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 JEP  Vol.6 No.8 , August 2015
Removal of Basic Blue 9 Dye by Hydrogen Peroxide Activated by Electrogenerated Fe2+/Fe3+ and Simultaneous Production of Hydrogen
Abstract: Electrochemical techniques were used to oxidize organic pollutants by Fenton process using a mix of H2O2 and ferrous ions at a parallel plate reactor. The first stage was to build a micro scale reactor comprising two compartments, cathode and anode, separated by a membrane (Nafion-117). Each compartment has inlets and outlets to allow the flow of fluids (10 Lmin-1). The function of the reactor is to oxidize organic pollutants as well as to produce H2. Hydrogen is electrogenerated in the catholyte by the reduction of protons on a carbon steel cathode in acidic medium (0.05 M H2SO4). At the same time, a mixture of Fe2+/Fe3+ ions is produced in the anolyte (0.05 M Na2SO4, pH ≈ 2) by means of the oxidation of a sacrificial electrode made of stainless steel mesh. Fe2+/Fe3+ ions interact with H2O2 to generate strong oxidants which are responsible for oxidizing the organic matter and removing color. A voltage of 1 V was applied between the electrodes and remained constant, while the current observed was approximately 0.06 A. Under these conditions, the activation rate with different H2O2 concentrations (15, 20, 25, 30, 35, 40, 45 and 50 mM) was evaluated. The maximum activation rate (1.3 mM·min-1) was obtained using 30 mM H2O2. Under these conditions, the oxidation of a synthetic industrial effluent (0.615 mM BB9) was performed and the following results were obtained: 95% of this concentration was removed in 5 minutes and 15 mL of H2 was electrogenerated in 30 minutes.
Cite this paper: Bustos-Terrones, Y. , Rojas-Valencia, M. , Álvarez-Gallegos, A. and García, P. (2015) Removal of Basic Blue 9 Dye by Hydrogen Peroxide Activated by Electrogenerated Fe2+/Fe3+ and Simultaneous Production of Hydrogen. Journal of Environmental Protection, 6, 781-791. doi: 10.4236/jep.2015.68071.
References

[1]   Suteu, D., Bilba, D. and Coseri, S. (2014) Macroporous Polymeric Ion Exchangers as Adsorbents for the Removal of Cationic Dye Basic Blue 9 from Aqueous Solutions. Journal of Applied Polymer Science, 131.
http://dx.doi.org/10.1002/app.39620

[2]   Yavuz, Y., Savas-Koparal, A. and Ögütveren, ü. (2011) Electrochemical Oxidation of Basic Blue 3 Dye Using a Diamond Anode: Evaluation of Colour, COD and Toxicity Removal. Journal of Chemical Technology and Biotechnology, 86, 261-265.
http://dx.doi.org/10.1002/jctb.2512

[3]   Riera-Torres, M. and Gutiérrez, M. (2010) Colour Removal of Three Reactive Dyes by UV Light Exposure after Electrochemical Treatment. Chemical Engineering Journal, 156, 114-120.
http://dx.doi.org/10.1016/j.cej.2009.10.006

[4]   Özcan, A., Oturan, N., Oturan, M. and Sahin, Y. (2009) Removal of Acid Orange 7 from Water by Electrochemically Generated Fenton’S Reagent. Journal of Hazardous Materials, 163, 1213-1220.
http://dx.doi.org/10.1016/j.jhazmat.2008.07.088

[5]   Daneshvar, N., Oladegaragoze, A. and Djafarzadeh, N. (2006) Decolorization of Basic Dye Solutions by Electrocoagulation: An Investigation of the Effect of Operational Parameters. Journal of Hazardous Materials, 129, 116-122. http://dx.doi.org/10.1016/j.jhazmat.2005.08.033

[6]   Navarro-Solís, I., Villalba-Almendra, L. and Alvarez-Gallegos, A. (2010) H2 Production by PEM Electrolysis, Assisted by Textile Effluent Treatment and a Solar Photovoltaic Cell. International Journal of Hydrogen Energy, 35, 10833-10841.
http://dx.doi.org/10.1016/j.ijhydene.2010.07.086

[7]   Figueroa, S., Vázquez, L. and Alvarez-Gallegos, A. (2009) Decolorizing Textile Wastewater with Fenton’s Reagent Electrogenerated with a Solar Photovoltaic Cell. Water Research, 43, 283-294.
http://dx.doi.org/10.1016/j.watres.2008.10.014

[8]   Brillas, E., Sirés, I. and Oturan, M. (2009) Electro-Fenton Process and Related Electrochemical Technologies Based on Fenton’s Reaction Chemistry. Chemical Reviews, 109, 6570-6631.
http://dx.doi.org/10.1021/cr900136g

[9]   Oturan, M., Oturan, N., Lahitte, C. and Trevin, S. (2001) Production of Hydroxyl Radicals by Electrochemically Assisted Fenton’s Reagent: Application to the Mineralization of an Organic Micropollutant, Pentachlorophenol. Journal of Electroanalytical Chemistry, 507, 96-102.
http://dx.doi.org/10.1016/S0022-0728(01)00369-2

[10]   Duesterberg, C. and Waite, T. (2006) Process Optimization of Fenton Oxidation Using Kinetic Modeling. Environmental Science and Technology, 40, 4189-4195.
http://dx.doi.org/10.1021/es060311v

[11]   Liu, H., Li, X., Leng, Y. and Wang, C. (2007) Kinetic Modeling of Electro-Fenton Reaction in Aqueous Solution. Water Research, 41, 1161-1167.
http://dx.doi.org/10.1016/j.watres.2006.12.006

[12]   Ventura, A., Jacquet, G., Bermond, A. and Camel, V. (2002) Electrochemical Generation of the Fenton’s Reagent: Application to Atrazine Degradation. Water Research, 36, 3517-3522.
http://dx.doi.org/10.1016/S0043-1354(02)00064-7

[13]   Hammami, S., Bellakhal, N., Oturan, M., Oturan, N. and Dachraoui, M. (2008) Degradation of Acid Orange 7 by Electrochemically Generated OH Radicals in Acidic Aqueous Medium Using a Boron-Doped Diamond or Platinum Anode: A Mechanistic Study. Chemosphere, 73, 678-684.
http://dx.doi.org/10.1016/j.chemosphere.2008.07.010

[14]   Hammami, S., Oturan, N., Oturan, M., Bellakhal, N. and Dachraoui, M. (2007) Oxidative Degradation of Direct Orange 61 by Electro-Fenton Process Using a Carbon Felt Electrode: Application of the Experimental Design Methodology. Journal of Electroanalytical Chemistry, 610, 75-84.
http://dx.doi.org/10.1016/j.jelechem.2007.07.004

[15]   Qiang, Z., Chang, J. and Huang, C. (2003) Electrochemical Regeneration of Fe2+ in Fenton Oxidation Processes. Water Research, 37, 1308-1319.
http://dx.doi.org/10.1016/S0043-1354(02)00461-X

[16]   Sabareeswaran, S., Balaji, R., Ramya, K., Rajalakshmi, N. and Dhathathereyan, K. (2013) Carbon Assisted Water Electrolysis for Hydrogen Generation. AIP Conference Proceedings, 1538, 43-47.
http://dx.doi.org/10.1063/1.4810030

[17]   Ewan, B. and Allen, R. (2005) A Figure of Merit Assessment of the Routes to Hydrogen. International Journal of Hydrogen Energy, 30, 809-819.
http://dx.doi.org/10.1016/j.ijhydene.2005.02.003

[18]   Goltsov, V., Veziroglu, T. and Goltsova, L. (2006) Hydrogen Civilization of the Future—A New Conception of the IAHE. International Journal of Hydrogen Energy, 31, 153-159.
http://dx.doi.org/10.1016/j.ijhydene.2005.04.045

[19]   Grigoriev, S., Porembsky, V. and Fateev, V. (2006) Pure Hydrogen Production by PEM Electrolysis for Hydrogen energy. International Journal of Hydrogen Energy, 31, 171-175.
http://dx.doi.org/10.1016/j.ijhydene.2005.04.038

[20]   Chanchal, S. (2008) Direct Synthesis of Hydrogen Peroxide from Hydrogen and Oxygen: An Overview of Recent Developments in the Process. Applied Catalysis A: General, 350, 133-149.
http://dx.doi.org/10.1016/j.apcata.2008.07.043

[21]   Fernandes, A., Morao, A., Magrinho, M., Lopes, A. and Goncalves, I. (2004) Electrochemical Degradation of C. I. Acid Orange 7. Dyes and Pigments, 61, 287-296.
http://dx.doi.org/10.1016/j.dyepig.2003.11.008

[22]   Lucas, M. and Peres, J. (2006) Decolorization of the Azo Dye Reactive Black 5 by Fenton and Photo-Fenton Oxidation. Dyes and Pigments, 71, 236-244.
http://dx.doi.org/10.1016/j.dyepig.2005.07.007

[23]   Barros, A., Pizzolato, T., Carissimi, E. and Schneider, I. (2006) Decolorizing Dye Wastewater from the Agate Industry with Fenton Oxidation Process. Minerals Engineering, 19, 87-90.
http://dx.doi.org/10.1016/j.mineng.2005.04.004

[24]   Flox, C., Ammar, S., Arias, C., Brillas, E., Vargas-Zavala, A. and Abdelhedi, R. (2006) Electro-Fenton and Photoelectro-Fenton Degradation of Indigo Carmine in Acidic Aqueous Medium. Applied Catalysis B: Environmental, 67, 93-104.
http://dx.doi.org/10.1016/j.apcatb.2006.04.020

[25]   Bae, W., Lee, S. and Ko, G. (2004) Evaluation of Predominant Reaction Mechanisms for the Fenton Process in Textile Dyeing Wastewater Treatment. Water Science and Technology, 49, 91-96.

[26]   Awad, H. and Galwa, N. (2005) Electrochemical Degradation of Acid Blue and Basic Brown Dyes on Pb/PbO2 Electrode in the Presence of Different Conductive Electrolyte and Effect of Various Operating Factors. Chemosphere, 61, 1327-1335.
http://dx.doi.org/10.1016/j.chemosphere.2005.03.054

[27]   Boye, B., Morième, M. and Brillas, E. (2003) Anodic Oxidation, Electro-Fenton and Photoelectro-Fenton Treatments of 2,4,5-Trichlorophenoxyacetic Acid. Journal of Electroanalytical Chemistry, 557, 135-146.
http://dx.doi.org/10.1016/S0022-0728(03)00366-8

[28]   Rodrigues, C., Madeira, L. and Boaventura, R. (2009) Treatment of Textile Effluent by Chemical (Fenton’s Reagent) and Biological (Sequencing Batch Reactor) Oxidation. Journal of Hazardous Materials, 172, 1551-1559.
http://dx.doi.org/10.1016/j.jhazmat.2009.08.027

[29]   Sala, M. and Gutiérrez-Bouzán, M. (2012) Electrochemical Techniques in Textile Processes and Wastewater Treatment. International Journal of Photoenergy, 2012, Article ID: 629103.
http://dx.doi.org/10.1155/2012/629103

[30]   Carneiro, P., Osugi, M., Fugivara, C., Boralle, N., Furlan, M. and Zanoni, M. (2005) Evaluation of Different Electrochemical Methods on the Oxidation and Degradation of Reactive Blue 4 in Aqueous Solution. Chemosphere, 59, 431-439.
http://dx.doi.org/10.1016/j.chemosphere.2004.10.043

[31]   Mohan, N., Balasubramanian, N. and Basha, C. (2007) Electrochemical Oxidation of Textile Wastewater and Its Reuse. Journal of Hazardous Materials, 147, 644-651.
http://dx.doi.org/10.1016/j.jhazmat.2007.01.063

[32]   Radha, K. V., Sridevi, V. and Kalaivani, K. (2009) Electrochemical Oxidation for the Treatment of Textile Industry Wastewater. Bioresource Technology, 100, 987-990.
http://dx.doi.org/10.1016/j.biortech.2008.06.048

[33]   Meriç, S., Kaptan, D. and Ölmez, T. (2004) Color and COD Removal from Wastewater Containing Reactive Black 5 Using Fenton’s Oxidation Process. Chemosphere, 54, 435-441.
http://dx.doi.org/10.1016/j.chemosphere.2003.08.010

[34]   Xu, X., Liao, P., Yuan, S., Tong, M., Luo, M. and Xie, W. (2013) Cu-Catalytic Generation of Reactive Oxidizing Species from H2 and O2 Produced by Water Electrolysis for Electro-Fenton Degradation of Organic Contaminants. Chemical Engineering Journal, 233, 117-123.
http://dx.doi.org/10.1016/j.cej.2013.08.046

 
 
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