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 JEP  Vol.7 No.3 , February 2016
A Forensic Approach for Assessing Modes of Subsurface Petroleum Releases
Abstract:

Chronic petroleum discharges resulting from underground storage tank (UST) system failures may continue for months or years, whereas catastrophic releases result from structural failures or overfills that occur over shorter time periods. A forensic analytical framework is useful for distinguishing between chronic and catastrophic releases and identifying responsible parties. However, the forensic program must account for the petroleum type because identifying release modes relies on understanding the chemical evolution of petroleum through time within the context of site conditions. Here we discuss key petroleum components that aid in reconstructing the release and identifying potential responsible parties when subsurface conditions are known.

Cite this paper: Anton, J. and Oudijk, G. (2016) A Forensic Approach for Assessing Modes of Subsurface Petroleum Releases. Journal of Environmental Protection, 7, 312-322. doi: 10.4236/jep.2016.73027.
References

[1]   Oudijk, G. (2013) Forensic Characterization of Gasoline Releases Impacting the Environment. Proceedings of the Soil Forensics Conference of the European Forensics Society, Den Haag, September 2012.

[2]   Stout, S.A., Uhler, A.D., McCarthy, K.J. and Emsbo-Mattingly, S. (2002) Chemical Fingerprinting of Hydrocarbons. In: Murphy, B.L. and Morrison, R.D., Eds., Introduction to Environmental Forensics, Academic Press, San Diego, 137-260.

[3]   Hoag, G.E. and Marley, M.C. (1986) Gasoline Residual Saturation in Saturated Uniform Aquifer Materials. American Society of Civil Engineers Environmental Engineering Division, 112, 586-604.
http://dx.doi.org/10.1061/(ASCE)0733-9372(1986)112:3(586)

[4]   Lyman, W.J., Reidy, P.J. and Levy, B. (1992) Mobility and Degradation of Organic Contaminants in Subsurface Environments. CRC Press, Boca Raton.

[5]   Balouet, J.-C., Smith, K.T., Vroblesky, D. and Oudijk, G. (2009) Use of Dendrochrology and Dendrochemistry in Environmental Forensics: Does It Meet the Daubert Criteria? Environmental Forensics, 10, 268-276.
http://dx.doi.org/10.1080/15275920903347545

[6]   Balouet, J.-C., Oudijk, G., Smith, K.T., Petrisor, I., Grudd, H. and Stocklassa, B. (2007) Dendroecology and Environmental Forensics: From Fundamentals to Case Studies. Environmental Forensics, 8, 1-17.
http://dx.doi.org/10.1080/15275920601180487

[7]   Balouet, J.C. and Oudijk, G. (2006) The Use of Dendroecological Methods to Estimate the Time Frame of Environmental Releases. Environmental Claims Journal, 18, 1-18.

[8]   Kaplan, I.R., Galperin, Y., Lu, S.-T. and Lee, R.-P. (1997) Forensic Environmental Geochemistry: Differentiation of Fuel Types, Their Sources and Release Time. Organic Geochemistry, 27, 289-317.
http://dx.doi.org/10.1016/S0146-6380(97)87941-7

[9]   Christensen, L.B. and Larsen, T.H. (1993) Method for Determining the Age of Diesel Spills in the Soil. Ground Water Monitoring and Remediation, 13, 142-149. http://dx.doi.org/10.1111/j.1745-6592.1993.tb00458.x

[10]   Wade, M.J. (2001) Age-Dating Diesel Spills: Using the European Empirical Time-Based Model in the USA. Environmental Forensics, 2, 347-358. http://dx.doi.org/10.1006/enfo.2001.0069

[11]   Hurst, R.W. and Schmidt, G.W. (2005) Age Significance of nC17/pr Ratios in Forensic Investigations of Refined Product and Crude Oil Releases. Environmental Geosciences, 12, 177-192. http://dx.doi.org/10.1306/eg.04260404004

[12]   Galperin, Y. and Camp, H. (2002) Petroleum Product Identification in Environmental Samples: Distribution Patterns in Fuel-Specific Homologous Series. Soil and Sediment Contamination, April/May Issue, 27-29.

[13]   Hurst, R.W. and Schmidt, G.W. (2007) Age Significance of nC17/pr Ratios in Forensic Investigations of Refined Product and Crude Oil Releases: Reply. Environmental Geosciences, 14, 111-112.
http://dx.doi.org/10.1306/eg.013007R07002

[14]   Oudijk, G. (2007) Age Significance of n-C17/pr Ratios in Forensic Investigations of Refined Product and Crude Oil Releases: Discussion. Environmental Geosciences, 14, 110-112. http://dx.doi.org/10.1306/eg.013007D06009

[15]   Kaplan, I.R. and Galperin, Y. (2008) Zero-Order Kinetics Model for the Christensen-Larsen Method for Fugitive Fuel Age Estimates. Ground Water Monitoring and Remediation, 28, 94-97.
http://dx.doi.org/10.1111/j.1745-6592.2008.00196.x

[16]   Oudijk, G. (2009) Age Dating Heating-Oil Releases, Part 1: Heating-Oil Composition and Subsurface Weathering. Environmental Forensics, 10, 107-119. http://dx.doi.org/10.1080/15275920902873384

[17]   Oudijk, G. (2009) Age Dating Heating-Oil Releases, Part 2: Assessing Weathering and Release Time Frames through Chemistry, Geology and Site History. Environmental Forensics, 10, 120-131.
http://dx.doi.org/10.1080/15275920902945885

[18]   Oudijk, G. and Wade, M.J. (2011) On Age-Dating Distillate Fuels: A Commentary on the Methods of Hurst and Schmidt (2005) and Galperin and Kaplan (2008). Environmental Forensics, 12, 1-2.
http://dx.doi.org/10.1080/15275922.2011.547434

[19]   Oudijk, G. (2012) Uso dos Biomarcadores para Identificar a Origem da Contamina??o pot Petróleo. Revista água, 5, 32-33.

[20]   Philp, R.P. (2002) Application of Stable Isotopes and Radioisotopes in Environmental Forensics. In: Murphy, B. and Morrison, R.D., Eds., Introduction to Environmental Forensics, Chap. 5, Academic Press, San Diego, 395-455.

[21]   Philp, R.P. (2007) The Emergence of Stable Isotopes in Environmental and Forensic Geochemistry Studies: A Review. Environmental Chemistry Letters, 5, 57-66. http://dx.doi.org/10.1007/s10311-006-0081-y

[22]   Oudijk, G. (2012) The History of Leaded Petrol in North America and Europe. Environmental Forensics. In: Morrison, R.D. and O’Sullivan, G., Eds., Proceedings of the 2011 INEF Conference, RSC Publishing, Cambridge, UK, 49-63.
http://dx.doi.org/10.1039/9781849734967-00049

[23]   Oudijk, G. (2010) The Rise and Fall of Organometallic Additives in Automotive Gasoline. Environmental Forensics, 1, 17-49. http://dx.doi.org/10.1080/15275920903346794

[24]   Oudijk, G. (2005) Fingerprinting and Age Dating of Gasoline Releases—A Case Study. Environmental Forensics, 6, 2-10. http://dx.doi.org/10.1080/15275920590913994

[25]   Wade, M.J. (2014) Failures in the Historical Age Dating of Separate Phase Product Leaded Gasoline Releases in the United States Forensic Geochemical Community. Proceedings of the International Network of Environmental Forensics conference, State College, 10-12 June 2013, 37-66. http://dx.doi.org/10.1039/9781782628347-00037

[26]   Oudijk, G. (2007) The Use of Alkyl Leads in Gasoline Age-Dating Investigations: New Insights, Common Investigative Techniques, Limitations and Recommended Practices. Environmental Claims Journal, 19, 68-87.
http://dx.doi.org/10.1080/10406020601158329

[27]   Philp, R.P. (1985) Fossil Fuel Biomarkers. Elsevier, New York.

[28]   Wang, C., Du, J., Gao, X., Duan, Y. and Sheng, Y. (2011) Chemical Characterization of Naturally Weathered Oil Residues in the Sediment from Yellow River Delta, China. Marine Pollution Bulletin, 62, 2469-2475.
http://dx.doi.org/10.1016/j.marpolbul.2011.08.021

[29]   Philp, R.P. and Lewis, C.A. (1987) Organic Geochemistry of Biomarkers. Annual Reviews of Earth and Planetary Science, 15, 363-395. http://dx.doi.org/10.1146/annurev.ea.15.050187.002051

[30]   Stout, S.A., Uhler, A.D. and McCarthy, K. (2005) Middle Distillate Fuel Fingerprinting Using Drimane-Based Bicyclic Sequiterpanes. Environmental Forensics, 6, 241-252.
http://dx.doi.org/10.1080/15275920500194407

[31]   Bruce, L., Miller, T. and Hochman, B. (1991) Solubility versus Equilibrium Saturation of Gasoline Compounds: A Method to Estimate Fuel/Water Partition Coefficient Using Solubility of Koc. AGWSE/API Conference on Petroleum Hydrocarbons and Organic Chemicals in Ground Water, Houston, 571-582.

[32]   Maxxam Analytical (2008) Chromatogram Interpretation Guide. Mississauga, Ontario, unpublished.

[33]   Falta, R.W. (2004) The Potential for Ground Water Contamination by the Gasoline Lead Scavengers Ethylene Dibromide and 1,2-Dichloroethane. Ground Water Monitoring and Remediation, 24, 76-87.
http://dx.doi.org/10.1111/j.1745-6592.2004.tb01294.x

[34]   United States Department of Defense (2003) Toxicological Assessment of Jet-Propulsion Fuel 8. Subcommittee of Jet-Propulsion Fuel 8, Committee on Toxicology, National Research Council, 230 p.

[35]   Kaplan, I.R. and Galperin, Y. (1996) Patterns of Chemical Changes during Environmental Alteration of Hydrocarbon Fuels. Ground Water Monitoring and Remediation, 16, 113-124.
http://dx.doi.org/10.1111/j.1745-6592.1996.tb01178.x

[36]   Lu, S.-T. and Kaplan, I.R. (2008) Characterization of Motor Lubricating Oils and Their Oil-Water Partition. Environmental Forensics, 9, 295-309. http://dx.doi.org/10.1080/15275920802119441

[37]   Kaplan, I.R., Rasco, J. and Lu, S.-T. (2010) Chemical Characterization of Transformer Mineral-Insulating Oils. Environmental Forensics, 11, 117-145. http://dx.doi.org/10.1080/15275920903558760

[38]   Schaeffer, T.L., Cantwell, S.G., Brown, J.L., Watt, D.S. and Fall, R.R. (1979) Microbial Growth on Hydrocarbons: Terminal Branching Inhibits Biodegradation. Applied and Environmental Microbiology, 38, 742-746.

[39]   Oudijk, G. (2012) Age Dating of Middle-Distillate Fuels Released to the Subsurface Environment. In: Dar, I.A., Ed., Earth Sciences, Chap. 12, InTech, Croatia, 541-583. http://dx.doi.org/10.5772/28382

[40]   Hostettler, F.D., Bekins, B.A., Rostad, C.E. and Herkelrath, W.N. (2008) Response to Commentary on Observed Methanogenic Biodegradation Progressions. Environmental Forensics, 9, 121-126.
http://dx.doi.org/10.1080/15275920802115738

[41]   Bregnard, T.P.-A., H?ner, A., H?hener, P. and Zeyer, J. (1997) Anaerobic Degradation of Pristane in Nitrate-Reducing Microcosms and Enrichment Cultures. Applied and Environmental Microbiology, 63, 2077-2081.

[42]   Wang, Z.D., Fingas, M., Yang, C. and Hollebone, B. (2004) Biomarker Fingerprinting: Application and Limitation for Correlation and Source Identification of Oils and Petroleum Products. Preprint Paper—American Chemical Society, Division of Fuel Chemistry, 49, 331-334.

[43]   Stout, S.A. and Douglas, G.C. (2004) Diamondoid Hydrocarbons—Application in the Chemical Fingerprinting of Natural Gas Condensate and Gasoline. Environmental Forensics, 5, 225-235.
http://dx.doi.org/10.1080/15275920490886734

[44]   Philp, P.R. (2011) Personal Communication.

 
 
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