ABSTRACT Discharges from the Mining-and-Chemical Com- bine (MCC) of Rosatom, downstream from Krasnoyarsk-26, near of the Krasnoyarsk resulted in radioactive contamination of sedi-ments of the River Yenisei. The concentration of artificial gammaemitting radionuclides (137Cs, 60Co, 152Eu, and 241Am) was determined to analyze the migration processes leading to the transport of these radionuclides. The concentration of artificial radionuclides in the surface layers of the studied area varied in wide ranges: 137Cs – 318 - 1800 Bq/kg, 60Co – 87 - 720 Bq/kg, 152Eu – 12 - 287 Bq/kg and 241Am – 6 - 76 Bq/kg. There was a sequence of migration of radionuclides investigated in the surface layer of sedi-ments that were collected in the near zone of influence of the MCC: 241Am ≈ 152Eu >60Co >137Cs. Radionuclide species have been found to be directly related to sediment structure and composition.
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Lydia, B. and Svetlana, A. (2011) The relationship of mineral and geochemical composition to artificial radionuclide partitioning inYenisei river sediments downstream frommining-and-chemical combine rosatom. Natural Science, 3, 517-529. doi: 10.4236/ns.2011.37073.
 Bolsunovsky, A.Ya., Ermakov, A.I., Myasoedov, B.F., Novikov, A.P. and Sobolev, A.I., (2000) New data on the content of transuranic elements in bottom sediments of the Yenisei River. Doklady Earth Sciences, 386, 971-974.
 Bolsunovsky, A. (2004) Artificial radionuclides in aquatic plants of the Yenisei River in the area affected by effluents of a Russian plutonium complex. Aquatic Ecology, 38, 57-62.
 Bolsunovsky, A. and Bondareva, L., (2007) Actinides and other radionuclides in sediments and submerged plants of the Yenisei River. Journal of Alloys and Compounds, 444-445, 495-499.
 Orlov, D.S., Sadovnikova, L.K. and Sukhanova, N.I. (2005) Khimiya pochv (soil chemistry). Vysshaya Shkola, Moscow.
 Yashin, I.M., Shishov, L.L. and Raskatov, V.A. (2001) Metodologiya i opyt izucheniya migratsii veshchestv (a methodology of and experience in studying material migration). MSkhA Publishers, Moscow.
 VcLean, J.E. and Bledsoe, B.E. (1992) Behavior of metal in soils. Report EPA USA. 25 p.
 Schultz, M., Burnett, B., Kenneth, G.W., et al. (1995) Development of a sequential extraction technique to define the fractionation of radioactive elements in NIST natural matrix standards. 41st Conference on Bioassay, Analytical, and Environmental Radiochemistry, Boston, 12-16 November 1995, 707-715.
 Howard, J.L. and Vanderbrink, W.J. (1999) Sequential extraction analysis of heavy metals in sediments of variable composition using nitrilotriacetic acid to counteract resorption. Environmental Pollution, 106, 285-292.
 Wang, Zh., Shan, X.-Q. and Zhang, Sh. (2002) Com- parison between fractionation and bioavailability of trace elements in rhizosphere and bulk soils. Chemosphere, 46, 1163-1171.
 Goryachenkova, T.A., Pavlotskaya, F.I. and Bin, N.T. (1990) Forms of the existence of plutonium in soils. Radiochemistry, 2, 47-54.
 Putyrskaya, V., Klemt, E. and R?llin, S. (2009) Migration of 137Cs in tributaries, lake water and sediment of Lago Maggiore (Italy, Switzerland)—Analysis and comparison with Lago di Lugano and other lakes. Journal of Environmental Radioactivity, 100, 35-48.
 Gasco, C., Anton, M.-P. and Gonzales, A.M. (1999) Geochemical association of transuranics in svalbard sediments. 4th International Conference on Environmental Radioactivity in the Arctic. Edinburgh, 20-23 September 1999, 216-218.
 Sowder, A.G., Bertch, P.M. (1998) Speciation of uranium and nickel in aged-contaminated sediments: Coupling spatially resolved SXRT and XANES with chemical extractions/Savannah River ecology laboratory. The University of Georgia, Aiken.
 Fedotov, P.S. and Spivakov, B.Y. (2008) Statistical and dynamic methods of fractionation of element forms in soils, silts and bottom sediments. Success in Chemistry, 7. 690-703.
 Gitelson, I.I., Abrosov, N.S. and Gladyshev, M.I. (1988) The main hydrological and hydrobiological characteristics of the Yenisei River. Transport of Carbon and Minerals in Major World Rivers, Lakes and Estuaries, Geologisch-Palaeontologisches Institut, Hamburg.
 Gee, G.W. and Bauder, J.W. (1986). Particle-size analysis. In: Klute, A. Ed., Methods of Soil Analysis, Annual Meetings of the American Society of Agronomy and Crop Science Society of America, Madison, 383-411.
 Bondareva, L.G. and Bolsunovsky, A.Ya. (2008) Speciation of artificial radionuclides 60Co, 137Cs, 152Eu and 241Am in bottom sediments of the Yenisei River, Radiochemistry, 50, 547-552.
 Alvarado, J.S., Neal, T.J., Smith, L.L. and Erickson, M.D. (1996) Microwave dissolution of plant tissue and the subsequent determination of trace lanthanide and actinide elements by inductively coupled plasma-mass spectrometry. Analytical Chemica Acta, 322, 11-20.
 Kaminski, S., Konoplev, A., Lindner, G. and Schr?der, H.G. (1998) The fate of artificial caesium radionuclides in Lake Constance. Archive fur Hydrobiologie Special Issues Advanced Limnology, 53, 369-409.
 Klemt, E., Kaminski, S., Miller, R., Zibold, G., Astner, M., Burger, M. and Schmid, E. (2000) Normierung von extraktionsexperimenten zur bestimmung der bindung von radiocaesium an sedimente des luganersees. Umweltradioaktivit?t und Strahlendosen in der Schweiz 1999. Bundesamt für Gesundheit. B. 4.4.1-5.
 Kartal, ?., Ayd?n, Z. and Tokal?o?lu, ?. (2006) Fractionation of metals in street sediment samples by using the BCR sequential extraction procedure and multivariate statistical elucidation of the data. Journal of Hazardous Materials, 132, 80-89.
 Rauret, G., López-Sanchez, J., Sauquillo, et al. (1999) Improvement of the BCR three step sequential extraction procedure prior to certification of new soil and sediment reference materials. Journal of Environmental Monito- ring, 1, 57-60.
 Afonin, V.P., Gunicheva, T.N. and Piskunova, L.F. (1984) Rentgenofluorestsentnyi silikatnyi analiz (X-ray fluore- scence silicate analysis). Nauka, Novosibirsk.
 Vakulovsky, S.M. (Ed.) (2003). Estimation and prediction of the consequences for the environment and population of radioactive contamination of the river Yenisei by discharges of the Krasnoyarsk mining and chemical industrial complex. Final Project Technical Report of International Science and Technology Centre Project 1404, SPA-Typhoon, Obninsk.
 Zotina, T.A., Bolsunovsky, A.Ya. and Bondareva, L.G. (2010) Accumulation of 241Am by suspended matter, diatoms and aquatic weeds of the Yenisei River. Journal of Environmental Radioactivity, 101, 148-152.
 Grim R. E. Clay Mineralogy, second edn., McGraw-Hill, New York, 1968.
 Cygan R.T., Greathouse J.A., Heinz H., Kalinichev A.G., (2009). Molecular model and simulations of layered materials. J. Mater Chem. 19, 2470-2481.
 Shvanov, V.N., Frolov, V.T., Sergeyeva, E.I., et al. (1998) Systematika i klassifikacia ocadochnih porod i ih analogov. S-Pb., Nedra.
 Bolsunovsky, A.Ya. and Tcherkezian, V.O. (2001) Hot particles of the Yenisei River flood plain, Russia. Journal of Environmental Monitoring, 57,167-174.
 Salbu, B. (2001) Hot particles—A challenge within radioecology. Journal of Environmental Radioactivity, 53, 267-268.
 Bolsunovsky, A.Ya., Goryachenkova, T.A., Tcherkezian, V.O. and Myasoedov, B.F. (1998) Hot particles in Krasnoyarsk Region. Radiochemistry, 40, 278-281.
 Sukhorukov, F.V., Melgunov, M.S. and Chuguevsky, A.V. (2009) “Hot” and active particles in alluvial soils and sediments of the Yenisei River: Radioisotope composi- tion. Radioprotection, 44, 227-231.
 Gritchenko, Z.G., Kuznetsov, Yu.V., Legin, V.K., Strukov, V.N., Myasoedov, B.F., Novikov, A.P., Shishlov, A.E. and Savitskii, Yu.V. (2001) Hot particles of the second kind in flood lands of the Yenisey River. Radiochemistry, 43, 639-642.
 Pavlotskaya, F.I. (1974) Migratsiya radioaktivnykh produktov globalnykh vypadenii v pochvakh (migration of radioactive products of global fallouts in the soils). Atomizdat, Moscow.