Effects of Process Parameters on the Size of Nanostructure Magnesium Oxide Synthesized by a Surfactant and Ligand Assisted Wet Chemical Method

Yousef  Valizadeh; Parizad  Motamedara; Katayoun  Marjani; Amirmasoud  Sabourimanesh; Alimorad  Rashidi

doi:10.4236/csta.2015.42004

CSTA Vol.4 No.2 , June 2015

Effects of Process Parameters on the Size of Nanostructure Magnesium Oxide Synthesized by a Surfactant and Ligand Assisted Wet Chemical Method

Amirmasoud Sabourimanesh¹^*, Alimorad Rashidi², Katayoun Marjani¹, Parizad Motamedara¹, Yousef Valizadeh¹

Abstract: A surfactant and ligand assisted wet chemical method was employed for the preparation of nanostructure magnesium oxide with a high specific area and sphere-like nanoparticles. The influence of surfactants and ligands on the crystallite size and morphology of MgO was studied using various parameters. X-ray diffraction (XRD) studies show that the crystallite size varies. Observations with Field Emission Scanning Electron Microscopy (FFSEM) and Transmission Electron Microscopy (TEM) show that the ligands and surfactants strongly affect the size of nanostructure. We synthesized less than 15 nm using a PVA 72000 surfactant in the presence of EDA and 4-methyl morpholine ligands, 15 - 40 nm with a PVA 72000 surfactant in the presence of oleic acid, and more than 40 nm with a PEG 6000 surfactant. The effects of several process parameters, such as surfactant, ligand and solvent, were examined.

Keywords: Magnesium Oxide, Crystal Structure, Nanostructure, FESEM, XRD, Surfaces

Cite this paper: Sabourimanesh, A. , Rashidi, A. , Marjani, K. , Motamedara, P. and Valizadeh, Y. (2015) Effects of Process Parameters on the Size of Nanostructure Magnesium Oxide Synthesized by a Surfactant and Ligand Assisted Wet Chemical Method. Crystal Structure Theory and Applications, 4, 28-34. doi: 10.4236/csta.2015.42004.

References

[1] Su, Y., Wei, H., Zhou, Z., Yang, Z., Wei, L. and Zhang, Y. (2011) Rapid Synthesis and Characterization of Magnesium oxide Nanocubes via DC Arc Discharge. Materials Letters, 65, 100-103.

http://dx.doi.org/10.1016/j.matlet.2010.09.015

[2] Shen, G., Chen, P.C., Ryu, K. and Zhou, C. (2009) Devices and Chemical Sensing Applications of Metal Oxide Nanowires. Journal of Materials Chemistry, 19, 828-839.
http://dx.doi.org/10.1039/B816543B

[3] Comini, E., Baratto, C., Faglia, G., Ferroni, M., Vomiero, A. and Sberveglieri, G. (2009) Quasi-One Dimensional Metal Oxide Semiconductors: Preparation, Characterization and Application as Chemical Sensors. Progress in Materials Science, 54, 1-67.
http://dx.doi.org/10.1016/j.pmatsci.2008.06.003

[4] Takahashi, N. (2007) Simple and Rapid Synthesis of MgO with Nano-Cube Shape by Means of a Domestic Microwave Oven. Solid State Sciences, 9, 722-724.
http://dx.doi.org/10.1016/j.solidstatesciences.2007.05.007

[5] Kato, Y., Takahashi, F., Watanabe, A. and Yoshizawa, Y. (2001) Thermal Analysis of a Magnesium Oxide/Water Chemical Heat Pump for Cogeneration. Applied Thermal Engineering, 21, 1067-1081.

[6] Klug, K.L. and Dravid, V.P. (2002) Observation of Two- and Three-Dimensional Magnesium Oxide Nanostructures Formed by Thermal Treatment of Magnesium Diboride Powder. Applied Physics Letters, 81, 1687-1689.
http://dx.doi.org/10.1063/1.1502003

[7] Jüstel, T. and Nikol, H. (2000) Optimization of Luminescent Materials for Plasma Display Panels. Advanced Materials, 12, 527-530.
http://dx.doi.org/10.1002/(SICI)1521-4095(200004)12:7<527::AID-ADMA527>3.0.CO;2-8

[8] Zheng, B., Lu, C., Gu, G., Makarovski, A., Finkelstein, G. and Liu, J. (2002) Efficient CVD Growth of Single-Walled Carbon Nanotubes on Surfaces Using Carbon Monoxide Precursor. Nano Letters, 2, 895-898.
http://dx.doi.org/10.1021/nl025634d

[9] Wagner, G.W., Bartram, P.W., Koper, O. and Klabunde, K.J. (1999) Reactions of VX, GD, and HD with Nanosize MgO. The Journal of Physical Chemistry B, 103, 3225-3228.
http://dx.doi.org/10.1021/jp984689u

[10] Hao, Y., Meng, G., Ye, C., Zhang, X. and Zhang, L. (2005) Kinetics-Driven Growth of Orthogonally Branched Single- Crystalline Magnesium Oxide Nanostructures. The Journal of Physical Chemistry B, 109, 11204-11208.
http://dx.doi.org/10.1021/jp050545l

[11] Xu, B.Q., Wei, J.M., Wang, H.Y., Sun, K.Q. and Zhu, Q.M. (2001) Nano-MgO: Novel Preparation and Application as Support of Ni Catalyst for CO2 Reforming of Methane. Catalysis Today, 68, 217-225.
http://dx.doi.org/10.1016/S0920-5861(01)00303-0

[12] Xie, Y. and Yuan, C. (2003) Visible-Light Responsive Cerium Ion Modified Titania Sol and Nanocrystallites for X-3B Dye Photodegradation. Applied Catalysis B: Environmental, 46, 251-259.
http://dx.doi.org/10.1016/S0926-3373(03)00211-X

[13] Meshkani, F. and Rezaei, M. (2010) Effect of Process Parameters on the Synthesis of Nanocrystalline Magnesium Oxide with High Surface Area and Plate-Like Shape by Surfactant Assisted Precipitation Method. Powder Technology, 199, 144-148.
http://dx.doi.org/10.1016/j.powtec.2009.12.014

[14] Natter, H., Schmelzer, M., Lffler, M.S., Krill, C.E., Fitch, A. and Hempelmann, R. (2000) Grain-Growth Kinetics of Nanocrystalline Iron Studied in Situ by Synchrotron Real-Time X-Ray Diffraction. The Journal of Physical Chemistry B, 104, 2467-2476.
http://dx.doi.org/10.1021/jp991622d

[15] Zhang, J., Sun, L., Yin, J., Su, H., Liao, C. and Yan, C. (2002) Control of ZnO Morphology via a Simple Solution Route. Chemistry of Materials, 14, 4172-4177.
http://dx.doi.org/10.1021/cm020077h

[16] Straumal, B.B., Protasova, S.G., Mazilkin, A.A., Baretzky, B., Myatiev, A.A., Straumal, P.B., et al. (2012) Amorphous Interlayers between Crystalline Grains in Ferromagnetic ZnO Films. Materials Letters, 71, 21-24.
http://dx.doi.org/10.1016/j.matlet.2011.11.082

[17] Samodi, A., Rashidi, A., Marjani, K. and Ketabi, S. (2013) Effects of Surfactants, Solvents and Time on the Morphology of MgO Nanoparticles Prepared by the Wet Chemical Method. Materials Letters, 109, 269-275.
http://dx.doi.org/10.1016/j.matlet.2013.07.085

[18] Jung, H.S., Lee, J.K., Kim, J.Y. and Hong, K.S. (2003) Crystallization Behaviors of Nanosized MgO Particles from Magnesium Alkoxides. Journal of Colloid and Interface Science, 259, 127-132.
http://dx.doi.org/10.1016/S0021-9797(03)00034-1

[19] Chittofrati, A. and Matijevi, E. (1990) Uniform Particles of Zinc Oxide of Different Morphologies. Colloids and Surfaces, 48, 65-78.
http://dx.doi.org/10.1016/0166-6622(90)80219-T

[20] Kwon, Y.J., Kim, K.H., Lim, H.S. and Shim, K.B. (2002) J. of Ceram. Proc. Res, 3, 146-149.