OJG  Vol.5 No.10 , October 2015
Dolomitization in Campanian Oil Shale Rocks from South-Western Jordan
ABSTRACT
This work represents the first detailed study of an oil shale (OS) section from the Upper Campanian Amman Silicified Limestone (ASL) Formation in south-western part of Jordan. More than five meters of oil shale have been recorded. Using the petrography and geochemistry, this study aims to focus on such non-conventional types of oil shale rocks in Jordan and to shed some light on their composition and formational environment. Unlike oil shale from Maastrichtian to early Tertiary, this type of oil shale is highly dolomitized. The dolomite is diagenetic in origin. This oil shale type contains considerable amount of OM and remarkably enriched in some trace elements and shows quite low sulfur content. Results suggest that the formation of dolomite appears to be limited by the rate of organic matter oxidation.

Cite this paper
Alnawafleh, H. , Tarawneh, K. , Khoury, H. , Abdelhadi, N. , Shakkoury, O. , Dwairi, R. and Amaireh, M. (2015) Dolomitization in Campanian Oil Shale Rocks from South-Western Jordan. Open Journal of Geology, 5, 689-700. doi: 10.4236/ojg.2015.510061.
References
[1]   Alali, J. and Sawaqed, S. (2006) Oil Shale Resources Development in Jordan. Unpublished Report. Natural Resources Authority, Amman.

[2]   Abed, A.M. (2000) The Geology of Jordan and Its Environment and Water (in Arabic). Publication of the Jordanian Geologists Association, Amman.

[3]   Abed, A.M., Arouri, K., Amiereh, B.S. and Al-Hawari, Z. (2009) Characterization and Genesis of Some Jordanian Oil Shales. Dirasat, Pure Sciences, 36, 7-17

[4]   Abed, A.M., Al-Arouri, K. and Boreham, C.J. (2005) Source Rock Potential of the Phosphorite Bituminous Chalk-Marl Sequence in Jordan. Marine and Petroleum Geology, 22, 413-425.
http://dx.doi.org/10.1016/j.marpetgeo.2004.12.004

[5]   Abed, A.M. and Arouri, K. (2006) Characterization and Genesis of Oil Shales from Jordan. International Conference on Oils Shale: “Recent Trends in Oil Shale”, 7-9 November 2006, Amman, PAPER No. Rtos-A121.

[6]   Abed, A.M. and Al-Arouri, K. (1994) Organic Geochemistry of Central Jordan Upper Cretaceous Phosphorites: Phosphogenesis and Source Rock. Proceedings of the 2nd International Conference—Geology of the Arab World, Cairo University, Cairo, 321-338

[7]   Abed, A.M. and Amireh, B.S. (1983) Petrography and Geochemistry of Some Jordanian oil Shales from North Jordan. Journal of Petroleum Geology, 5, 261-274.
http://dx.doi.org/10.1111/j.1747-5457.1983.tb00571.x

[8]   Alnawafleh, H.M. (2007) Geological Factors Controlling the Variability of Maastrichtian Bituminous Rocks in Jordan. PhD Thesis, The University of Nottingham, Nottingham.

[9]   Alnawafleh, H. and Fraige, F. (2013) Characterization of South and Central Jordan Oil Shales. European Journal of Scientific Research, 102, 589-595

[10]   Alnawafleh, H.M. and Fraige, F.Y. (2015) Analysis of Selected Oil Shale Samples from El-Lajjun, Central Jordan. Geomaterials, 5, 77-84. http://dx.doi.org/10.4236/gm.2015.53008

[11]   Dercourt, J., Gaetani, M., Vrielynck, B., Barrier, E., Biju-Duval, B., Brunet, M.F., Cadet, J.P., Crasquin, S. and Sandulescu, M., Eds. (2000) Atlas Peri-Tethys, Palaeogeographical Maps. 24 Maps and Explanatory Notes: 1-XX, CCGM/ CGMW, Paris, 1-269.

[12]   Abed, A.M. (1994) Shallow Marine Phosphorite-Chert-Palygorskite Association, Late Cretaceous, Amman Formation, Jordan. In: Iijima, A., Abed, A.M. and Garrison, R., Eds., Siliceous, Phosphatic and Glauconitic Sediments of the Tertiary and Mesozoic, VSP, Zeist, 205-324.

[13]   Abu-Jaber, N., Jawad Ali, A. and Shinaq, R. (1997) Genesis of the Amman Formation Silicified Limestone of Jordan. Africa Geoscience Review, 4, 381-393.

[14]   Abu Saad, L. and Al Bashish, M. (1999) Surface and Subsurface Lithostratigraphic Relationships of the Cretaceous Amman Silicified Limestone Formation (Belqa Group) in Jordan. Subsurface Geology Bulletin, No. 10, The Hashemite Kingdom of Jordan, Ministry of Energy and Mineral Resources, Natural Resources Authority, Amman, 58 p.

[15]   Powell, J.H. (1989) Stratigraphy and Sedimentation of the Phanerozoic Rocks in Central and South Jordan—Part B: Kurnub, Ajlun and Belqa Groups. Geological Bulletin, No. 11, The Hashemite Kingdom of Jordan, Ministry of Energy and Mineral Resources, Natural Resources Authority, Amman, 130 p.

[16]   Alonso-Zarza, A.M. and Martín-Pérez, A. (2008) Dolomite in Caves: Recent Dolomite Formation in Oxic, Non-Sulfate Environments. Castacar Cave, Spain. Sedimentary Geology, 205, 160-164.
http://dx.doi.org/10.1016/j.sedgeo.2008.02.006

[17]   Al-Awadi, M., Clark, W.J., Moore, W.R., Herron, M., Zhang, T., Zhao, W., Hurley, N., Kho, D., Montaron, B. and Sadooni, F. (2009) Dolomite: Perspectives on a Perplexing Mineral. Oilfield Review, 21, 32-45.

[18]   Pichler, T. and Humphrey, J.D. (2001) Formation of Dolomite in Recent Island-Arc Sediments Due to Gas-Seawater-Sediment Interaction. Journal of Sedimentary Research, 71, 394-399.
http://dx.doi.org/10.1306/2DC4094D-0E47-11D7-8643000102C1865D

[19]   Madanat, M. and Al-Omari, Y. (2006) Mineral Status and Future Opportunity: Dolomite. Geological Survey Administration. Unpublished Report, The NRA, Amman.
http://www.nra.gov.jo/images/stories/pdf_files/Dolomite.pdf

[20]   Abed, A.M. and Kraishan, G.M. (1991) Evidence for Shallow-Marine Origin of a “Monterey-Formation Type” Chert-Phosphorite-Dolomite Sequence: Amman Formation (Late Cretaceous), Central Jordan. Facies, 24, 25-38. http://dx.doi.org/10.1007/BF02536839

[21]   Al-Mehdawi, H.S. (2000) Petrography, Geochemistry and Evaluation of Organic Matter of Oil Shale in the Area between Wadi Zahar and Wadi Abu-Ziyad (NW Jordan). Unpublished Master’s Thesis, Yarmouk University, Irbid.

[22]   Amireh, B.S. (1979) Geochemistry and Petrography of Some Jordanian Oil Shales. Unpublished Master’s Thesis, The University of Jordan, Amman.

[23]   Hufnagel, H. (1980) Investigation of the El-Lajjun Oil Shale Deposit, Bundesanstalt fur Geowissenschaften und Rohstoffe, Hannover. Technical Cooperation Project No. 78.2156.5.

[24]   Hufnagel, H., Schmitz, H.H. and El-Kaysi, K. (1980) Investigation of the El Lajjun Oil Shale Deposits. Unpublished Report, NRA, Amman.

[25]   Jarrar, M. and Mustafa, H. (1995) Mineralogical and Geochemical Study of the Oil Shale of Wadi Esh-Shallala (N-Jordan). Abhath Al-Yarmouk. Pure Science and Engineering Series, 4, 111-136.

[26]   Jarrar, M.N. (1989) Composition, Stratigraphy and Depositional Environment of Kerogeneous Limestone of Wadi Esh-Shallalla (NW Jordan). Unpublished Master’s Thesis, Yarmouk University, Irbid.

[27]   Ali Hussein, M., Alqudah, M., van den Boorn, S., Kolonic, S., Podlaha, O.G. and Mutterlose, J. (2014) Eocene Oil Shales from Jordan—Their Petrography, Carbon and Oxygen Stable Isotopes. GeoArabia, 19, 139-162.

[28]   Ali Hussein, M., Alqudah, M., Podlaha, O.G., Blessenohl, M. and Mutterlose, J. (2015) Depositional Environment of Late Cretaceous to Eocene Organic-Rich Marls from Jordan. GeoArabia, 20, 191-210.

[29]   Alqudah, M., Ali Hussein, M., Podlaha, O.G., van den Boorn, S., Kolonic, S. and Mutterlose, J. (2014) Calcareous Nannofossil Biostratigraphy of Eocene Oil Shales from Central Jordan. GeoArabia, 19, 117-140.

[30]   Alqudah, M., Ali Hussein, M., Van den Boorn, S., Giraldo, V., Kolonic, S., Podlaha, O.G. and Mutterlose, J. (2014) Eocene Oil Shales from Jordan—Paleoenvironmental Implications from Reworked Microfossils. Marine and Petroleum Geology, 52, 93-106. http://dx.doi.org/10.1016/j.marpetgeo.2014.02.001

[31]   Alqudah, M., Ali Hussein, M., Van den Boorn, S., Podlaha, O.G. and Mutterlose, J. (2015) Biostratigraphy and Depositional Setting of Maastrichtian e Eocene Oil Shales from Jordan. Marine and Petroleum Geology, 60, 87-104. http://dx.doi.org/10.1016/j.marpetgeo.2014.07.025

[32]   Bowen, R. and Jux, U. (1987) Afro-Arabian Geology. Chapman and Hall, London.

[33]   Chaimaov, T.A., Barazangi, M., Al-Saad, D., Sawaf, T. and Gebran, A. (1992) Mesozoic and Cenozoic Deformation Inferred from Seismic Stratigraphy in the Southwestern Intracontinental Palmyride Fold-Thrust Belt, Syria. Geological Society of America Bulletin, 104, 704-715.
http://dx.doi.org/10.1130/0016-7606(1992)104<0704:MACDIF>2.3.CO;2

[34]   Almogi-Labin, A., Bein, A. and Sass, E. (1993) Late Cretaceous Upwelling System along the Southern Tethys Margin: Interrelationship between Productivity, Bottom Water Environments, and Organic Matter Preservation. Paleoceanography, 8, 671-690. http://dx.doi.org/10.1029/93PA02197

[35]   Khoury, H.N. (2015) Uranium Minerals of Central Jordan. Applied Earth Science, 124, 104-128.
http://dx.doi.org/10.1179/1743275815Y.0000000005

[36]   Barjous, M.O. (1992) The Geology of the Ash Shawbak Area. Map Sheet No. 3151 III, Bulletin 19, Natural Resources Authority, Amman.

[37]   Peters, K.E., Walters, C.C. and Moldowan, J.M. (2005) The Biomarker Guide, Part II: Biomarkers and Isotopes in Petroleum Exploration and Earth History. Cambridge University Press, Cambridge.

[38]   Minster, T., Yoffe, O., Nathan, Y. and Flexer, A. (1997) Geochemistry, Mineralogy and Paleoenvironments of Deposition of the Oil Shale Member in the Negev. IJES, 46, 41-59.

[39]   Dill, H.G., Kus, J., Abed, A.M., Sachsenhofer, R.F. and Abul Khair, H. (2009) Diagenetic and Epigenetic Alteration of Cretaceous to Paleogene Organic-Rich Sedimentary Successions in North-Western Jordan, Typical of the Western Margin of the Arabian Plate. GeoArabia, 14, 101-140.

[40]   Soudry, D. (2000) Carbonate-Phosphate Competition in the Negev Phosphorites: A Microstructural Study. In: Glenn, C.R., Prevot-Lucas, L. and Lucas, J., Eds., Marine Authigenesis: From Global to Microbial, SEPM Special Publication No. 66, SEPM (Society for Sedimentary Geology), Oklahoma, 415-426.

[41]   Cappellen, P.V. (2003) Biomineralization and Global Biogeochemical Cycles. Reviews in Mineralogy and Geochemistry, 54, 357-381. http://dx.doi.org/10.2113/0540357

[42]   Minster, T. (2001) Significance of P2O5 Distribution in the Oil Shale Member, Gareb Formation, Mishor Rotem and Oron Basins. GSI-Current Research, 13, 47-51.

[43]   Minster, T., Nathan, Y. and Raveh, A. (1992) Carbon and Sulfur Relationships in Marine Senonian Organic-Rich, Iron-Poor Sediments—A Case Study. Chemical Geology, 97, 145-161.
http://dx.doi.org/10.1016/0009-2541(92)90141-Q

[44]   Sangiorgi, F., Dinelli, E., Maffioli, P., Capotondi, L., Giunta, S., Morigi, C., Principato, M.S., Negri, A., Emeis, K.C. and Corselli, C. (2006) Geochemical and Micropaleontological Characterisation of a Mediterranean Sapropel S5: A Case Study from Core BAN89GC09 (South of Crete). Palaeogeography, Palaeoclimatology, Palaeoecology, 235, 192-207. http://dx.doi.org/10.1016/j.palaeo.2005.09.029

[45]   Stuben, D., Kramar, U., Berner, Z., Stinnesbeck, W., Keller, G. and Adatte, T. (2002) Trace Elements, Stable Isotopes, and Clay Mineralogy of the Elles II K-T Boundary Section in Tunisia: Indications for Sea Level Fluctuations and Primary Productivity. Palaeogeography, Palaeoclimatology, Palaeoecology, 178, 321-345. http://dx.doi.org/10.1016/S0031-0182(01)00401-1

[46]   Minster, T., Ilani, S. and Yoffe, O. (1997) Manganese as an Indicator of the Intensity of Anoxia during the Deposition of the Senonian Oil Shales in the Negev. Oil Shale, 40, 5-18.

[47]   Martinez-Ruiz, F., Paytan, A., Kastner, M., Gonzalez-Donoso, J.M., Linares, D., Bernasconi, S.M. and Jimenez-Espejo, F.J. (2003) A Comparative Study of the Geochemical and Mineralogical Characteristics of the S1 Sapropel in the Western and Eastern Mediterranean. Palaeogeography, Palaeoclimatology, Palaeoecology, 190, 23-37. http://dx.doi.org/10.1016/S0031-0182(02)00597-7

[48]   Stoll, H.M. and Schrag, D.P. (2001) Sr/Ca Variations in Cretaceous Carbonates: Relation to Productivity and Sea Level Changes. Palaeogeography, Palaeoclimatology, Palaeoecology, 168, 311-336.
http://dx.doi.org/10.1016/S0031-0182(01)00205-X

[49]   Bellanca, A., Erba, E., Neri, R., Premoli Silva, I., Sprovieri, M., Tremolada, F. and Verga, D. (2002) Palaeoceanographic Significance of the Tethyan “Livello Selli” (Early Aptian) from the Hybla Formation, Northwestern Sicily: Biostratigraphy and High-Resolution Chemostratigraphic Records. Palaeogeography, Palaeoclimatology, Palaeoecology, 185, 175-196. http://dx.doi.org/10.1016/S0031-0182(02)00299-7

[50]   Fleurance, S., Cuney, M., Malartre, M. and Reyx, J. (2013) Origin of the Extreme Polymetallic Enrichment (Cd, Cr, Mo, Ni, U, V, Zn) of the Late Cretaceous-Early Tertiary Belqa Group, Central Jordan. Palaeogeography, Palaeoclimatology, Palaeoecology, 369, 201-219.
http://dx.doi.org/10.1016/j.palaeo.2012.10.020

 
 
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