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 IJOC  Vol.6 No.1 , March 2016
Synthesis, Spectroscopy and X-Ray Characterization, of Novel Derivatives of Substituted 2-(Benzothiazol-2’-ylthio)acetohydrazide
Abstract: Treatment of 2-(benzo[d]thiazol-2’-ylthio)acetohydrazide (3) with acetylacetone afforded N-(4-oxopentan-2-ylidine) acetohydrazide derivative 5. The acetohyrazide derivatives 3 and 5 were utilized as a key intermediate for the synthesis of a novel heterocyclic compounds. The synthesis of a novel series of condensation and substituted derivatives of 2-(benzo[d]thiazol-2’-ylthio) acetohydrazide in good yield has been reported. The newly synthesized compounds were characterized by elemental analysis 1H-NMR, 13C-NMR spectra and X-ray crystallographic investigations. The reported crystal structures of these novel 2-(benzo[d] thiazol-2’-ylthio)acetohydrazide derivatives are expected to be a remarkable contribution to the crystallographic database of heterocyclic compounds.
Cite this paper: Al-Omran, F. and El-Khair, A. (2016) Synthesis, Spectroscopy and X-Ray Characterization, of Novel Derivatives of Substituted 2-(Benzothiazol-2’-ylthio)acetohydrazide. International Journal of Organic Chemistry, 6, 31-43. doi: 10.4236/ijoc.2016.61004.
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[10]   The CCDC File 1012540 Contains the Supplementary Crystallographic Data for Compounds 6 in This Paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk

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[12]   The CCDC file 1012539 contains the supplementary crystallographic data for compounds 10 in this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk

[13]   The CCDC file 1012538 contains the supplementary crystallographic data for compound 13 in this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk

[14]   The CCDC file 1012541 contains the supplementary crystallographic data for compound 15 in this report. These data can be obtained free of charge from the Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk

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[16]   The CCDC file 1032664 contains the supplementary crystallographic data for compound 23 in this report. These data can be obtained free of charge from the Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk

 
 
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