FTIR and Raman Studies of Cellulose Fibers of Luffa cylindrica
Affiliation(s)
1 Depatment of Physics, Orissa University of Agriculture and Technology, Bhubaneswar, India. 2 Department of Education in Science and Mathematics, National Council of Educational Research and Training, Bhubaneswar, India. 3 Post Graduate Department of Botany, Vani Vihar, Utkal University, Bhubaneswar, India.
1 Depatment of Physics, Orissa University of Agriculture and Technology, Bhubaneswar, India. 2 Department of Education in Science and Mathematics, National Council of Educational Research and Training, Bhubaneswar, India. 3 Post Graduate Department of Botany, Vani Vihar, Utkal University, Bhubaneswar, India.
ABSTRACT
In view of biomedical applications of cellulose fibers in orthopedics, dentistry and reconstructive surgery, Luffa cylindrica (LC), a local forest product of Orissa, India, has been used for preparation of alkali treated LC fiber modified with calcium carbonate and calcium phosphate separately by following standard procedures. FTIR and Raman spectra were obtained for these samples at wavelength range 500 - 4000 cm–1 and 300 - 3000 cm–1 respectively. Lattice structures of cellulose i.e., crystalline cellulose and amorphous cellulose were detected using Raman spectroscopy and discussed. The property of cellulose such as its degree of crystallinity was determined from intensity of FT IR peaks and was found to be 74.12%. The presence of calcite and hydroxy apatite, polymorphs of calcium carbonate and calcium phosphate respectively were confirmed in the treated modified LC fibers which can be used as bioactive materials.
In view of biomedical applications of cellulose fibers in orthopedics, dentistry and reconstructive surgery, Luffa cylindrica (LC), a local forest product of Orissa, India, has been used for preparation of alkali treated LC fiber modified with calcium carbonate and calcium phosphate separately by following standard procedures. FTIR and Raman spectra were obtained for these samples at wavelength range 500 - 4000 cm–1 and 300 - 3000 cm–1 respectively. Lattice structures of cellulose i.e., crystalline cellulose and amorphous cellulose were detected using Raman spectroscopy and discussed. The property of cellulose such as its degree of crystallinity was determined from intensity of FT IR peaks and was found to be 74.12%. The presence of calcite and hydroxy apatite, polymorphs of calcium carbonate and calcium phosphate respectively were confirmed in the treated modified LC fibers which can be used as bioactive materials.
Cite this paper
Parida, C. , Dash, S. and Pradhan, C. (2015) FTIR and Raman Studies of Cellulose Fibers of Luffa cylindrica. Open Journal of Composite Materials, 5, 5-10. doi: 10.4236/ojcm.2015.51002.
Parida, C. , Dash, S. and Pradhan, C. (2015) FTIR and Raman Studies of Cellulose Fibers of Luffa cylindrica. Open Journal of Composite Materials, 5, 5-10. doi: 10.4236/ojcm.2015.51002.
References
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http://dx.doi.org/10.1002/anie.200390160 [6] Yang, L., Perez-Amodio, S., Barrère-de Groot, F.Y., Everts, V., van Blitterswijk, C.A. and Habibovic, P. (2010) The Effects of Inorganic Additives to Calcium Phosphate on in Vitro Behavior of Osteoblasts and Osteoclasts. Biomaterials, 31, 2976-2989. [7] Herrea-Franco, P.J. and Valadez-Gonzalez, A. (2005) A Study of the Mechanical Properties of Short Natural-Fiber Reinforced Composites. Composites Part B, 36, 597-608. [8] Ciolain, D., Ciolain, F. and Popa, V.I. (2011) Amorphous Cellulose—Structure and Characterization. Cellulose Chemistry and Technology, 45, 13-21. [9] Schenzel, K. and Fischer, S. (2004) Applications of FT Raman for the Characterization of Cellulose. Lenzinzer Berichte, 83, 64-70. [10] Li, L.C. (2007) Identification of Textile Fiber by Raman Microspectroscopy. Forensic Science Journal, 6, 55-62. [11] Mazali, I.O. and Alves, O.L. (2005) Morphosynthesis: High Fidelity Inorganic Replica of the Fibrous Network of Luffa cylindrica. Annals of the Brazilian Academy of Sciences, 77, 25-31. [12] D.K. Pattanyak, Divya P, Sujal Upadhaya, (2005) Synthesis and Evolution of Hydroxyl Apatite Ceramics. Trends in Biomaterials and Artificial Organs, 18, 169-175.
[1] Kumar, G.S., Girija, E.K., Thamizhavel, A., Yokogawa, Y. and Kalkura, S.N. (2010) Synthesis and characterization of Bioactive Hydroxyapatite-Calcite Nanocomposite for Biomedical Applications. Journal of Colloid and Interface Science, 349, 56-62. [2] Preve, P.S. (2000) X-Ray Diffraction Characterization of Crystallinityu and Phase Composition in Plasma Sprayed Hydroxyl Apatite Coatings. Journal of Thermal Spray Technology, 9, 369-376. [3] Walsh, D., Lebeau, B. and Mann, S, (1999) Morphosynthesis of Calcium Carbonate (Vaterite) Microsponges. Advanced Materials, 11, 324-328. [4] Hall, S.R., Bolger, H. and Mann, S. (2003) Morphosynthesis of Complex Inorganic Forms Using Pollen Grain Templates. Chemical Communications, 22, 2784-2785. [5] Cook, G., Timms, P.L. and Spickermann, C.G. (2003) Exact Replication of Biological Structures by Chemical Vapor Deposition of Silica. Angewandte Chemie International Edition, 42, 557-559.
http://dx.doi.org/10.1002/anie.200390160 [6] Yang, L., Perez-Amodio, S., Barrère-de Groot, F.Y., Everts, V., van Blitterswijk, C.A. and Habibovic, P. (2010) The Effects of Inorganic Additives to Calcium Phosphate on in Vitro Behavior of Osteoblasts and Osteoclasts. Biomaterials, 31, 2976-2989. [7] Herrea-Franco, P.J. and Valadez-Gonzalez, A. (2005) A Study of the Mechanical Properties of Short Natural-Fiber Reinforced Composites. Composites Part B, 36, 597-608. [8] Ciolain, D., Ciolain, F. and Popa, V.I. (2011) Amorphous Cellulose—Structure and Characterization. Cellulose Chemistry and Technology, 45, 13-21. [9] Schenzel, K. and Fischer, S. (2004) Applications of FT Raman for the Characterization of Cellulose. Lenzinzer Berichte, 83, 64-70. [10] Li, L.C. (2007) Identification of Textile Fiber by Raman Microspectroscopy. Forensic Science Journal, 6, 55-62. [11] Mazali, I.O. and Alves, O.L. (2005) Morphosynthesis: High Fidelity Inorganic Replica of the Fibrous Network of Luffa cylindrica. Annals of the Brazilian Academy of Sciences, 77, 25-31. [12] D.K. Pattanyak, Divya P, Sujal Upadhaya, (2005) Synthesis and Evolution of Hydroxyl Apatite Ceramics. Trends in Biomaterials and Artificial Organs, 18, 169-175.