The Study of Inhibition Effect of Rhenium Thioacetic and Dithiocarbonic Acids in Oxidation Reaction
Author(s)
Fakhriyya M. Nasiri1,
Fikret A. Kuliev2*,
Arif J. Efendy1,
Lyudmila I. Kojarova1,
Farida A. Abdullayeva1,
Irada H. Melikova1,
Natevan F. Aykan1
Affiliation(s)
1 Institute of Catalysis and Inorganic Chemistry Named after Academician M.F.Nagiyev of Azerbaijan, Baku, Azerbaijan. 2 Azerbaijan Medical University, Baku, Azerbaijan.
1 Institute of Catalysis and Inorganic Chemistry Named after Academician M.F.Nagiyev of Azerbaijan, Baku, Azerbaijan. 2 Azerbaijan Medical University, Baku, Azerbaijan.
ABSTRACT
Antioxidant activity of interaction products of the studied compounds with tret-Butyl hydroperoxide is studied. New, more active acceptors of free radicals are formed in the process of oxidative transformations of initial compounds. It is investigated that the products have high inhibiting properties. The parameter fk, characterizing inhibitory effect of an inhibitor is studied.
Antioxidant activity of interaction products of the studied compounds with tret-Butyl hydroperoxide is studied. New, more active acceptors of free radicals are formed in the process of oxidative transformations of initial compounds. It is investigated that the products have high inhibiting properties. The parameter fk, characterizing inhibitory effect of an inhibitor is studied.
Cite this paper
Nasiri, F. , Kuliev, F. , Efendy, A. , Kojarova, L. , Abdullayeva, F. , Melikova, I. and Aykan, N. (2015) The Study of Inhibition Effect of Rhenium Thioacetic and Dithiocarbonic Acids in Oxidation Reaction. Advances in Chemical Engineering and Science, 5, 338-344. doi: 10.4236/aces.2015.53035.
Nasiri, F. , Kuliev, F. , Efendy, A. , Kojarova, L. , Abdullayeva, F. , Melikova, I. and Aykan, N. (2015) The Study of Inhibition Effect of Rhenium Thioacetic and Dithiocarbonic Acids in Oxidation Reaction. Advances in Chemical Engineering and Science, 5, 338-344. doi: 10.4236/aces.2015.53035.
References
[1] Kuliev, A.M. (1982) Chemistry and Technology of Additives to Oils and Fuels. M.: Chemistry, 360. [2] Denisov, Е.Т., Sarkisov, O.M. and Liechtenstein G.I. (2000) Chemical Kinetics. М.: Nauka. 568. [3] Patent No. 2239494 (RF) (2004) Oxidation Catalysts of Phenol Compounds Series. (Bogolitsyn, K.G., Popova, N.P., Skrebets, T.E. and Kosheleva, A.E.) BI, 31, 324. [4] Nasiri, F.M., Efendy, A.J., Melikova, I.G. and Zaytseva, Z.A. (2009) Study of Kinetics of Antioxidant Effect of Carbamate and Thioamide in Oxidation Process of Hydrocarbons. Azerbaijan Chemistry Journal, 1, 62-73. [5] Denisov, E.T. and Kovalev, T.I. (1993) Oxidation and Stabilization of Reactive Fuels. М: Chemistry, 272. [6] Denisov, E.T. (1981) Rate Constants of Hemolytic Liquid-Phase Reactions. М.: Nauka, 711.
[1] Kuliev, A.M. (1982) Chemistry and Technology of Additives to Oils and Fuels. M.: Chemistry, 360. [2] Denisov, Е.Т., Sarkisov, O.M. and Liechtenstein G.I. (2000) Chemical Kinetics. М.: Nauka. 568. [3] Patent No. 2239494 (RF) (2004) Oxidation Catalysts of Phenol Compounds Series. (Bogolitsyn, K.G., Popova, N.P., Skrebets, T.E. and Kosheleva, A.E.) BI, 31, 324. [4] Nasiri, F.M., Efendy, A.J., Melikova, I.G. and Zaytseva, Z.A. (2009) Study of Kinetics of Antioxidant Effect of Carbamate and Thioamide in Oxidation Process of Hydrocarbons. Azerbaijan Chemistry Journal, 1, 62-73. [5] Denisov, E.T. and Kovalev, T.I. (1993) Oxidation and Stabilization of Reactive Fuels. М: Chemistry, 272. [6] Denisov, E.T. (1981) Rate Constants of Hemolytic Liquid-Phase Reactions. М.: Nauka, 711.