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 MSCE  Vol.5 No.4 , April 2017
Enhancement of Oxygen Evolution Activity of Ruddlesden-Popper-Type Strontium Ferrite by Stabilizing Fe4+
Abstract: Development of active iron based water oxidation for designing an ideal artificial photosynthesis devices operating under benign neutral pH is highly demanded. We investigated the electrocatalytic activity of Ruddlesden-Pop-per-type strontium ferrite (Sr3Fe2O7) toward the oxygen evolution reaction (OER). Owing to the temperature-dependent efficiency of the charge disproportionation of Fe4+, the OER activity of Sr3Fe2O7 varied with the temperature, and the onset potential for the OER at a neutral pH underwent a negative shift of approximately 200 mV by increasing the temperature for the stabilization of Fe4+. When metal substitution was made to Sr3Fe2O7 for stabilizing Fe4+ at room temperature, the temperature dependence of the OER activity disappeared and the OER was driven at a small overpotential without increasing the temperature, indicating that the stabilization of Fe4+ is substantially important for achieving high OER activity.
Cite this paper: Takashima, T. , Ishikawa, K. and Irie, H. (2017) Enhancement of Oxygen Evolution Activity of Ruddlesden-Popper-Type Strontium Ferrite by Stabilizing Fe4+. Journal of Materials Science and Chemical Engineering, 5, 45-55. doi: 10.4236/msce.2017.54005.
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