OJMS  Vol.5 No.3 , July 2015
Chlorsiliconorganic Compound Formed during Lipid Separation from Japan Marine Ascidia
ABSTRACT
The crystal substance has been isolated from chloroform-ethanol extract of sea organism Halocynthia aurantium. A set of spectrometry methods was used to describe a structure of this compound. It was appeared that element analysis showed ≈60% chlorine, less silicon, carbon and hydrogen. Another spectroscopy method (UV, IR, NMR) did not give an additional information. The data obtained suggests us that we have the matter with unusual compound. X-ray-phase analysis was used also. On the basis of an element analysis and X-ray diffraction parameters the formula of compound С2H2Si4Cl12 has been offered.

Cite this paper
Isay, S. , Busarova, N. and Zemnuhova, L. (2015) Chlorsiliconorganic Compound Formed during Lipid Separation from Japan Marine Ascidia. Open Journal of Marine Science, 5, 290-294. doi: 10.4236/ojms.2015.53024.
References
[1]   Mischenko, Т.Ya., Korotchenko, O.D. and Isay, S.V. (1982) Search for Prostaglandin-Like Substances in Marine Organisms. Bulletin of Experimental Biology and Medicine, 94, 94-96.

[2]   Rochow, E.G. (1945) The Direct Synthesis of Organosilicon Compounds. Journal of the American Chemical Society, 67, 963-965. http://dx.doi.org/10.1021/ja01222a026

[3]   Brook, M.A. (2000) Silicon in Organic, Organometallic, and Polymer Chemistry. John Wiley & Sons, New York, 704pp.

[4]   Bains, W. and Tacke, R. (2003) Silicon Chemistry as a Novel Source of Chemical Diversity in Drug Design. Current Opinion in Drug Discovery & Development, 6, 526-543.

[5]   Colvin, E.W., Baldwin, J.E. and Buckommgham, A.D. (2013) Silicon in Organic Synthesis: Butterworths Monographs in Chemistry. Science, New York.

[6]   Price, C.T., Koval, K.J. and Langford, J.R. (2013) Silicon: A Review of Its Potential Role in the Prevention and Treatment of Postmenopausal Osteoporosis. International Journal of Endocrinology, 2013, Article ID: 316783. http://dx.doi.org/10.1155/2013/316783

[7]   Burzynski, S. (2012) Novel Cancer Research and Fight to Prove Its Worth. Alternative Therapies in Health and Medicine, 18, 54-61.

[8]   Kipping, F. and Lloyd, L.L. (1901) Organic Derivatives of Silicon. Triphenylsilicon and Alkoxysilicon Chlorides. Journal of the Chemical Society, Transactions, 79, 449.
http://dx.doi.org/10.1039/ct9017900449

[9]   Briquet, F., Colas, A. and Thomas, X. (1996) Silicones for Medical Use. Conf. 20-21 March 1996, France.

[10]   Murakami, K., Yorimitsu, H. and Oshima, K. (2010) Synthesis of Tetraorganosilanes: (Chloromethyl)Dimethylphenylsilane. Organic Syntheses, 87, 178.
http://dx.doi.org/10.1002/0471264229.os087.19

[11]   Colas, A. and Curtis, J. (2004) Silicones Biomaterials: History and Chemistry. Biomaterials Science: An Introduction to Materials in Medicine, 2, 80-85.

[12]   Moretto, H.-H., Schulze, M. and Wagner, G. (2015) “Silicones” in Ulmann’s Encyclopedia of Industrial Chemistry. Wiley-VcH, Weinheim.

[13]   Gubin, S.P. (1987) Chemistry of Clusters. Bases of Classification and a Structure. Science, Moscow.

[14]   Rudinger, Ch., Beruda, H. and Schmidbaur, H. (1994) Synthesis and Molecular Structure of Silylated Ethenes and Acetylenes. Zeitschrift für Naturforschung, 49b, 1348.
http://dx.doi.org/10.1515/znb-1994-1008

[15]   Li, Y.F., Li, F.Y., Zhou, Z. and Chen, Z.F. (2011) SiC2 Silagraphene and Its One-Dimensional Derivatives: Where Planar Tetracoordinate Silicon Happens. Journal of the American Chemical Society, 133, 900. http://dx.doi.org/10.1021/ja107711m

[16]   Tillmann, J., Meyer, L., Schweizer, J.I., Bolte, M., Lamer, H.-W., Wagner, M. and Holthausen, M.C. (2014) Chloride-Induced Aufbau of Perchlorinated Cyclohexasilanes from Si2Cl6: A Mechanistic Scenario. Chemistry—A European Journal, 20, 9234. http://dx.doi.org/10.1002/chem.201402655

 
 
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