” Cement Concrete Research, Vol. 27, 2005, pp. 191-196. Hdoi:10.1016/j.cemconcomp.2004.02.006

[17]   M. S. Shetty, “Concrete Technology,” S. Chand and Co. Ltd., New Delhi, 2004.

[18]   A. J. Weil, R. J. Bolton and E. J. Wertz, “Electron Para-magnetic Resonance,” Elementary Theory and Practical Applications, John Wiley & Sons, New York, 1994.

[19]   P. S. Rao, “Single Crystal EPR Study of Fe(III) Doped Magnesium Potassium Tutton’s Salt. Part 3,” Spectro-chimica Acta A, Vol. 52, No. 9, 1996, pp. 1127-1134. doi:10.1016/0584-8539(95)01637-6

[20]   M. Y. A. Mollah, W. Yu, R. Schennach and D. L. Cocke, “A Fourier Transform Infrared Spectroscopic Investigation of the Early Hydration of Portland Cement and the Influence of Sodium Lignosulfonate,” Cement Concrete Research, Vol. 30, No. 2, 2000, pp. 267-273. doi:10.1016/S0008-8846(99)00243-4

[21]   P. S. Rao and S. Subramanian, “Single Crystal E.P.R Studies of Some First Row Transition Ions in Hex-AimiDazole Zinc(II) Dichloride Tetrahydrate,” Mo-lecular Ph- ysics, Vol. 54, No. 2, 1985, pp. 415-427. doi:10.1080/00268978500100321

 
 
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