AJAC  Vol.6 No.3 , February 2015
Crystal Structure of ZnCl3 (Methyl-(2-Pyridin-2-yl-Ethyl)-Ammonium)
Abstract: A new Zn(II) complex with the monodentate ligand methyl-(2-pyridin-2-yl-ethyl)-ammonium, ZnCl3C8H13N2, has been prepared and characterized by single crystal X-ray diffraction. The Zn(II) ion is tetracoordinated by one nitrogen atom of organic ligand and three chlorine ligands. In the atomic arrangement, the ZnNCl3 tetrahedra form corrugated chains extending along the b-axis. The organic entities are located between these chains through N-H···Cl, C-H···Cl and C-H···N hydrogen bonds to form layers parallel to (b, c) plan. Among these hydrogen bonds two are bifurcated.
Cite this paper: Ben Nasr, M. , Jeanneau, E. and Ben Nasr, C. (2015) Crystal Structure of ZnCl3 (Methyl-(2-Pyridin-2-yl-Ethyl)-Ammonium). American Journal of Analytical Chemistry, 6, 189-195. doi: 10.4236/ajac.2015.63017.

[1]   Dybtsev, D.N., Chun, H., Yoon, S.H., Kim, D. and Kim, K. (2004) Microporous Manganese Formate: A Simple Metal-Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties. Journal of the American Chemical Society, 126, 32-33.

[2]   Smith, D.W. (1976) Chlorocuprates(II). Coordination Chemistry Reviews, 21, 93-158.

[3]   Ye, B.H., Chem, X.M., Xue, G.Q. and Ji, L.N. (1998) Mononuclear Nickel Complexes Assembled into Two-Dimensional Networks via Hydrogen Bonds and π-π Stacking Interactions. Journal of the Chemical Society, Dalton Transactions, 17, 2827-2832.

[4]   Sorenson, J.R.J. (1976) Copper Chelates as Possible Active Forms of the Antiarthritic Agents. Journal of Medicinal Chemistry, 19, 135-148.

[5]   May, P.M. and Williams, D.R. (1981) Role of Low Molecular Weight Copper Complexes in the Control of Rheumatoid Arthritis. In: Metal Ions in Biological Systems, Vol. 12, Helmut Sigel, New York, 283-317.

[6]   Subramanian, P.S. and Srinivas, D. (1996) Synthesis, Spectral Characterization and Magnetic Properties of Dicarboxylato-Bridged Dinuclear Copper(II) Complexes with n-Pyridylsalicylidenaminato Ligand. Polyhedron, 15, 985-989.

[7]   Kaabi, K., El Glaoui, M., Zeller, M. and Ben Nasr, C. (2010) Diaquabis(Perchlorato)(1,10-Phenanthroline)Copper(II). Acta Crystallographica, E66, m1145-m1146.

[8]   Sheldrick, G.M. and SHELXS86 (1986) Program for Crystal Structure solution. Acta Crystallographica, A24, 351-359.

[9]   Betteridge, P.W., Carruthers, J.R., Cooper, R.I., Prout, K. and Watkin, D.J. (2003) CRYSTALS Version 12: Software for Guided Crystal Structure Analysis. Journal of Applied Crystallography, 36, 1487.

[10]   Brandenburg, K. (1998) Diamond Version 2.0 Impact GbR. Bonn, Germany.

[11]   Macrae, C.F., Bruno, I.J., Chisholm, J.A., Edgington, P.R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. and Wood, P.A. (2008) New Features for the Visualization and Investigation of Crystal Structures. Journal of Applied Crystallography, 41, 466-470.

[12]   Chen, X.-F., Liu, S.-H., Zhu, X.-H., Vittal, J.J., Tan, E.-K. and You, X.-Z. (2000) 4,4’-Bipyridine-N: N-Bis[bis(pyrrilidine-dithiocarboxylato-S,S’)zinc(II). Acta Crystallographica, C56, 42-43.

[13]   Hou, J.-J. and Zhang, X.-M. (2006) Structures and Magnetic Properties of a Series of Metal Phosphonoacetates Synthesized from in Situ Hydrolysis of Triethyl Phosphonoacetate. Crystal Growth & Design, 6, 1445-1452.

[14]   Smolenaers, P.J., Beattie, J.K. and Hutchinson, N.D. (1981) Crystal and Molecular Structure of Racemic Tris(Ethylene-diamine)Ruthenium(II) Tetrachlorozincate(II). Inorganic Chemistry, 20, 2202-2206.

[15]   Gahan, L.R., Hambley, T.W., Sargeson, A.M. and Snow, M.R. (1982) Encapsulated Metal Ions: Synthesis, Structure, and Spectra of Nitrogen-Sulfur Ligand Atom Cages Containing Cobalt(III) and Cobalt(II). Inorganic Chemistry, 21, 2699-2706.

[16]   Chen, W.-T., Liu, D.-S., Ying, S.-M., Chen, H.-L. and Xu, Y.-P. (2008) ZnCl3(4-Methyl-4,4-Bipyridinium) with 4-Methyl- 4,40-Bipyridinium Generated in Situ: Synthesis, Structure and Photoluminescence. Inorganic Chemistry Communications, 11, 1212-1214.