JWARP  Vol.9 No.5 , April 2017
Alleviation of Pesticide Residue in Surface Water
Abstract: Reduction of environmental pollution incurred from pesticide use is very important. Zeolite is a natural mineral capable of removing certain chemical contaminants from water. This study was carried out to test the effect of zeolite treatment on pesticide residue alleviation in surface water. Ten surface water samples were treated with natural zeolite by filtering through. An EPA method was used to extract pesticide residue from the water samples and the surfactant used to modify the net charge on the zeolite was hexadecyltrimethylammonium chloride (HDTMA-Cl). Gas chromatography-mass spectrometry was used to analyze water samples. Alleviation was achieved in all the 10 water samples that were filtered through zeolite. The highest removal of pesticides from water with zeolite included 100% of bifenthrin in sample CLC, atrazine in BPH, CDG and LBT; metolachlor in CLC, LBT, BCH, TRH2 and BPI; acetolachlor in BBH and BCH; azoxystrobin in BBH; desethylatrazine in BCH and BPI; metribuzin in BCH, TRH2 and BPI; and both clomazone and bromacil in sample BDC. A minimum reduction of 10.9% was found for metolachlor in sample BRH. Further reduction of pesticide residues up to 50% was recorded in the SMZ treatment as the concentrations of 4 out of 8 pesticide residues were reduced. This study confirms the potential of both the natural zeolite-Clinoptilolite, and SMZ of alleviating pesticide residues in water.
Cite this paper: Adeniyi, O. , Hernandez, A. , LeBlanc, M. , King, J. and Janes, M. (2017) Alleviation of Pesticide Residue in Surface Water. Journal of Water Resource and Protection, 9, 523-535. doi: 10.4236/jwarp.2017.95034.

[1]   Starner, K., Spurlock, F., Gill, S., Goh, K., Feng, H., Hsu, J., Lee, P., Tran, D. and White, J. (2005) Pesticide Residue in Surface Water from Irrigation-Season Monitoring in the San Joaquin Valley, California, USA. Bulletin of Environmental Contamination and Toxicology, 74, 920-927.

[2]   Laurie, B., Sauvage, S., Srinivasan, R., Leccia, O. and Sanchez-Perez, J.-M. (2014) Application Date as a Controlling Factor of Pesticide Transfers to Surface Water during Runoff Events. CATENA, 119, 97-103.

[3]   Lemic, J., Kovacevic, D., Tomasevic-Canovic, M., Kovacevic, D., Stanic, T. and Pfend, R. (2006) Removal of Atrazine, Lindane and Diazinone from Water by Organo-Zeolites. Water Research, 40, 1079-1085.

[4]   De Smedt, C., Ferrer, F., Leus, K. and Spanoghe, P. (2015) Removal of Pesticides from Aqueous Solutions by Adsorption on Zeolites as Solid Adsorbents. Adsorption Science & Technology, 33, 457-485.

[5]   Li, H., Sheng, G., Teppen, B.J., Johnston, C.T. and Boyd, S.A. (2003) Sorption and Desorption of Pesticides by Clay Minerals and Humic Acid-Clay Complexes. Soil Science Society of America Journal, 67, 122-131.

[6]   Boussahel, R., Bouland, S., Moussaoui, K.M. and Montiel, A. (2000) Removal of Pesticide Residues in Water Using the Nanofiltration Process. Desalination, 132, 205-209.

[7]   Ogata, F., Tominaga, H., Yabutani, H. and Kawasaki, N. (2011) Removal of Estrogens from Water Using Activated Carbon and Ozone. Journal of Oleo Science, 60, 609-611.

[8]   Tarasevich, Y.I. and Polyakov, V.E. (1995) Demanganation of Artesian Waters Using Modified Clinoptilolite. Natural Zeolites, Sofia’95, 65-67.

[9]   Welte, B., Montiel, A. and Dupas, S. (1996) Evolution de la concentration en pesticides dans deux filteres de traiterment d’eau de surface. Source Resources, 3, 28-32.

[10]   Colella, C. (1996) Ion Exchange Equilibria in Zeolita Minerals. Mineralium Deposita, 31, 554-562.

[11]   Pansini, M. (1996) Natural Zeolites as Cation Exchangers for Environmental Protection. Mineralium Deposita, 31, 563-575.

[12]   Ibrahim, K.M. and Akashah, T. (2004) Lead Removal from Wastewater Using Faujasite Tuff. Environmental Geology, 46, 865-870.

[13]   Li, Z., Roy, S.J., Zou, Y. and Bowman, R.S. (1998) Long-Term Chemical and Biological Stability of Surfactant-Modified Zeolite. Environmental Science and Technology, 32, 628-2632.

[14]   Krishna, B.S., Murty, D.S.R. and Jai Prakash, B.S. (2001) Surfactant-Modified Clay as Adsorbent for Chromate. Applied Clay Science, 20, 65-71.

[15]   Campos, V., Morais, L.C. and Buchler, P.M. (2007) Removal of Chromate from Aqueous Solution Using Treated Natural Zeolite. Environmental Geology, 52, 1521-1525.

[16]   Bowman, R.S., Haggerty, G.M., Huddleston, R.G., Neel, D. and Flynn, M.M. (1995) Surfactant-Enhanced Subsurface Remediation. ACS Symposium Series 594, American Chemical Society, Washington, DC, 54-64. In: Campos, V., Morais, L.C. and Buchler, P.M., Eds., Removal of Chromate from Aqueous Solution Using Treated Natural Zeolite, Environmental Geology, 52, 1521-1525.

[17]   Adeniyi, O., Hernandez, A., LeBlanc, M., King, J. and Janes, M. (2016) Quantitation of Pesticide Residue in Water and Food in Louisiana, USA. Journal of Water Resource and Protection, 8, 1145-1157.

[18]   Bowman, R. (2005) Surfactant-Altered Zeolites as Permeable Barriers for the in-Situ Treatment of Contaminated Groundwater. New Mexico Tech Technical Report 0522, 46 p.

[19]   Lemic, J., Tomasevic-Canovic, M., Adamovic, M., Kovacevic, D. and Milicevic, S. (2007) Competitive Adsorption of Polycyclic Aromatic Hydrocarbons on Organo-Zeolites. Microporous and Mesoporous Materials, 105, 317-323.

[20]   Karmen, M., Logar, N.Z., Sijeg, M. and Farkas, A. (2013) Chapter 5 Natural Zeolites in Water Treatment—How Effective Is Their Use. In: Elshorbagy, W. and Kabir Chowdhury, R., Eds., Water Treatment, INTECH.

[21]   Moussavia, G., Talebi, S., Farrokhi, M. and Sabouti, R.M. (2011) The Investigation of Mechanism, Kinetic and Isotherm of Ammonia and Humic Acid Co-Adsorption onto Natural Zeolite. Chemical Engineering Journal, 171, 1159-1169.

[22]   Mumpton, F.A. (1999) La roca magica: Uses of Natural Zeolites in Agriculture and Industry. Proceedings of the National Academy of Sciences of the United States of America, 96, 3463-3470.

[23]   Sullivan, E.J., Carey, J.W. and Bowman, R.S. (1998) Thermodynamics of Cationic Surfactant Sorption onto Natural Clinoptilolite. Journal of Colloid and Interface Science, 206, 369-380.

[24]   Bowman, R.S. (2003) Applications of Surfactant-Modified Zeolites to Environmental Remediation. Microporous and Mesoporous Materials, 61, 43-56.

[25]   Inglezakis, V.J., Doula, M.K., Aggelatou, V. and Zorpas, A.A. (2010) Removal of Iron and Manganese from Underground Water by Use of Natural Minerals in Batch Mode Treatment. Desalination and Water Treatment, 18, 341-346.

[26]   Curkovic, L., Cerjan-Stefanovic, S. and Filipan, T. (1997) Metal Ion Exchange by Natural and Modified Zeolites. Water Research, 31, 1379-1382.