Effect of Seed Size, Suspension Recycling and Substrate Pre-Treatment on the CVD Growth of Diamond Coatings
Author(s)
Awadesh Kumar Mallik1*,
Sandip Bysakh1,
Radhaballabh Bhar2,
Shlomo Z. Rotter3,
Joana Catarina Mendes3
Affiliation(s)
1 CSIR-Central Glass & Ceramic Research Institute, Kolkata, India. 2 Department of Instrumentation Science, Jadavpur University, Kolkata, India. 3 Instituto de Telecomunicações, Campus Universitário de Santiago, Aveiro, Portugal.
1 CSIR-Central Glass & Ceramic Research Institute, Kolkata, India. 2 Department of Instrumentation Science, Jadavpur University, Kolkata, India. 3 Instituto de Telecomunicações, Campus Universitário de Santiago, Aveiro, Portugal.
ABSTRACT
CVD growth of uniform conformal polycrystalline diamond (PCD) coatings over complex three dimensional structures is very important material processing technique. It has been found that the nucleation and subsequent growth period is very critical for successful development of CVD diamond based technologies. There are many methods of enhancing diamond nucleation on foreign substrates-ultrasonic treatment with diamond seed suspension being the best among them. A combination of ultrasonic seeding (US) technique with prior treatment (PT) of the substrate under CVD diamond growth conditions for brief period of time, has found to be very effective in enhancing the diamond nucleation during CVD growth—together they are known as NNP. But successive usage of the same seeding suspension up to ten cycles deteriorates the seeding efficiency. 6th seeding cycle onwards the silicon substrates are barely get covered by diamond crystallites. Five different diamond micron grits were used for seeding the silicon substrates and it is observed that US with the sub-micron particles (0.25 μm) is very effective in efficient nucleation of PCD on Si substrates. PT of the substrate somewhat negates the effect of successive use of the same seeding slurry but it is best to avoid recycling of the same seeding suspension using micron size diamond grits.
CVD growth of uniform conformal polycrystalline diamond (PCD) coatings over complex three dimensional structures is very important material processing technique. It has been found that the nucleation and subsequent growth period is very critical for successful development of CVD diamond based technologies. There are many methods of enhancing diamond nucleation on foreign substrates-ultrasonic treatment with diamond seed suspension being the best among them. A combination of ultrasonic seeding (US) technique with prior treatment (PT) of the substrate under CVD diamond growth conditions for brief period of time, has found to be very effective in enhancing the diamond nucleation during CVD growth—together they are known as NNP. But successive usage of the same seeding suspension up to ten cycles deteriorates the seeding efficiency. 6th seeding cycle onwards the silicon substrates are barely get covered by diamond crystallites. Five different diamond micron grits were used for seeding the silicon substrates and it is observed that US with the sub-micron particles (0.25 μm) is very effective in efficient nucleation of PCD on Si substrates. PT of the substrate somewhat negates the effect of successive use of the same seeding slurry but it is best to avoid recycling of the same seeding suspension using micron size diamond grits.
KEYWORDS
Microwave Plasma CVD, Seeding, Diamond Micron Grits, Novel Nucleation Process (NNP), Polycrystalline Diamond
Microwave Plasma CVD, Seeding, Diamond Micron Grits, Novel Nucleation Process (NNP), Polycrystalline Diamond
Cite this paper
Mallik, A. , Bysakh, S. , Bhar, R. , Rotter, S. and Mendes, J. (2015) Effect of Seed Size, Suspension Recycling and Substrate Pre-Treatment on the CVD Growth of Diamond Coatings. Open Journal of Applied Sciences, 5, 747-763. doi: 10.4236/ojapps.2015.512071.
Mallik, A. , Bysakh, S. , Bhar, R. , Rotter, S. and Mendes, J. (2015) Effect of Seed Size, Suspension Recycling and Substrate Pre-Treatment on the CVD Growth of Diamond Coatings. Open Journal of Applied Sciences, 5, 747-763. doi: 10.4236/ojapps.2015.512071.
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http://dx.doi.org/10.1021/jp036887d [14] Nemanich, R.J., Carlisle, J.A., Hirata, A. and Haenen, K. (2014) CVD Diamond—Research, Applications, and Challenges. MRS Bulletin, 39, 490-494. http://dx.doi.org/10.1557/mrs.2014.97 [15] Schwander, M. and Partes, K. (2011) A Review of Diamond Synthesis by CVD Processes. Diamond & Related Materials, 20, 1287-1301. http://dx.doi.org/10.1016/j.diamond.2011.08.005 [16] Mallik, A.K., Mendes, J.C., Rotter, S.Z. and Bysakh, S. (2014) Detonation Nanodiamond Seeding Technique for Nucleation Enhancement of CVD Diamond—Some Experimental Insights. Advances in Ceramic Science and Engineering, 3, 36-45. http://dx.doi.org/10.14355/acse.2014.03.005 [17] Lee, S.T., Lin, Z. and Jiang, X. (1999) CVD Diamond Films: Nucleation and Growth. Materials Science and Engineering R, 25, 123-154. http://dx.doi.org/10.1016/S0927-796X(99)00003-0 [18] Smolin, A.A., Ralchenko, V.G., Pimenov, S.M., Kononenko, T.V. and Loubnin, E.N. (1993) Optical Monitoring of Nucleation and Growth of Diamond Films. Applied Physics Letters, 62, 3449-3451.
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