MSA  Vol.2 No.8 , August 2011
Electronic States in Trans-CoCl2(H2O)4 Complex
ABSTRACT
The polarized absorption spectra of cobalt(II) in trans-CoCl2(H2O)4.2H2O provides important information about the electronic structure. Semi-empirical calculation of the crystal-field levels of the cobalt(II) with D4h point group symmetry in CoCl2(H2O)4.2H2O are carried out, leading to a good agreement between the theoretical and experimental energy levels.

Cite this paper
nullH. Souissi and S. kammoun, "Electronic States in Trans-CoCl2(H2O)4 Complex," Materials Sciences and Applications, Vol. 2 No. 8, 2011, pp. 1121-1126. doi: 10.4236/msa.2011.28151.
References
[1]   C. Reber, “Absorption and Luminescence Spectroscopy of Transition Metal Compounds: from Coordination Geome-tries to Exited-State Properties.” Canadian Journal of Ana-lytical Sciences and Spectroscopy, Vol. 53, 2008, pp. 91-101.

[2]   E. González, A. Rodrigue-Witchel and C. Reber, “Absorp-tion Spectroscopy of Octahedral Nickel(II) Complexes: A Case Study of Interactions between Multiple Electronic Ex-cited States,” Coordination Chemistry Reviews, Vol. 251, 2007, p. 351. doi:org/10.1016/j.ccr.2006.08.011

[3]   R. Beaulac and C. Reber, “Spectroscopic Effects of Ex-cited-State Coupling in a Tetragonal Chromonium (III) Complex,” Inorganic Chemistry, Vol. 47, No. 12, 2008, pp. 5048-5054. doi:org/10.1021/ic702281k

[4]   G. Bussière, C. Reber, D. Neuhauser, D. A. Walter and J. I. Zink, “Molecular Properties Obtained by Analysis of Elec-tronic Spectra Containing Interference Dips. Comparisons of Analytical Equations and Exact Models Based on Cou-pled Potential Energy Surfaces,” Journal of Physics Chem-istry A, Vol. 107, 2003, pp. 1258-1265. doi:org/10.1021/jp0218490

[5]   P. L. W. Tregenna-Pigott, S. P. Best, H. U. Gudel, H. Weihe and C. C. Wilson, “Influence of the Mode of Water Coordination on the Electronic Structure of the [V(OH2)6]3+ Cation,” Journal of Solid State Chemistry, Vol. 145, 1999, p. 460. doi:org/10.1006/jssc.1999.8154

[6]   R. Meier, M. Boddin, S. Mitzenheim, V. Schmid and T. Schonherr, “Elucidation of V(III) Complex Coordination Numbers by Electronic Spectra,” Journal of Inorganic Biochemistry, Vol. 69, No. 4, 1998, pp. 249-252. doi:org/10.1016/S0162-0134(97)10031-9

[7]   T. Schonherr, V. Schmid and R. Meier, “Study on Coordi-nation Numbers Six and Seven in V(III) Complexes with Aquo, Cyanide and Aminopolycarboxylic Ligands by Means of the Angular Overlap Model,” Spectrochimica Acta Part A, Vol. 54, No. 11, 1998, pp. 1659-1669. doi:org/10.1016/S1386-1425(98)00094-8

[8]   G. Bussière, R. Beaulac, B. Cardinal-David and C. Reber, “Interacting Electronic States in Trans-MCl2(H2O)4n+ Com-plexes (M: V3+, Cr3+, Ni2+, Co2+),” Coordination Chemistry Reviews, Vol. 219-221, 2001, pp. 509-543.

[9]   S. Kammoun, M. Dammak, R. Maalej and M. Kamoun, “Crystal-Field Analysis for d8 ions at D4h Symmetry Sites: Electronic States in Trans-NiCl2(H2O)4 Complex,” Journal of Luminescence, Vol. 124, No. 2, 2007, pp. 316-320. doi:org/10.1016/j.jlumin.2006.04.006

[10]   S. Kammoun, M. Dammak, R. Maalej, M. Kamoun. “Elec-tronic States of Vanadium(III) in Trans-VCl2(H2O)4+ Chromophore,” Journal of Alloys and Compounds, Vol. 453, No. 1-2, 2008, pp. 64-68. doi:org/10.1016/j.jallcom.2006.11.180

[11]   H. Souissi and S. Kammoun, “Theoretical Studyoftheelec-Tronicstructureofa Tetragonal chromium(III)complex,” Journal of Luminescence, Vol. 131, No. 12, 2011, pp. 2515-2520. http://dx.doi:org/10.1016/j.jlumin.2011.05.044

[12]   G. Bussière, C. Reber, “Coupled Excited States in Nickel(II) Complexes Probed by Polarized Absorption Spectroscopy,” Journal of American Chemistry Society, Vol, 120, No. 25, 1998, pp. 6306. doi:org/10.1021/ja9740733

[13]   M. A. Hitchman, R. G. McDonald, P. W. Smith and R. Stranger, “Electronic Spectrum and Metal-Ligand Bonding Parameters of the V(H2O)63+ Ion,” Journal of Chemistry Socience Dalton Transition, 1988, pp. 1393-1395. doi:org/10.1039/dt9880001393

[14]   R. C. Powell, “Physics of Solid-State Laser Materials,” Springer-Verlag, New York, 1998.

[15]   D. J. Newman and B. Ng, “Crystal Field Handbook,” Cam-bridge University Press, Cambridge, 2000.

[16]   S. Sugano, Y. Tanabe and H. Kamimura, “Multiplets of Transition-Metal Ions in Crystals,” Academic Press, New York, 1970.

[17]   F. A. Cotton, C. A. Murillo and X. Wang, “Linear Tricobalt Compounds with Di-(2-pyridyl)amide (dpa) Ligands: stud-ies of the paramagnetic Compound Co3(dpa)4Cl2 in Solu-tion,” Inorganic Chemistry, Vol. 38, 1999, pp. 6294-6297. doi:org/10.1021/ic990944t

 
 
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