Davidovits  proposed that an alkaline liquid could be used to react with silicon (Si) and aluminium (Al) in a source material of geological origin such as kaolinite, clays, etc., or byproduct materials such as fly-ash and rice husk ash to produce binders. As the chemical reaction that takes place in this case is polymerisation process, he coined the term “geopolymer” to represent these binders. The choice of source materials for making geopolymer depends on factors such as availability, cost, etc. Usually sodium or potassium-based solutions are used as alkaline liquids. There is abundant quantum of raw materials consisting of siliceous and argillaceous materials which have the potential of being utilised for the production of “geopolymer” masonry blocks. The “abundant” availability of raw materials, in this paper, refers to tank-bed-soil deposits, which can be seen in plentiful, especially in south India. Lime is another raw material which is abundantly available naturally. Another source of raw material for production of GP-based units is from debris of buildings, which contains huge quantity of bricks. The bricks from construction and demolition waste can potentially be used for production of GP-based units. Another significant reason for the present research is that the strength requirement for masonry block is not as much as that of, say, conventional concrete. Indeed, for low-rise masonry buildings (up to 4 storeys or thereabouts), unit strengths in the order of 5.0 to 10.0 MPa would suffice. The present study focuses on the issues related to energy and cost on production geopolymer adobes, an alternative to conventional masonry units. The choice of materials/process has been derived based on the basic requirements for masonry units and binders. The need for using locally available materials and a relatively easy process at low level of energy input has provided the motivation for the present work. The fact that many of the raw materials stated earlier are abundantly available is another reason to look at the production of geopolymer-lime-pozzolana-tank-bed-soil-brick-powder-based masonry products. Indeed, this approach is scantly researched. In the present research work, all the raw materials used were of geological origin and it was mixed with sodium-based alkaline solution, therefore the masonry adobes were name as geopolymer masonry units.
Embodied energy is the sum of all the energy required to produce a product i.e. total energy consumed to procure the raw materials, transport it, process it for the production of product, and manufacture the product. Quantification of embodied energy is usually done as a part of Life cycle Analysis (LCA). LCA involving embodied energy, operational energy and demolition energy is termed as “cradle-to-grave” analysis. On the other hand, the “cradle-to-gate” analysis is done to specify the embodied energy of building materials by aggregating all the energies up to the point of using them in a building. Table 1 provides the embodied energy of different building materials obtained by such analysis by various researchers.
The embodied energy for different building blocks has been presented in Table 2. Variation in embodied energy observed for masonry units with different structural system has been presented in Table 3. These values are especially
Table 1. Embodied energy of different building materials.
Table 2. Embodied energy of building blocks  .
Table 3. Variation in EE observed for masonry units with different structural system  .
relevant for the materials used in and around Bengaluru, India.
2. Present Study
In the present investigation, Geopolymer-based masonry units were cast and tested for various strength parameters. The dimensions of units were similar to the dimensions of table moulded bricks. The size of unit was 230 mm length, 105 mm breadth and 75 mm height with frog on one side. As per Bureau of Indian Standard specification IS1077-1992  , the minimum wet compressive strength of bricks shall not be less than be 3.5 MPa. The mix proportions for the production of masonry units were selected based on the strength parameters of cubes studied during the development of the product. The mix proportions of cubes which gave wet compressive strength greater than 3.5 MPa were selected for the production of masonry units. Tests were carried out on TBS-BP-L/LPC-based masonry in order to obtain the critical parameters required for design of masonry. They included 1) Compressive strength of masonry units, 2) Water absorption of masonry units, 3) Stress-strain characteristics of masonry units under compressive load, 4) Stress-strain behavior of stack-bonded masonry prisms under compressive load and 5) Shear bond strength of masonry triplets. The results indicated that they could be used as an alternative for conventional masonry.
The various raw materials used for casting masonry units and their mix proportions selected for unit production have been tabulated in Table 4. The concentration of the alkaline solution is also indicated.
A Brief Background on Lime Pozzolana Cement
According to IS 4098-1983  lime pozzolana mixture is manufactured by “inter-grinding class C hydrated lime and pozzolana such as calcined clay or fly ash or rice husk ash in suitable proportions in a ball mill or tube mill or by blending ingredients in the form of fine powder”. Further it states that “lime-pozzolana mixture which is essentially a mixture of lime and pozzolana could be used as an alternate cementing material to ordinary Portland cement for certain categories of work like masonry mortar and plaster, foundation concrete, levelling coarse under floors, road and airfield bases, precast building blocks (including light weight blocks), paving blocks, soil stabilization and as filler in water bound macadam in road construction”. Lime based mortars, Lime-sand, Lime-Flyash, Lime surkhi based mortars has equivalent or more strength than cement based mortars. The lime based mortars are known to possess better properties in both plastic and hardened state; they have 1) reduced heat of hydration and thermal shrinkage, 2) increased workability and water retention and 3) relatively better strength of finished surface.
However, these days lime based mortar is primarily used in restoration of historic masonry buildings. In rural areas, lime is still produced traditionally and used in construction on a small-scale.
The lime made from burning of lime stone possessing good quantity of calcium
Table 4. Details of raw materials and their mix proportions.
carbonate (CaCO3) in a kiln, is generally known as hydraulic lime. This has a very low shelf life and it readily reacts with water and/or atmospheric moisture, carbon-di-oxide (CO2) and renders itself unsuitable for binding applications. It would be useful if they are converted to a more stable form calcium hydroxide (Ca(OH)2) using the well-known process of slaking. As a binding agent, slaked lime is nowhere comparable to cement. However a value added stable compound is the lime-pozzolana cement. This is a combination of pozzolana blended with lime in a well-defined manner. Jagdish et al.  have carried out extensive studies on production and use of lime-pozzolana cement. They describe two methods of production. The first method is production of “Pre-mixed” lime pozzolana cement while the second method is the production of in-situ lime-pozzolana cement. While the former method makes use of intensive mechanical energy, the latter uses thermal energy. In the present study, however, LPC has been produced in the laboratory in a similar way as hydraulic cement is produced i.e. by calcination of lime and clay in a specially designed kiln. Calcium carbonate was dry mixed with high clay content soil in 1:1 proportion (Yoganand et al.)  . Later, required quantity of water was added and wet mixed in grinder for 30 minutes. Later the prepared mix was spread on a glass plate and briquettes were made from the wet paste. Later the briquettes were allowed to dry. After drying, these briquettes were burnt in kiln at a temperature of 600˚C to 900˚C for 3 to 4 hours. Figure 1 show the flow chart for LPC production and Figure 2 shows the process of LPC production. The physical characteristics of the produced LPC was quantified based on the tests specified in IS 4098-1983  . Table 5 gives the results and it can be noted that they conform to the requirements. The same has been used for production of TBS-BP-LPC based geopolymer bricks.
3. Production of Geopolymer Masonry Units
The preparation of solution, process of mixing, casting and curing have been done accordingly. The pictorial representation of production of masonry units have been given in Figure 2.
The average compressive strength of all these units was well above the minimum strength of 3.5 MPa prescribed by IS1905-1987  . The average water absorption values were well within the permissible limit of 20% as per IS1077-1992  . Thus, it can be concluded that all the masonry units were suitable for low-rise, load-bearing masonry applications practiced in India. It would be interesting to compare the compressive strength of these units with that of typical table moulded bricks (TMB) available in south India. The comparison is presented in Table 6.
4. Embodied Energy Computation
One of the approaches to assess the influence of the materials on environment is by carrying out life cycle energy assessment (LCA). The primary step in this process is to compute the embodied energy of the building products. There are a
Figure 1. Pictorial representation of LPC production process.
Figure 2. Pictorial representation of production of masonry units.
Table 5. Physical characteristics of LPC as per IS 4098-1983  .
Table 6. Compressive strength of GP masonry units compared with TMB.
number of factors that affect the embodied energy of building materials viz., availability and process of extraction of raw materials, geographic location, distance and mode of transportation to the processing site, type and efficiency of machinery used for processing and distance from which material is to be procured for construction. The method adopted for embodied energy calculation, validity and accuracy of the data compiled plays a crucial role in LCA. There could be “cradle-to-grave”, “cradle-to-site” or even “cradle-to-gate” type of EE assessment depending upon the requirement. In the present study the end product i.e. the geopolymer masonry units are made at site using the adobe process; hence the cradle-to-site analysis has been carried out.
For the purpose of computing embodied energy, the energy required for certain processes from the present study have been computed based on the fuel/electrical energy associated with the process. For some of the materials which have been procured, such as lime, alkaline solutions etc, the embodied energy from literature have been taken   . The energy expended from the manual efforts, such as sieving, mixing, placing in the mould etc, has not been considered.
Table 7 provides the description and calculation of the embodied energy of
Table 7. Embodied energy computation for production of TBS-BP-L/LPC geopolymer masonry units.
the ingredients of TBS-BP-L/LPC based geopolymer masonry units.
5. Results and Discussions
The Embodied energy of the four types of TBS-BP-L/LPC-based geopolymer masonry units of size 230 × 105 × 75 mm (i.e., the size of typical table-moulded bricks) has been presented in Table 8. The table also provides the cost comparison and their respective compressive strength.
It would be pertinent to look at the main contributors to EE and cost of each
Table 8. Comparative analysis for TBS-BP-L/LPC geopolymer masonry units and table moulded bricks.
unit. Table 3 shows the quantity of the ingredient materials used in each of the 4 types of masonry units. The EE and cost of each material is also provided. It has to be noted that the EE and cost of grinding has also been included. The comparison clearly reveals that table moulded brick has the least EE amongst the five types of masonry units. The embodied energy of GP masonry units made without lime or LPC was the minimum (4.74 MJ/unit) among the remaining four and this is marginally more than that of the EE of TMB.
The addition of lime or LPC has only increased the EE values. Expectedly, addition of the binders and alkaline solution has led to higher cost as well. However, the addition of these materials is not without any benefits. They have indeed contributed to the enhanced compressive strength. It would now be interesting to look at the EE benefits of TBS-BP-based GP units in terms of relative strength. The EE of each masonry unit is normalized with respect to its compressive strength and presented in Table 8. This comparison appears encouraging and clearly indicates that the blocks made by using LPC (8M and 2M) possess the least EE per unit compressive strength (0.37 MJ/MPa), which is nearly half of that of TMB.
Similarly, the cost of each masonry unit has been normalized with respect to its compressive strength. It can be observed thatTBS45-B45-LP10 (8M) bricks were comparable in cost to that of table-moulded bricks looked at from the units of cost per unit strength.
The graphical comparison of the EE of the four types of GP blocks is shown in Figure 3. Embodied energy and compressive strength comparison is shown in Figure 4. The comparison indicates that the bulk contributors are the alkaline materials, especially Na2SiO3. The major contributor for cost is also alkaline materials; again the bulk is from Na2SiO3. It can, hence, be concluded that any further improvements in the development of GP masonry units using TBS-BP should have to keep the issue of energy and cost contribution of NaOH and Na2SiO3. This is possible by using alkaline solutions at lower concentration and reduced NaOH: Na2SiO3 ratio. Perhaps using locally available ingredients which
Figure 3. Embodied energy contribution material breakup.
Figure 4. Comparison between embodied energy and cost of masonry units.
possess reactive silica may lead to dispensing with the use of Na2SiO3 and thus contribute to energy and cost benefits. Further studies are being undertaken in this direction.
6. Concluding Remarks
The followings are the highlights of embodied energy computations:
・ The embodied energy of GP masonry units made without lime or LPC was the minimum among the four, which was 4.74 MJ/unit. This EE (embodied energy) value is comparable to that of similar-sized, table-moulded bricks of south India; however, the strength of GP units was better than that of TMBs of south India. The EE values of the other GP units ranged from 5.06 to 6.5 MJ/unit.
・ The cost comparison trends were also along similar lines as that of EE. All the masonry units were significantly expensive when compared to the cost of similar-sized TMBs. Again, the major contributors were NaOH and Na2SiO3. It is evident that reducing molarity and ratio of NaOH:Na2SiO3 should to be the next steps in reaping the benefits of energy and cost.
・ In terms of relative strength, embodied energy of each type of masonry unit per unit compressive strength was favorable when compared to that of table-moulded bricks of south India.
・ It could be concluded that any further improvements in the development of GP masonry units using TBS-BP should keep the issue of energy and cost contribution of NaOH and Na2SiO3.
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