Adsorption of Naphthalene on Clay and Sandy Soil from Aqueous Solution
ABSTRACT
The adsorption behavior of naphthalene using clay and sandy soil as adsorbents is examined under ambient conditions. The adsorption equilibrium of naphthalene on clay and sandy soil was evaluated by the Langmuir, Freundlich and Tempkin isotherms. The results showed that the equilibrium data for naphthalene fitted the Freundlich model best within the concentration range studied for both clay and sandy soil. Experimental results showed that the time taken to attain adsorption equilibrium for naphthalene was 26 hrs and 20 hrs for clay and sandy soil, respectively. Among the tested kinetic models in this study, the pseudo-second order successfully predicted the adsorption process.
The adsorption behavior of naphthalene using clay and sandy soil as adsorbents is examined under ambient conditions. The adsorption equilibrium of naphthalene on clay and sandy soil was evaluated by the Langmuir, Freundlich and Tempkin isotherms. The results showed that the equilibrium data for naphthalene fitted the Freundlich model best within the concentration range studied for both clay and sandy soil. Experimental results showed that the time taken to attain adsorption equilibrium for naphthalene was 26 hrs and 20 hrs for clay and sandy soil, respectively. Among the tested kinetic models in this study, the pseudo-second order successfully predicted the adsorption process.
Cite this paper
Osagie, E. and Owabor, C. (2015) Adsorption of Naphthalene on Clay and Sandy Soil from Aqueous Solution. Advances in Chemical Engineering and Science, 5, 345-351. doi: 10.4236/aces.2015.53036.
Osagie, E. and Owabor, C. (2015) Adsorption of Naphthalene on Clay and Sandy Soil from Aqueous Solution. Advances in Chemical Engineering and Science, 5, 345-351. doi: 10.4236/aces.2015.53036.
References
[1] Chang, C., Chang, C., Chen, K., Tsai, W., Shie, J. and Chen, Y. (2004) Adsorption of Naphthalene on Zeolite from Aqueous Solution. Journal of Colloid and Interface Science, 277, 29-34.
http://dx.doi.org/10.1016/j.jcis.2004.04.022 [2] World Health Organization (2009) Nitrobenzene in Drinking-Water: Background Document for Development of WHO Guidelines for Drinking-Water Quality. [3] WFD, E. (2000) Directive 2000/60/EC of the European Parliament and of the Council Establishing a Framework for the Community Action in the Field of Water Policy. Joint Text Approved by the Conciliation Committee Provided for in Article, 251. [4] Williams, P. (1990) Sampling and Analysis of Polycyclic Aromatic Compounds from Combustion Systems: A Review. Journal of the Institute of Energy, 63, 22-30. [5] Bandosz, T.J. (2006) Activated Carbon Surfaces in Environmental Remediation. Academic Press, Waltham. [6] McCabe, W.L., Smith, J.C. and Harriott, P. (1993) Unit Operations of Chemical Engineering. McGraw-Hill, New York. [7] Koh, S. and Dixon, J.B. (2001) Preparation and Application of Organo-Minerals as Sorbents of Phenol, Benzene and Toluene. Applied Clay Science, 18, 111-122.
http://dx.doi.org/10.1016/S0169-1317(00)00040-5 [8] Lagergren, S. (1898) About the Theory of So-Called Adsorption of Soluble Substances. [9] Sivraj, R., Namasivayam, C. and Kadirvelu, K. (2001) Orange Peel as an Adsorbent in the Removal of Acid Violet 17 (Acid Dye) from Aqueous Solution. Waste Manage, 21, 105-110.
http://dx.doi.org/10.1016/S0956-053X(00)00076-3 [10] Treybal, R.E., Rodríguez, A.G. and Lozano, F.J. (1980) Operaciones de transferencia de masa. McGraw-Hill, New York. [11] Curry, C.W., Bennett, R.H., Hulbert, M.H., Curry, K.J. and Faas, R.W. (2004) Comparative Study of Sand Porosity and a Technique for Determining Porosity of Undisturbed Marine Sediment. Marine Georesources and Geotechnology, 22, 231-252.
http://dx.doi.org/10.1080/10641190490900844 [12] Huang, W., Peng, P., Yu, Z. and Fu, J. (2003) Effects of Organic Matter Heterogeneity on Sorption and Desorption of Organic Contaminants by Soils and Sediments. Applied Geochemistry, 18, 955-972.
http://dx.doi.org/10.1016/S0883-2927(02)00205-6
[1] Chang, C., Chang, C., Chen, K., Tsai, W., Shie, J. and Chen, Y. (2004) Adsorption of Naphthalene on Zeolite from Aqueous Solution. Journal of Colloid and Interface Science, 277, 29-34.
http://dx.doi.org/10.1016/j.jcis.2004.04.022 [2] World Health Organization (2009) Nitrobenzene in Drinking-Water: Background Document for Development of WHO Guidelines for Drinking-Water Quality. [3] WFD, E. (2000) Directive 2000/60/EC of the European Parliament and of the Council Establishing a Framework for the Community Action in the Field of Water Policy. Joint Text Approved by the Conciliation Committee Provided for in Article, 251. [4] Williams, P. (1990) Sampling and Analysis of Polycyclic Aromatic Compounds from Combustion Systems: A Review. Journal of the Institute of Energy, 63, 22-30. [5] Bandosz, T.J. (2006) Activated Carbon Surfaces in Environmental Remediation. Academic Press, Waltham. [6] McCabe, W.L., Smith, J.C. and Harriott, P. (1993) Unit Operations of Chemical Engineering. McGraw-Hill, New York. [7] Koh, S. and Dixon, J.B. (2001) Preparation and Application of Organo-Minerals as Sorbents of Phenol, Benzene and Toluene. Applied Clay Science, 18, 111-122.
http://dx.doi.org/10.1016/S0169-1317(00)00040-5 [8] Lagergren, S. (1898) About the Theory of So-Called Adsorption of Soluble Substances. [9] Sivraj, R., Namasivayam, C. and Kadirvelu, K. (2001) Orange Peel as an Adsorbent in the Removal of Acid Violet 17 (Acid Dye) from Aqueous Solution. Waste Manage, 21, 105-110.
http://dx.doi.org/10.1016/S0956-053X(00)00076-3 [10] Treybal, R.E., Rodríguez, A.G. and Lozano, F.J. (1980) Operaciones de transferencia de masa. McGraw-Hill, New York. [11] Curry, C.W., Bennett, R.H., Hulbert, M.H., Curry, K.J. and Faas, R.W. (2004) Comparative Study of Sand Porosity and a Technique for Determining Porosity of Undisturbed Marine Sediment. Marine Georesources and Geotechnology, 22, 231-252.
http://dx.doi.org/10.1080/10641190490900844 [12] Huang, W., Peng, P., Yu, Z. and Fu, J. (2003) Effects of Organic Matter Heterogeneity on Sorption and Desorption of Organic Contaminants by Soils and Sediments. Applied Geochemistry, 18, 955-972.
http://dx.doi.org/10.1016/S0883-2927(02)00205-6