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 OALibJ  Vol.2 No.3 , March 2015
Preparation and Characterization of Copper Oxide Nanoparticles Synthesized via Chemical Precipitation Method
Abstract: Copper oxide nanoparticles (CuO-NPs) were synthesized via chemical precipitation method using copper (II) chloride dihydrate and sodium hydroxide. Then nanoparticles were characterized by using X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), Energy Dispersive X-ray (EDX), and Fourier Transform Infra Red (FTIR) spectroscopy. The XRD patterns and EDX spectra showed that the prepared CuO-NPs were highly pure, crystalline and nano-sized. The SEM image suggested that nano particles were spherical and there was a tendency of agglomerations. The nanoparticles showed interactions between copper and oxygen atoms supported by FTIR studies.
Cite this paper: Luna, I. , Hilary, L. , Chowdhury, A. , Gafur, M. , Khan, N. and Khan, R. (2015) Preparation and Characterization of Copper Oxide Nanoparticles Synthesized via Chemical Precipitation Method. Open Access Library Journal, 2, 1-8. doi: 10.4236/oalib.1101409.
References

[1]   Khan, R.A., Beck, S., Dussault, D., Salmieri, S., Bouchard, J. and Lacroix, M. (2013) Mechanical and Barrier Properties of Nanocrystalline Cellulose Reinforced Poly(caprolactone) Composites: Effect of Gamma Radiation. Journal of Applied Polymer Science, 129, 3038-3046.
http://dx.doi.org/10.1002/app.38896

[2]   Ahamed, M., Alhadlaq, H.A., Khan, M., Karuppiah, P. and Al-Dhabi, N.A. (2014) Synthesis, Characterization, and Antimicrobial Activity of Copper Oxide Nanoparticles. Journal of Nanomaterials, 3, 33-42.
http://dx.doi.org/10.1155/2014/637858

[3]   Mustafa, G., Tahir, H., Sultan, M. and Akhtar, N. (2013) Synthesis and Characterization of Cupric Oxide (CuO) Nanoparticles and Their Application for the Removal of Dyes. African Journal of Biotechnology, 12, 6650-6662.

[4]   Kida, T., Oka, T., Nagano, M., Ishiwata, Y. and Zheng, X.G. (2007) Synthesis and Application of Stable Copper Oxide Nanoparticle Suspensions for Nanoparticulate Film Fabrication. Journal of the American Ceramic Society, 90, 107-112.
http://dx.doi.org/10.1111/j.1551-2916.2006.01402.x

[5]   Kim, Y.S., Hwang, I.S., Kim, S.J., Lee, C.Y. and Lee, J.H. (2008) CuO Nanowire Gas Sensors for Air Quality Control in Automotive Cabin. Journal of Sensors and Actuators B: Chemical, 135, 298-303.
http://dx.doi.org/10.1016/j.snb.2008.08.026

[6]   Anandan, S. and Yang, S. (2007) Emergent Methods to Synthesize and Characterize Semiconductor CuO Nanoparticles with Various Morphologies—An Overview. Journal of Experimental Nanoscience, 2, 23-56.
http://dx.doi.org/10.1080/17458080601094421

[7]   Zhang, W., Guo, F., Wang, F., Zhao, N., Liu, L. and Li, J. (2014) Synthesis of Quinazolines via CuO Nanoparticles Catalyzed Aerobic Oxidative Coupling of Aromatic Alcohols and Amidines. Journal of Organic and Biomolecular Chemistry, 12, 5752-5766.
http://dx.doi.org/10.1039/C4OB00569D

[8]   Suleiman, M., Mousa, M., Hussein, A., Hammouti, B., Hadda, T.B. and Warad, I. (2013) Copper (II)-Oxide Nanostructures: Synthesis, Characterizations and Their Applications—Review. Journal of Materials and Environmental Science, 5, 792-807.

[9]   Manimaran, R., Palaniradja, K., Alagumurthi, N., Sendhilnathan, S. and Hussain, J. (2014) Preparation and Characterization of Copper Oxide Nanofluid for Heat Transfer Applications. Applied Nanoscience, 4, 163-167.
http://dx.doi.org/10.1007/s13204-012-0184-7

[10]   Albadi, J., Mansournezhad, A. and Abbaszadeh, H. (2013) CuO-CeO2 Nanocomposite: A Highly Efficient Recyclable Catalyst for the Green Synthesis of 1, 8-Dioxooctahydroxanthenes in Water. Journal of the Chinese Chemical Society, 60, 1193-1206.

[11]   Zhou, Z., Lu, C., Wu, X. and Zhang, X. (2013) Cellulose Nanocrystals as a Novel Support for CuO Nanoparticles Catalysts: Facile Synthesis and Their Application to 4-Nitrophenol Reduction. RSC Advances, 3, 26066-26073.
http://dx.doi.org/10.1039/c3ra43006e

[12]   Joshua, J.P., Krishnan, S., Raj, D., Uthrakumar, R., Laxmi, S. and Das, S.J. (2014) Novel Synthesis of Tenorite (CuO) Nanoparticles by Wet Chemical Method. International Journal of ChemTech Research, 6, 22-33.

[13]   Volanti, D., Keyson, D., Cavalcante, L., Simoes, A., Joya, M. and Longo, E. (2008) Synthesis and Characterization of CuO Flower-Nanostructure Processing by a Domestic Hydrothermal Microwave. Journal of Alloys and Compounds, 459, 537-542.
http://dx.doi.org/10.1016/j.jallcom.2007.05.023

[14]   Fan, H., Yang, L., Hua, W. and Xie, S. (2004) Controlled Synthesis of Monodispersed CuO Nanocrystals. Nanotechnology, 15, 37-51.
http://dx.doi.org/10.1088/0957-4484/15/1/007

[15]   Yang, X., Chen, S., Zhao, S., Li, D. and Ma, H. (2003) Synthesis of Copper Nanorods Using Electrochemical Methods. Journal of the Serbian Chemical Society, 68, 843-847.
http://dx.doi.org/10.2298/JSC0311843Y

[16]   Wang, H., Xu, J.Z., Zhu, J.J. and Chen, H.Y. (2002) Preparation of CuO Nanoparticles by Microwave Irradiation. Journal of Crystal Growth, 244, 88-94.
http://dx.doi.org/10.1016/S0022-0248(02)01571-3

[17]   Pandey, V., Mishra, G., Verma, S., Wan, M. and Yadav, R. (2012) Synthesis and Ultrasonic Investigations of CuO- PVA Nanofluid. Journal of Materials Sciences and Applications, 3, 664-653.
http://dx.doi.org/10.4236/msa.2012.39097

[18]   International Centre for Diffraction Data (ICDD) (2000) Joint Committee on Powder Diffraction Standards, Diffraction Data File No. 05-0661, 12-23.

[19]   Radhakrishnan, A.A. and Beena, B.B. (2014) Structural and Optical Absorption Analysis of CuO Nanoparticles. Indian Journal of Advances in Chemical Science, 2, 158-161.

[20]   Raksa, P., Kittikunodom, S., Choopun, S., Chairungsri, T., Mangkorntong, P. and Mankorntong, N. (2005) CuO Nanowires by Oxidation Reaction. CMU Journal of Nanotechnology, 4, 1-5.

[21]   Kumar, H. and Rani, R. (2006) Antibacterial Study of Copper Oxide Nanoparticles Synthesized by Microemulsion. Journal of Raman Spectroscopy, 36, 562-574.

[22]   Kloprogge, J.T., Hickey, L. and Frost, R.L. (2004) FT-Raman and FT-IR Spectroscopic Study of Synthetic Mg/Zn/Al-Hydrotalcites. Journal of Raman Spectroscopy, 35, 967-974.
http://dx.doi.org/10.1002/jrs.1244

[23]   Markova-Deneva, I. (2010) Infrared Spectroscopy Investigation of Metallic Nanoparticles Based on Copper, Cobalt, and Nickel Synthesized through Borohydride Reduction Method. Journal of the University of Chemical Technology and Metallurgy, 45, 351-378.

[24]   Karthik, K., Victor Jaya, N., Kanagaraj, M. and Arumugam, S. (2011) Temperature-Dependent Magnetic Anomalies of CuO Nanoparticles. Solid State Communications, 151, 564-568.
http://dx.doi.org/10.1016/j.ssc.2011.01.008

[25]   Chen, L.J., Li, G.S. and Li, L.P. (2008) CuO Nanocrystals in Thermal Decomposition of Ammonium Perchlorate. Journal of Thermal Analysis and Calorimetry, 91, 581-587.
http://dx.doi.org/10.1007/s10973-007-8496-7

[26]   Padil, V.V.T. and Cernik, M. (2013) Green Synthesis of Copper Oxide Nanoparticles Using Gum Karaya as a Biotemplate and Their Antibacterial Application. International Journal of Nanomedicine, 8, 889-898.

 
 
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