GEP  Vol.3 No.4 , June 2015
Removal of Fluoride from Groundwater by Carbonised Punica granatum Carbon (“CPGC”) Bio-Adsorbent
Abstract
This study applies the development and application of low cost, Punica granatum bio-adsorbent for the removal of fluoride in groundwater. The batch adsorption study was carried out to analyze the defluoridation by contact time variation, adsorbent dose, adsorbate concentration, adsorbent particle size and presence of co-anions at neutral pH. The analysis of the isotherm equilibrium data using the Langmuir and Freundlich equations by linear methods showed that the data fitted better with Freundlich model (R2 > 0.980). Prepared adsorbent showed enhanced removal of fluoride concentration by 78.1% at equilibrium contact time of 75 minutes. Carbonised Punica granatum Carbon (CPGC) seeds showed a high affinity for fluoride ions compared with other conventional adsorbents. Therefore, it can be considered as a potentially “good”, low-cost bio-adsorbent for de-fluoridation of water compared to other bio-adsorbent.

Cite this paper
Kanaujia, S. , Singh, B. and Singh, S. (2015) Removal of Fluoride from Groundwater by Carbonised Punica granatum Carbon (“CPGC”) Bio-Adsorbent. Journal of Geoscience and Environment Protection, 3, 1-9. doi: 10.4236/gep.2015.34001.
References

[1]   World Health Organization (WHO) (1984) Fluoride and Fluorides: Environmental Health Criteria 36. Geneva.

[2]   World Health Organization (WHO) (2002) Fluorides—Environmental Health Criteria 227. Geneva.

[3]   Viswanathan, G., Gopalakrishnan, S. and Siva Ilango S. (2001) Assessment of Water Contribution on Total Fluoride intake of Various Age Groups of People in Fluoride Endemic And Non-Endemic Areas of Dindigul District, Tamil Nadu, South India. Water Research, 44, 6186-6200.
http://dx.doi.org/10.1016/j.watres.2010.07.041

[4]   Yadav, A.K., Kaushik, C.P., Haritash, A.K., Singh, B., Raghuvanshi, S.P. and Kansal, A. (2007) Determination of Exposure and Probable Ingestion of Fluoride through Tea, Toothpaste, Tobacco and Pan Masala. Journal of Hazardous Materials, 142, 77-80.
http://dx.doi.org/10.1016/j.jhazmat.2006.07.051

[5]   Harrison, P.T.C. (2005) Fluoride in Water: A UK Perspective. Journal of Fluorine Chemistry, 126, 1448-1456.
http://dx.doi.org/10.1016/j.jfluchem.2005.09.009

[6]   Valdez-Jiménez, L., Soria Fregozo, C., Miranda Beltrán, M.L., Gutiérrez Coronado, O. and Pérez Vega, M.I. (2011) Effects of the Fluoride on the Central Nervous System. Neurología, 26, 297-300.
http://dx.doi.org/10.1016/j.nrl.2010.10.008

[7]   Browne, D., Whelton, H. and Mullane, D.O. (2005) Fluoride Metabolism and Fluorosis. Journak of Dentistry, 33, 177-186.
http://dx.doi.org/10.1016/j.jdent.2004.10.003

[8]   Mandinic, Z., Curcic, M., Antonijevic, B., Carevic, M., Mandic, J., Djukic-Cosic, D. and Lekic, C.P. (2010) Fluoride in Drinking Water and Dental Fluorosis. Science of the Total Environment, 408, 3507-3512.
http://dx.doi.org/10.1016/j.scitotenv.2010.04.029

[9]   Karthikeyan, G. and Shanmugasundarraj, A. (2000) Isopleth Mapping and In-Situ Fluoride Dependence on Water Quality in the Krishnagiri Block of Tamil Nadu in South India. Fluoride, 33, 121-127.

[10]   Kumar, S., Bharti, V.K., Singh, K.B. and Singh, T.N. (2010). Quality Assessment of Potable Water in the Town of Kolasib, Mizoram (India). Environmental Earth Sciences, 61, 115-121.
http://dx.doi.org/10.1007/s12665-009-0326-8

[11]   Singh, A.K., Raj, B., Tiwari, A.K. and Mahato, M.K. (2013) Evaluation of Hydrogeochemical Processes and Groundwater Quality in the Jhansi District of Bundelkhand Region, India. Environmental Earth Sciences, 70, 1225-1247.
http://dx.doi.org/10.1007/s12665-012-2209-7

[12]   Meenakshi, R.C. and Maheshwari, J. (2006) Fluoride in Drinking Water and Its Removal. Journal of Hazardous Materials, 137, 456-463.
http://dx.doi.org/10.1016/j.jhazmat.2006.02.024

[13]   Mourad, N.M., Sharshar, T., Elnimr, T. and Mousa, M.A. (2009) Radioactivity and Fluoride Contamination Derived from a Phosphate Fertilizer Plant in Egypt. Applied Radiation and Isotopes, 67, 1259-1268.
http://dx.doi.org/10.1016/j.apradiso.2009.02.025

[14]   Fan, C.S. and Li, K.C. (2013) Production of Insulating Glass Ceramics from Thin Film Transistor-Liquid Crystal Display (TFT-LCD) Waste Glass and Calcium Fluoride Sludge. Journal of Cleaner Production, 57, 335-341.
http://dx.doi.org/10.1016/j.jclepro.2013.06.002

[15]   Ponsot, I., Falcone, R. and Bernardo, E. (2013) Stabilization of Fluorine-Containing Industrial Waste by Production of Sintered Glass-Ceramics. Ceramics International, 39, 6907-6915.
http://dx.doi.org/10.1016/j.ceramint.2013.02.025

[16]   World Health Organization (2008) Guidelines for Drinking-Water Quality. WHO, Geneva.

[17]   Susheela, A.K. (1999) Fluorosis Management Programme in India. Current Science, 77, 1250-1256.

[18]   CGWB (2010) Groundwater Quality in Shallow Aquifers of India. Central Ground Water Board, Faridabad, 117.

[19]   Tiwari, A.K. and Singh, A.K. (2014) Hydrogeochemical Investigation and Groundwater Quality Assessment of Pratapgarh District, Uttar Pradesh. Journal of the Geological Society of India, 83, 329-343.
http://dx.doi.org/10.1007/s12594-014-0045-y

[20]   Kanaujia, S., Singh, B. and Singh, S.K. (2013) Mapping of Fluoride Endemic Areas in Rae Bareli District, U.P., India. Chemical Science Transactions, 2, 1411-1417.
http://dx.doi.org/10.7598/cst2013.539

[21]   Kanaujia, S., Singh, B. and Singh, S.K. (2015) Novel Environmentally Benign Technique for the Removal of Fluoride, Arsenic and Coliform from Waste Water. International Journal of Sciences: Basic and Applied Research, 19, 88-96.

[22]   Liu, R.X., Guo, J.L. and Tang, H.X. (2002) Adsorption of Fluoride, Phosphate, and Arsenate Ions on a New Type of Ion Exchange Fiber. Journal of Colloid and Interface Science, 248, 268-274.
http://dx.doi.org/10.1006/jcis.2002.8260

[23]   Turner, B.D., Binning, P. and Stipp, S.L.S. (2005) Fluoride Removal by Calcite: Evidence for Fluorite Precipitation and Surface Adsorption. Environmental Science & Technology, 39, 9561-9568.
http://dx.doi.org/10.1021/es0505090

[24]   Ghosh, D., Sinha, M.K. and Purkait, M.K. (2013) A Comparative Analysis of Low-Cost Ceramic Membrane Preparation for Effective Fluoride Removal Using Hybrid Technique. Desalination, 327, 2-13.
http://dx.doi.org/10.1016/j.desal.2013.08.003

[25]   Menkouchi Sahli, M.A., Annouar, S., Tahaikt, M., Mountadar, M., Soufiane, A. and Elmidaoui, A. (2007) Fluoride Removal for Underground Brackish Water by Adsorption on the Natural Chitosan and Electrodialysis. Desalination, 212, 37-45.
http://dx.doi.org/10.1016/j.desal.2006.09.018

[26]   Mohapatra, M., Anand, S., Mishra, B.K., Giles, D.E. and Singh, P. (2009) Review of Fluoride Removal from Drinking Water. Journal of Environmental Management, 91, 67-77.
http://dx.doi.org/10.1016/j.jenvman.2009.08.015

[27]   Meenakshi, S. and Viswanathan, N. (2007) Identification of Selective Ion-Exchange Resin for Fluoride Sorption. Journal of Colloid and Interface Science, 308, 438-450.
http://dx.doi.org/10.1016/j.jcis.2006.12.032

[28]   Sujana, M.G., Thakur, R.S., Das, S.N. and Rao, S.B. (1997) Defluorination of Waste Waters. Asian Journal of Chemistry, 9, 561-570.

[29]   Greenlee, L.F., Desmond, F.L., Freeman, B.D., Marrot, B. and Moulin, P. (2009) Reverse Osmosis Desalination: Water Sources, Technology, and Today’s Challenges. Water Research, 43, 2317-2348.
http://dx.doi.org/10.1016/j.watres.2009.03.010

[30]   Kabay, N., Arar, O., Samatya, S., Yuksel, U. and Yuksel, M. (2008) Separation of Fluoride from Aqueous Solution by Electrodialysis: Effect of Process Parameters and Other Ionic Species. Journal of Hazardous Materials, 153, 107-113.
http://dx.doi.org/10.1016/j.jhazmat.2007.08.024

[31]   Simsons, R. (1993) Trace Element Removal from Ash Dam Waters by Nanofiltration and Diffusion Dialysis. Desalination, 89, 325-341.
http://dx.doi.org/10.1016/0011-9164(93)80145-D

[32]   Dhakal, R.P., Ghimire, K.N. and Inoue, K. (2005) Adsorptive Separation of Heavy Metals from an Aquatic Environment Using Orange Waste. Hydrometallurgy, 79, 182-190.
http://dx.doi.org/10.1016/j.hydromet.2005.06.007

[33]   Demirbas, A. (2008) Heavy Metal Adsorption onto Agro-Based Waste Materials: A Review. Journal of Hazardous Materials, 157, 220-229.
http://dx.doi.org/10.1016/j.jhazmat.2008.01.024

[34]   Alagumuthu, G. and Rajan, M. (2010) Equilibrium and Kinetics of Adsorption of Fluoride onto Zirconium Impregnated Cashew Nut Shell Carbon. Chemical Engineering Journal, 158, 451-457.
http://dx.doi.org/10.1016/j.cej.2010.01.017

[35]   Leyva-Ramos, R., Rivera-Utrilla, J., Medellincastillo, N.A. and Sanchez-Polo, M. (2010) Kinetic Modeling of Fluoride Adsorption from Aqueous Solution onto Bone Char. Chemical Engineering Journal, 158, 458-467.
http://dx.doi.org/10.1016/j.cej.2010.01.019

[36]   Biswas, B.K., Inoue, K., Ghimire, K.N., Ohta, S., Harada, H., Ohto, K. and Kawakita, H. (2007) The Adsorption of Phosphate from an Aquatic Environment Using Metal-Loaded Orange Waste. Journal of Colloid and Interface Science, 312, 214-223.
http://dx.doi.org/10.1016/j.jcis.2007.03.072

[37]   Biswas, B.K., Inoue, K. and Ghimire, K.N. (2008) Removal and Recovery of Phosphorus from Water by Means of Adsorption onto Orange Waste Gel Loaded with Zirconium. Bioresource Technology, 99, 8685-8690.
http://dx.doi.org/10.1016/j.biortech.2008.04.015

[38]   Chauhan, V.S., Dwivedi, P.K. and Iyengar, L. (2007) Investigations on Activated Alumina Based Domestic Defluoridation Units. Journal of Hazardous Materials, 139, 103-107.
http://dx.doi.org/10.1016/j.jhazmat.2006.06.014

[39]   American Public Health Association (2007) Standard Methods for the Examination of Water and Wastewater. 14th Edition, American Public Health Association, Washington DC.

 
 
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