1. Introduction

This product of the dissolution of organic matter and trace elements (heavy metals, organic pollutants and chemicals, radionuclides...) is a source of pollution of soil and water, including groundwater. Among the inorganic compounds found in raw leachate are the heavy metals that attract attention because of their potential toxicity. Although these substances are generally present at low concentrations in the leachate (with the exception of iron and manganese), some can be dangerous if they infiltrate at a source of drinking water. The microbiological contamination, parasitological, biological and physicochemical water from groundwater poses real public health problem [3] [4] [5] .

2. Milieu Materials and Methods Study

2.1. Study Milieu

The samples were taken 23 wells, three wells (P21, P22, P23) are located inside the discharge, three other are adjacent to the discharge (P15, P16 and P17) and the remainder wells (P1, P2, ..., P20) distributed in the study area of M’nasra region. These samples are filled into plastic bottles and then sent to the laboratory ORMVAG, Kenitra. To better exploit the data collected, we have divided them into three groups according wells the distance that separates them from the source:

Ÿ Group 1 where the wells are within the discharge is composed of the wells 21; 22 and 23.

Ÿ Group 2 consists of moderately distant from the discharge shaft (15; 16 et 17).

Ÿ Group 3 includes the remaining wells often further.

2.2. Materials and Methods Study

3. Results and Discussion

3.1. Potential Hydrogen

The distribution of the potentials of hydrogen according to the distances which separates the relief wells also shows a highly significant difference (Fisher = 7.41; p < 0.001). The mean of the classification by the Tukey test, these three groups shows that the wells in the discharge have a slightly basic pH (pH = 7.83), followed by the other wells which are either at an average distance or far from the source with a pH of 7.43 and 7 respectively, 39. In addition, the three groups were very uniform in having a very low coefficient of variation ranging from 0.33% to 0.74% (Figure 1).

For the irrigation water, usually the recommended pH is between 6.5 and 8.5 [6] because a low pH promotes the growth of filamentous fungi and other responsible bodies floating sludge [7] . The measured pH values are acceptable according to Moroccan standards of the quality of groundwater and which are generally between 5.5 and 8.5 (Ministry of Environment, 2002).

3.2. Electrical Conductivity (EC)

To locate the status of wells in the three groups, we proposed to establish a variance analysis to a single dimension effect “distance”. The results of this analysis show a highly significant difference (p < 0.000) between the mean of the conductivity of the groups studied. The comparison of averages Tukey identified three non-overlapping groups. Group 1 comprise the wells in full discharge with a conductivity of up to 3.34 ms/cm, group 2 close to the landfill with an average conductivity of 1.42 ± 0.073 and end wells located at a significant distance from the source and which are characterized by low conductivity values (0.68 ± 0.021). The evolution of the average conductivity in wells of group 1 were very homogeneous (CV = 0.00%) opposite wells of the groups 2 and 3 show, respectively, significant variation coefficient of 35% and 43% (Figure 2).

However, groundwater discharge show high mineralization of about 3.33 ms/cm. This pollution occurs through two mechanisms: direct contamination which occurs at the discharge career and due by Contact leachate with the tablecloth that goes back to the bottom of quarries; indirect contamination due to infiltration and percolation of leachate through the soil and the unsaturated in general permeable area. It is favored by the shallow depth of the water table (4 m). This pollution is then spread in the same direction as that of the flow of the web to achieve the wells located in the vicinity of the landfill site. This explains the high conductivity values stored at the nearest well. These results agree with those obtained by El-Kharmouz [8] and greater than those found by [9] . Many factors could influence the local conductivity of water such as the amount of mineral or organic matter in suspension, the physicochemical quality of urban, agricultural or industrial discharges and evaporation phenomen. The determined average value is greater than 2.7 ms/cm, considered direct discharge limit value. Therefore, water well in the group 1 are unfit for irrigation and those of groups 2 and 3 correspond somehow to national standards. So we can classify these waters in the grid of underground water of very poor quality > 3000 ms/cm to 25˚C.

3.3. Salinity

The results in showed that the distance between the wells in the discharge is a classification criterion, the difference is therefore very highly significant (Fisher = 781.52, p < 0.000). Three categories were deduced by the Tukey test. Indeed, a first category represented by the distant wells of the discharge (mean = 0.436 g/l), followed by Group 2 (mean = 0.907 g/l) and finally the category of wells in the landfill (wells 21, 22 and 23) with a concentration of 2.13 g/l. high dispersion was pronounced in groups 2 and 3 respectively, with coefficients of variation of 39.12% and 51.57% (Figure 3).

3.4. Hardness: Calcium (Ca²⁺) + (Mg²⁺) (Mineral Matter)

The results of the analysis of variance shows that the factor “distance” in a very highly significant (Fisher = 247.720; p < 0.000). Therefore, the comparison of average class sinks into three distinct categories. The first category consists of the further well (group 3) and having registered moderately lower concentrations. The second category includes the well in the group 2 (sufficient distance greater than that of group 1) with an average of 183.04 ± 8.92 mg/l and a group variation of 33.75%. However, the group of wells located in the heart of the landfill is isolated from the other groups, while mean values with significant Ca²⁺ + Mg²⁺ (mean = 249.12 ± 8.2 mg/ml).

Furthermore, the recorded concentrations well above those set as appropriate limits, by the Moroccan authorities. These values indicate that the waters especially the first two groups are assumed to be very hard (Figure 4). The total hardness of water is produced by calcium and magnesium salts contained therein. This parameter has a large variation which is linked to the lithology of the aquifer and in particular to the composition of magnesium and calcium. Rock formations containing divalent metals (Mg²⁺, Ca²⁺, ...) are responsible for the hardness.

3.5. Calcium (Ca²⁺) (Mineral Matter)

The graphical representation of the Ca²⁺ content per well revealed a large dispersion among them. This variation is of the order of 43.9% is approved by an

analysis of variance one-dimensional “effect well” who was very highly significant (Fisher = 71.53; p < 0.000). The lowest content (38.40 mg/l) is recorded in the well 19 and a maximum concentration of 237.60 mg/l is displayed in the 15 wells.

A highly significant difference was marked between the averages of the three groups, and their classification did retain two non-overlapping categories. The first category consists only of group 3 whose average grade is low (Mean = 92.62 mg/l), the second category includes the Group 1 and 2 which display relatively high concentrations (168.48 and 163.30). The group variation exceeds 28%, this explains many nonseasonal stability Ca²⁺.

Possible negative correlation was marked between the distance between the well source and also of the Ca²⁺ content. From Figure 5, these values often exceed accepted standards for water consumption for group 1 and group 2. This shows a pollution of groundwater by calcium probably from the discharge through the leachate.

3.6. Magnesium (Mg²⁺) (Mineral)

This variation is much more visible, while collecting this to the distance between the wells in the discharge Ouled Berjal. Nevertheless, analysis of variance, followed by the test shows Tukey plain good discrimination intra and inter group. Three categories (Fisher = 17446.02; p < 0.000), therefore, have been described.

The first category is composed of the said further shaft and which are characterized by a concentration of 9.14 ± 4.79. The second category includes the well in the group 2 and which are characterized by an average concentration of 19.74 mg/l. The last category includes the well having a relatively high average 80.4 ± 4.22 mg/l, 95% of the observations are grouped around this average value (CV = 5.23%) (Figure 6).

Figure 6 the higher magnesium concentration is observed in the discharge with an average of 80.64 mg/L which exceeds the standard Moroccan what set at 50 mg/l (Ministry of Environment, 2002), this implies a change in the mineralization of the waste. The analysis showed an average concentration of well water is of the order of 11. 26 mg/l with a minimum of 1. 91 mg/l and a maximum of 26.4 mg/l.

3.7. Sodium (Na⁺) (Mineral Matter)

Analysis of variance single factor “distance effect” gives a fairly high value of Fisher (F = 3215.85). The effect therefore of the distance between the borings is very highly significant (p < 0.000). The comparison of averages has classified these groups into three distinct categories. The first category is characterized by very low average concentrations (=58.83 ± 2.49 mg/l) and the third category for the further shaft is marked this time by very high levels (=949.67 ± 19.72 mg/l). Wells groups 2 and 3 have identified a wide variation intra category respectively resulted in coefficients of variation of 74.52% and 60.85% (Figure 7).

3.8. Potassium (K⁺) (Mineral Matter)

Analysis of variance shows that the distance between them to have a major effect on the potassium content. The comparison of means by the Tukey resortir test has three non-overlapping categories. The first category includes wells that are far from the discharge (mean = 5.23 mg/l) and the third category contains wells that displayed contents K⁺ very high (mean = 33.30) (Figure 8).

3.9. Ammonium ()

Analysis of variance single factor “distance effect” shows that the distribution of

the average grade has a highly significant difference (Fisher = 358.31, p < 0.000). Furthermore, the average comparison enabled to distinguish two classes, first class is composed of one well in the group that recorded an average of 5.01 ± 0.078 and a second class bringing together well in groups 2 and 3. A high dispersion is marked in the latter two groups (CV = 28.64%, CV = 32.14) (Figure 9).

3.10. Chloride (Cl⁻)

The results of the analysis of variance show that the distance separating the discharge shaft has a major effect on the distribution of the chlorine content (Fisher = 4321.74; p 0.000). This dispersion was possible to classify the wells into three groups. Indeed, the well of the first group showed concentrations ranging 609 mg/l and 820 mg/l and those in the third group; they fluctuate between 35.5 mg/l and 161.4 mg/l (Figure 10).

3.11. Nitrate ()

ANOVA confirmed the highly significant effect of the position of the wells on the distribution of concentrations. The average comparison revealed 14 distinct groups; the latter group is made up of wells that displayed high levels of (Figure 11).

Analysis of variance “distance effect” shows a highly significant difference. Perfect discrimination was reported, resulting in three non-overlapping groups, maximum values were recorded in group 1, group 2 and then followed a third group where wells are not too loaded ion.

3.12. Bicarbonate ()

Analysis of variance for a single classification factor shows that the position of the well has a highly significant effect on the distribution of concentrations of bicarbonate (Fisher = 1539.37; p < 0.000), and the distance between these wells to landfill (Fisher = 394.26; p < 0.000) (Figure 12). However, the comparison of means was possible to classify the wells in order of increasing bicarbonate concentration, so the closest are most likely to be contaminated with bicarbonates.

3.13. Sulphate ()

The ANOVAI shows that the distance to a highly significant effect on the dispersion of the concentrations determined on the relevant wells. Moreover, the

comparison of means gave three non-overlapping categories, further were less sensitive to concentrations of ().

The distribution contents () as a function of the monthly variation shows no significant differences (F = 0.01; p = 1), but the observations have fluctuated between a minimum value of 12.86 mg/l and a maximum value of 600.38 mg/l (Figure 13).

4. Conclusion

The study of parameters indicative of contamination from leachate generated by the discharge of Ouled Berjal allowed us to identify a mineral water contamination of the water table. Indeed, it is the water collected from wells 21, 22 and 23, located right in the landfill and in the flow direction of the web which are the most vulnerable to contamination mineral, organic, and inorganic things.