GEP  Vol.3 No.3 , May 2015
Adsorption of Herbicide Butachlor in Cultivated Soils of Golestan Province, Iran
Abstract: Butachlor is a non-ionic herbicide that has been applied widely for agriculture, especially in paddy fields. Through batch equilibration experiments, the adsorption characteristics of butachlor were investigated in eight cultivated soil samples collected from Golestan Province, Iran. The data obtained from adsorption equilibrium experiments fitted the linear equation very well. Results showed that butachlor had weak to moderate adsorption capability in different soils. Trend of butachlor adsorption was similar to the order of abundance of organic carbon in the soils. The Gibbs free energy values were found negative and adsorption was spontaneous and exothermic in nature. Statistical analysis showed that organic carbon, CEC (cation exchange capacity), and the Rt ratio (ratio of TNV to organic matter content) were the more effective parameters governing butachlor retention and mobility in soils.
Cite this paper: Armanpour, S. and Bing, L. (2015) Adsorption of Herbicide Butachlor in Cultivated Soils of Golestan Province, Iran. Journal of Geoscience and Environment Protection, 3, 15-24. doi: 10.4236/gep.2015.33002.

[1]   Autio, S., Siimes, K., Laitinen, P., Ramo, S., Oinonen, S. and Eronen, L. (2004) Adsorption of Sugar Beet Herbicides to Finnish Soils. Chemosphere, 55, 215-226.

[2]   Kibe, K., Takahashi, M., Kameya, T. and Urano, K. (2000) Adsorption Equilibriums of Principal Herbicides on Paddy Soils in Japan. Science of the Total Environment, 263, 115-125.

[3]   Hernández, M., Villalobos, P., Morgante, V., González, M., Reiff, C., Moore, E. and Seeger, M. (2008) Isolation and Characterization of a Novel Simazine-Degrading Bacterium from Agricultural Soil of Central Chile, Pseudomonas sp. MHP41. FEMS Microbiology Letters, 286, 184-190.

[4]   Ateeq, B., Farah, M.A. and Ahmad, W. (2006) Evidence of Apoptotic Effects of 2,4-D and Butachlor on Walking Catfish, Clarias batrachus, by Transmission Electron Microscopy and DNA Degradation Studies. Life Science, 78, 977-986.

[5]   Geng, B.R., Yao, D. and Xue, Q.Q. (2005) Genotoxicity of the Pesticide Dichlorovos and Herbicide Butachlor in Rhacophorus Megacephal us tadpoles. Acta Zoologica Sinica (China), 51, 447-454.

[6]   Xu, D.P., Xu, Z.H., Zhu, S.Q., Cao, Y.Z., Wang, Y., Du, X.M., Gu, Q.B. and Li, F.S. (2005) Adsorption Behavior of Herbicide Butachlor on Typical Soils in China and Humic Acids from the Soil Samples. Journal of Colloid and Interface Science, 285, 27-32.

[7]   Yu, Y.L., Wu, X.M., Li, S.N., Fang, H., Zhan, H.Y. and Yu, J.Q. (2006) An Exploration of the Relationship between Adsorption and Bioavailability of Pesticides in Soil to Earthworm. Environmental Pollution, 141, 428-433.

[8]   Liu, Z., He, Y., Huang, P. and Jilani, G. (2008) The Ratio of Clay Content to Total Organic Carbon Content Is a Useful Parameter to Predict Adsorption of the Herbicide Butachlor in Soils. Environmental Pollution, 152, 163-171.

[9]   PPDB (2012) Pesticide Properties Database (PPDB) Developed by the Agriculture and Environment Research Unit, University of Hertfordshire, UK.

[10]   OECD (2000) OECD Guidelines for the Testing of Chemicals: Adsorption-Desorption Using a Batch Equilibrium Method. Organisation for Economic Co-operation and Development.

[11]   Liu, Y.H., Xu, Z.Z., Wu, X.G., Gui, W.J. and Zhu, G.N. (2010) Adsorption and Desorption Behavior of Herbicide Diuron on Various Chinese Cultivated Soils. Journal of Hazardous Materials, 178, 462-468.

[12]   Chiou, C.T., Potter, P.E. and Schmedding, D.W. (1983) Partition Equilibriums of Nonionic Organic Compounds between Soil Organic Matter and Water. Environmental Science & Technology, 17, 227-231.

[13]   Elshafei, G.S., Nasr, I.N., Hassan, A.S.M. and Mohammad, S.G.M. (2009) Kinetics and Thermodynamics of Adsorption of Cadusafos on Soils. Journal of Hazardous Materials, 172, 1608-1616.

[14]   Giles, C.H., MacEwan, T.H., Nakhwa, S.N. and Smith, D. (1960) Studies in Adsorption: Part XI. A System of Classification of Solution Adsorption Isotherms and Its Use in Diagnosis of Adsorption Mechanisms and in Measurement of Specific Surface Area Solids. Journal of the Chemical Society, 14, 3973-3993.

[15]   Wang, Q.Q., Yang, W.C. and Liu, W.P. (1999) Adsorption of Acetanilide Herbicides on Soils and Its Correlation with Soil Properties. Pesticide Science, 55, 1103-1108.
Welhouse, G.J. and Bleam, W.F. (1992) NMR Spectroscopic Investigation of Hydrogen Bonding in Atrazine. Environmental Science & Technology, 26, 959-964.

[16]   Sato, T., Kohnosu, S. and Hartwig, J.F. (1987) Adsorption of Butachlor to Soils. Journal of Agricultural and Food Chemistry, 35, 397-402.

[17]   Chiang, H.C., Yen, J.H. and Wang, Y.S. (1997) Sorption of Herbicides Butachlor, Thiobencarb, and Chlomethoxyfen in Soils. Bulletin of Environmental Contamination and Toxicology, 58, 758-763.

[18]   Flores, C., Morgante, V., González, M., Navia, R. and Seeger, M. (2009) Adsorption Studies of the Herbicide Simazine in Agricultural Soils of the Aconcagua Valley, Central Chile. Chemosphere, 74, 1544-1549.

[19]   Bromilow, R.H. (2005) Pesticides. In: Hillel, D., Rosenzweig, C., Powlson, D., Scow, K., Singer, M. and Sparks, D., Eds., Encyclopedia of Soils in the Environment, Vol. 3, Elsevier Ltd., Amsterdam, 188-195.

[20]   Yousefi Falakdehi, O., Golparvar, Gh., Safdel, H. and Lasht Neshayi, A. (2012) Investigation of Water Pollution in Zilki Rood in Gilan Province. Iran Water Research Journal, 10, 6. (In Persian)

[21]   Arshad, U., Aliakbar, A., Sadeghi, M., Jamalzad, F. and Chubian, F. (2006) Pesticide (Diazinon and Butachlor) Monitoring in Waters of the Shahid Beheshti Sturgeon Hatchery, Rasht, Iran. Journal of Applied Ichthyology, 22, 231-233.

[22]   European Union (2000) Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 Establishing a Framework for Community Action in the Field of Water Policy. Official Journal of the European Communities, 327, 1-72.

[23]   Horsfall, M., Spiff, A.I. and Abia, A.A. (2004) Studies on the Influence of Mercaptoacetic Acid (MAA) Modification of Cassava (Manihot sculenta Cranz) Waste Biomass on the Adsorption of Cu2+ and Cd2+ from Aqueous Solution. Bulletin of the Korean Chemical Society, 25, 969-976.

[24]   Hollis, J.M. (1991) Mapping the Vulnerability of Aquifers and Surface Waters to Pesticide Contamination at the National/Regional Scale. In: Walker, A., Ed., Pesticides in Soils and Water, BCPC Monograph, Vol. 47, National Soil Resources Institute, Cranfield University, Silsoe, 165-174.

[25]   Spurlock, F. and Biggar, J.W. (1994) Thermodynamics of Organic Chemical Partition in Soils. 2. Nonlinear Partition of Substituted Phenylureas from Aqueous Solution. Environmental Science & Technology, 28, 996-1002.

[26]   Tang, Z.W., Zhang, W. and Chen, Y.M. (2009) Adsorption and Desorption Characteristics of Monosulfuron in Chinese Soils. Journal of Hazardous Materials, 166, 1351-1356.

[27]   Theng, B.K.G. (1974) The Chemistry of Clay-Organic Reactions. John Wiley and Sons, New York.

[28]   El Arfaoui, A., Sayen, S., Marceau, E., Stievano, L., Guillon, E. and Couderchet, M. (2009) Relationship between Soil Composition and Retention Capacity of Terbumeton onto Chalky Soils. Environmental Chemistry, 6, 245-252.

[29]   Dubus, I.G., Barriuso, E. and Calvet, R. (2001) Sorption of Weak Organic Acids in Soils: Clofencet, 2,4-D and Salicylic Acid. Chemosphere, 45, 767-774.

[30]   Kovaios, I.D., Paraskeva, C.A., Koutsoukos, P.G. and Payatakes, A.C. (2006) Adsorption of Atrazine on Soils: Model Study. Journal of Colloid and Interface Science, 299, 88-94.

[31]   El Arfaoui, A., Sayen, S., Paris, M., Keziou, A., Couderchet, M. and Guillon, E. (2012) Is Organic Matter Alone Sufficient to Predict Isoproturon Sorption in Calcareous Soils? Science of the Total Environment, 432, 251-256.