OJAP  Vol.4 No.2 , June 2015
Trace Metals Concentrations at the Atmosphere Particulate Matters in the Southeast Asian Mega City (Dhaka, Bangladesh)
Abstract: Atmospheric particulate matters were collected on quartz fibre filters for 24 hours with a low volume sampler from January 2014 to March 2014 at the Southeast Asian mega city (Dhaka, Bangladesh). Particulate matters samples were analysed for eleven trace metals with inductively coupled plasma mass spectrometer (ICP-MS) at Cà Foscari University of Venice, Italy. Trace metals were extracted from filters with digestion method using a mixture of HNO3 and H2O2. The average concentration of the determined trace metals of As, Cd, Ni, Cu, Pb, Cr, Fe, Mn, Zn, Sband Se were 3.06, 6.28, 3.77, 11.98, 305.6, 9.2, 2057.0, 42.2, 303.3, 5.47 and 2.43 ng·mDž, respectively. Arsenic concentration is much lower in the atmosphere of Dhaka, though Bangladesh has severe arsenic problem in the ground water. Lead and cadmium concentrations showed decreasing trend in Dhaka compared than previous measurements—but still they have very high levels compared than Europe and USA. There is very limited information for Mn, Sb and Se concentrations in Dhaka air. Correlation studies showed that several trace metals had potential joint sources of origin, e.g., manganese is highly correlated with iron (r2 = 0.97) and nickel (r2 = 0.84), copper (r2 = 0.86); lead with arsenic (r2 = 0.79) and antimony (r2 = 0.78). Enrichment factors analysis was also done with the data base for the respective metals in earth crust and coal fly ash. As and Cu both have combined sources, whereas Cd, Pb and Zn were from coal fly ash.Trace metals concentrations in Dhaka city air were much higher than Europe and USA but comparable or slightly lower than other south Asian countries. This is the first extensive study for the eleven trace metals with ICP-MS in Dhaka, Bangladesh.
Cite this paper: Islam, M. , Majumder, S. , Mamun, A. , Khan, M. , Rahman, M. , Salam, A. (2015) Trace Metals Concentrations at the Atmosphere Particulate Matters in the Southeast Asian Mega City (Dhaka, Bangladesh). Open Journal of Air Pollution, 4, 86-98. doi: 10.4236/ojap.2015.42009.

[1]   Tsai, Y.I. and Cheng, M.T. (2004) Characterization of Chemical Species in Atmospheric Aerosols in a Metropolitan Basin. Chemosphere, 54, 1171-1181.

[2]   Park, S.S. and Kim, Y.J. (2005) Source Contributions to Fine Particulate Matter in an Urban Atmosphere. Chemosphere, 59, 217-226.

[3]   Watson, J.G., Zhu, T., Chow, J.C., Engelbrecht, J., Fujita, E.M. and Wilson, W.E. (2002) Receptor Modelling Application Framework for Particle Source Apportionment. Chemosphere, 49, 1093-1136.

[4]   Quiterio, S.L., da Silva, C.R.S., Arbilla, G. and Escaleira, V. (2004) Metals in Airborne Particulate Matter in the Industrial District of Santa Cruz, Rio de Janeiro, in an Annual Period. Atmospheric Environment, 38, 321-331.

[5]   Arditsoglou, A. and Samara, C. (2005) Levels of Total Suspended Particulate Matter and Major Trace Elements in Kosovo: A Source Identification and Apportionment Study. Chemosphere, 59, 669-678.

[6]   Shah, M.H. (2009) Atmospheric Particulate Matter: Trace Metals and Size Fractionation. VDM Verlag Dr. Muller, Saarbrucken, 228.

[7]   Shaheen, N., Shah, M.H. and Jaffar, M. (2005) A Study of Airborne Selected Metals and Particle Size Distribution in Relation to Climatic Variables and Their Source Identification. Water, Air, and Soil Pollution, 164, 275-294.

[8]   Callen, M.S., de la Cruz, M.T., Lopez, J.M., Navarro, M.V. and Mastral, A.M. (2009) Comparison of Receptor Models for Source Apportionment of the PM10 in Zaragoza (Spain). Chemosphere, 76, 1120-1129.

[9]   Prieditis, H. and Adamson, I.Y.R. (2002) Comparative Pulmonary Toxicity of Various Soluble Metals Found in Urban Particulate Dusts. Experimental Lung Research, 28, 563-576.

[10]   Magas, O.K., Gunter, J.T. and Regens, J.L. (2007) Ambient Air Pollution and Daily Pediatric Hospitalizations for Asthma. Environmental Science and Pollution Research, 14, 19-23.

[11]   Wild, P., Bourgkard, E. and Paris, C. (2009) Lung Cancer and Exposure to Metals: The Epidemiological Evidence. Method Molecular Biology, 472, 139-167.

[12]   Dreher, K.L., Jaskot, R.H., Lehmann, J.R., Richards, J.H., McGee, J.K., Ghio, A.J. and Costa, D.L. (1997) Soluble Transition Metals Mediate Residualoil Fly Ash Induced Acute Lung Injury. Journal of Toxicology Environmental Health, 50, 285-305.

[13]   Schaumann, F., Borm, P.J., Herbrich, A., Knoch, J., Pitz, M., Schins, R.P., Luettig, B., Hohlfeld, J.M., Heinrich, J. and Krug, N. (2004) Metal-Rich Ambient Particles (Particulate Matter 2.5) Cause Airway Inflammation in Healthy Subjects. American Journal of Respiratory and Critical Care Medicine, 170, 898-903.

[14]   Schwarze, P.E., Totlandsdal, A., Herseth, I.J., Holme, A.J., Låg, M., Refsnes, M., Øvrevik, J., Sandberg, W. and B ølling, K.A. (2010) Importance of Components and Sources for Health Effects of Particulate Air Pollution. Vanda Villanyi.

[15]   Gurgueira, S.A., Lawrence, J., Coull, B., Murthy, G.G. and Gonzalez-Flecha, B. (2002) Rapid Increases in the Steady-State Concentration of Reactive Oxygen Species in the Lungs and Heart after Particulate Air Pollution Inhalation. Environmental Health Perspective, 110, 749-755.

[16]   Bell, L.M., Ebisu, K., Peng, D.R., Samet, M.J. and Dominici, F. (2009) Hospital Admissions and Chemical Composition of Fine Particle Air Pollution. American Journal of Respiratory and Critical Care Medicine, 179, 1115-1120.

[17]   Fiaz, A. and Strum, P.J. (2000) New Directions: Air Pollutions and Road Traffic in Developing Countries. Atmospheric Environment, 34, 4745-4746.

[18]   Salam, A., Al Mamoon, H., Ullah, M.B. and Ullah, S.M. (2012) Measurement of the Atmospheric Aerosol Particle Size Distribution in a Highly Polluted Mega-City in Southeast Asia (Dhaka-Bangladesh). Atmospheric Environment, 59, 338-343.

[19]   WHO (2000) Cadmium. Air Quality Guidelines for Europe, 2nd Edition, World Health Organization Regional Office for Europe, Copenhagen.

[20]   Rahman, M.A., Rahim, A., Siddique, N.A. and Alam, A.M.S. (2013) Studies on Selected Metals and Other Pollutants in Urban Atmosphere in Dhaka Bangladesh. Dhaka University Journal of Science, 61, 41-46.

[21]   Salam, A., Bauer, H., Kassin, K., Ullah, S.M. and Puxbaum, H. (2003) Aerosol Chemical Characteristics of a Mega-City in Southeast Asia (Dhaka-Bangladesh). Atmospheric Environment, 37, 2517-2528.

[22]   Salam, A., Ullah, M.B., Islam, M.D., Salam, M.A. and Ullah, S.M. (2011) Carbonaceous Species in Total Suspended Particulate Matters at Different Urban and Suburban Locations in the Greater Dhaka Region, Bangladesh. Air Quality, Atmosphere and Health, 6, 239-245.

[23]   CEN (2005) Ambient Air Quality-Standard Gravimetric Measurement Method for the Determination of the PM2.5 Mass Fraction of Suspended Particulate Matter. EN 14907:2005.

[24]   Mondol, M.N., Khaled, M., Chamon, A.S. and Ullah, S.M. (2014) Trace Metal Concentration in Atmospheric Aerosols in Some City Areas of Bangladesh. Bangladesh Journal of Scientific and Industrial Research, 49, 263-270.

[25]   Huang, X.D., Olmez, I., Aras, N.K. and Gordon, G.E. (1994) Emissions of Trace Elements from Motor Vehicles: Potential Marker Elements and Source Composition Profile. Atmospheric Environment, 28, 1385-1391.

[26]   Chuersuwan, N., Nimrat, S., Lekphet, S. and Kerdkumrai, T. (2008) Levels and Major Sources of PM2.5 and PM10 in Bangkok Metropolitan Region. Environment International, 34, 671-677.

[27]   Sharma, V.K. and Patil, R.S. (1992) Chemical Composition and Source Identification of Bombay Aerosol. Environmental Technology, 13, 1043-1052.

[28]   Salam, A., Hossain, T., Siddique, M.N.A. and Alam, A.M.S. (2008) Characteristics of Atmospheric Trace Gases, Particulate Matter, and Heavy Metal Pollution in Dhaka, Bangladesh. Air Quality Atmosphere Health, 1, 101-109.

[29]   Chan, W.H and Lusis, M.A. (1986) Smelting Operations and Trace Metals in Air and Precipitation in the Sudbury Basin. Advances in Environmental Science and Technology, 17, 113-143.

[30]   Norseth, T. (1994) Environmental Pollution around Nickel Smelters in the Kola Peninsula (Russia). Science of the Total Environment, 148, 103-108.

[31]   Sivertsen, B. (1991) Air Pollution in the Border Areas of Norway/Soviet Union January 1990-March 1991. Lillestrøm, Norwegian Institute for Air Research, (NILU OR: 69/91; Ref:0-8976). Analytik, Institut fur Anorganische und AngewandteChemie, Universit at Hamburg, Germany.

[32]   Saltzman, B.E., Cholak, J. and Schafer, L.J. (1985) Concentrations of Six Metals in the Air of Eight Cities. Environmental Science and Technology, 19, 328-333.

[33]   Schmidt, J.A. and Andren, A.W. (1990) The Atmospheric Chemistry of Nickel. In: Nriagu, J.O., Ed., Nickel in the Environment, Vol. 1999, Wiley, New York, 93-137.

[34]   Bennett, B.J. (1994) Environmental Nickel Pathways to Man. In: Sunderman Jr., F.W., Ed., Nickel in the Human Environment, Lyon International Agency for Research on Cancer, Lyon, 487-495.

[35]   Smith, D.J.T., Harrison, R.M., Luhana, L., Pio, C.A., Castro, L.M., Tariq, M.N., Hayat, S. and Quraishi, T. (1996) Concentrations of Particulate Airborne Polycyclic Aromatic Hydrocarbons and Metals Collected in Lahore, Pakistan. Atmospheric Environment, 30, 4031-4040.

[36]   Mori, I., Nishikawa, M., Tanimura, T. and Quan, H. (2003) Change in Size Distribution and Chemical Composition of Kosa (Asian Dust) Aerosol during Long Range Transport. Atmospheric Environment, 37, 4253-4263.

[37]   Khaliquzzaman, M., Biswas, S.K., Tarafdar, S.A., Islam, A. and Khan, A.H. (1997) Trace Element Composition of Size Fractionated Airborne Particulate Matter in Urban and Rural Areas in Bangladesh. Report, Accelerator Facilities Division and Chemistry Division, Atomic Energy Centre, Dhaka.

[38]   Fung, Y.S. and Wong, L.W.Y. (1995) Apportionment of Air Pollution Sources by Receptor Models in Hong Kong. Atmospheric Environment, 29, 2041-2048.

[39]   Balachandran, S., Meena, B.R. and Khillare, P.S. (2000) Particle Size Distribution and Its Elemental Composition in the Ambient Air of Delhi. Environment International, 26, 49-54.

[40]   Duce, R.A., Hoffman, G.L. and Zoller, W.H. (1975) Atmospheric Trace Metals at Remote Northern and Southern Hemisphere sites. Pollution or Natural Science, 187, 59-61.

[41]   Bowen, H.J.M. (1979) Environmental Chemistry of the Elements. Academic Press, London.

[42]   Georgii, H.W. and Müller, J. (2004) Schwermetallaerosole in der Großstadtluft (Heavy Metal). In: Godish, T., Ed., Air Quality, 4th Edition.

[43]   Kretzschmar, J.G., Delespaul, I. and De Rijck, T. (1980) Heavy Metal Levels in Belgium: A Five Year Survey. Science of the Total environment, 14, 85-97.

[44]   Wang, X.L., Sato, T., Xing, B.S., Tamamura, S. and Tao, S. (2005) Source Identification, Size Distribution and Indicator Screening of Airborne Trace Metals in Kanazawa, Japan. Aerosol Science, 36, 197-210.

[45]   Sharma, M. and Maloo, S. (2005) Assessment of Ambient Air PM10 and PM2.5 and Characterization of PM10 in the City of Kanpur, India. Atmospheric Environment, 39, 6015-6026.

[46]   NILU (Norwegian Institute of Air Research) (2002) Heavy Metals and POPS within the EMEP Region 2000. Report -EMEP/CCC-9/ 2002, Norwegian Institute of Air Research, Kjeller.

[47]   Goforth, M.R. and Christoforou, C.S. (2006) Particle Size Distribution and Atmospheric Metals Measurements in a Rural Area in the South Eastern USA. Science of the Total Environment, 217-227.

[48]   Mason, B. and Moore, C. (1982) Principles of Geochemistry. Wiley, New York.

[49]   Steiger, M. (1991) Die anthropogenen und natürlichen Quellenurbaner und mariner Aerosol charakterisiert und quantifiziertdurch Multielementanalyse und chemische Receptormodelle, Schriftenreihe Angewandte.

[50]   Puxbaum, H. (1993) Luftchemie. Schriftenreihe “Modern Analytical Chemie,” Band 5. Institutfür Analytical Chemie, Technische Universat Wien.

[51]   Chester, R., Nimmo, M. and Preston, M.R. (1999) The Trace Metal Chemistry of Atmospheric Dry Deposition Samples Collected at Cap Ferrat: A Coastal Site in the Western Mediterranean. Marine Chemistry, 68, 15-30.

[52]   Weckwerth, G. (2001) Verification of Traffic Emitted Aerosol Components in the Ambient Air of Cologne (Germany). Atmospheric Environment, 35, 5525-5536.

[53]   Sternbeck, J., Sjodin, A.A. and Andersson, K. (2002) Metal Emissions from Road Traffic and the Influence of Resuspension-Results from Two Tunnel Studies. Atmospheric Environment, 36, 4735-4744.

[54]   Singh, M., Jaques, P.A. and Sioutas, C. (2002) Size Distribution and Diurnal Characteristics of Particle-Bound Metals in Source and Receptor Sites of the Los Angeleles Basin. Atmospheric Environment, 36, 1675-1689.

[55]   Rogge, W.F., Hildemann, L.M., Mazurek, M.A., Cass, G.R. and Simoneit, B.R.T. (1993) Sources of Fine Organic Aerosols: 3 Road Dust, Tire Debris, and Organometallic Brake Lining Dust: Roads as Sources and Sinks. Environmental Science and Technology, 27, 1892-1904.

[56]   Nriagu, J.O. and Pacyna, J.M. (1988) Quantitative Assessment of Worldwide Contamination of Air, Water and Soils by Trace Metals. Nature, 333, 134-199.

[57]   Pacyna, J.M. (1998) Source Inventories for Atmospheric Trace Metals. In: Harrison, R.M. and van Grieken, R.E., Eds., Atmospheric Particles, IUPAC Series on Analytical and Physical Chemistry of Environmental Systems, Vol. 5, Wiley, Chichester, 385-423.