Synthesis of the Palladium Catalyst with the Supercritical СO2-Impregnation Method Realized in the Static Mode
Affiliation(s)
1 Federal State Budgetary Educational Institution of Higher Professional Education “Kazan National Research Technological University”, Kazan, Russia. 2 Technological University, Baghdad, Iraq.
1 Federal State Budgetary Educational Institution of Higher Professional Education “Kazan National Research Technological University”, Kazan, Russia. 2 Technological University, Baghdad, Iraq.
ABSTRACT
Results of research of supercritical fluid CO2-impregnation process (the static mode) within a problem of synthesis of the palladium catalyst are given. The kinetics of process is characterized in the pressure range from 15.0 to 35.0 MPa on temperatures 308.15?K, 313.15?K, 318.15?K, 323.15?K, 328.15?K and 333.15?K. Results of surface assessment and activity measurements of the catalyst samples synthesized by supercritical СO2-impregnation of aluminum oxide suggest competitiveness of the discussed approach in comparison to traditional methods.
Results of research of supercritical fluid CO2-impregnation process (the static mode) within a problem of synthesis of the palladium catalyst are given. The kinetics of process is characterized in the pressure range from 15.0 to 35.0 MPa on temperatures 308.15?K, 313.15?K, 318.15?K, 323.15?K, 328.15?K and 333.15?K. Results of surface assessment and activity measurements of the catalyst samples synthesized by supercritical СO2-impregnation of aluminum oxide suggest competitiveness of the discussed approach in comparison to traditional methods.
Cite this paper
Zakharov, A. , Jaddoa, A. , Bilalov, T. and Gumerov, F. (2014) Synthesis of the Palladium Catalyst with the Supercritical СO2-Impregnation Method Realized in the Static Mode. International Journal of Analytical Mass Spectrometry and Chromatography, 2, 113-122. doi: 10.4236/ijamsc.2014.24010.
Zakharov, A. , Jaddoa, A. , Bilalov, T. and Gumerov, F. (2014) Synthesis of the Palladium Catalyst with the Supercritical СO2-Impregnation Method Realized in the Static Mode. International Journal of Analytical Mass Spectrometry and Chromatography, 2, 113-122. doi: 10.4236/ijamsc.2014.24010.
References
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[1] Boreskov, G.K. (1986) Heterogeneous Catalysis. M .: Nauka. 298 C. [2] (2006) The Ethylene Production in the CIS: The Reactors and Catalysts. http://www.newchemistry.ru/letter.php?n_id=105&cat_id=5 [3] Muhlenov, I.P., Dopkina, E.I., Deryuzhina, V.I. and Soroko, V.E. (1989) Catalysts Technology. L .: Chemistry, 272 p. [4] McHugh, M.A. and Krukonis, V.J. (1994) Supercritical Fluids Extraction: Principles and Practice. 2nd Edition, Butterworth-Heinemann, Oxford, 507 p. [5] Gumerov, F.M., Sabirzyanov, A.N. and Gumerova, G.I. (2000) Sub- and Supercritical Fluids in Polymer Processing. Science, Kazan, 328 p. [6] Chernyshev, A.K., Gumerov, F.M. and Tsvetinsky, G.N. (2013) Carbon Dioxide. Galley Print, Moscow, 903. [7] Johnston, K.P., et al. (1989) New Direction in Supercritical Fluid Science and Technology. In: Supercritical Fluid Sci- ence and Technology. ACS Symposium Series, American Chemical Society City, Washington DC, Chapter l, 1-12. http://dx.doi.org/10.1021/bk-1989-0406.ch001 [8] Cansell, F. and Petitet, J.-P. (1995) Fluides Supercritiques et Materiaux. LIMHP CNRS, 372 p. [9] Bilalov, T.R., Gumerov, F.M., Gabitov, F.R., Kharlampidi, Kh.E., Fedorov, G.I., Sagdeev, A.A., Yarullin, R.S. and Yakushev, I.A. (2009) The Synthesis and Regeneration of Palladium Catalysts with the Use of Supercritical Carbon Dioxide. Russian Journal of Physical Chemistry B, 3, 80-92. http://dx.doi.org/10.1134/S1990793109070094 [10] Gallyamov, R.F., Sagdeev, A.A., Gumerov, F.M. and Gabitov, F.R. (2010) Regeneration of a “Nickel on Kieselguhr” Catalyst by Means of Supercritical Carbon Dioxide. Russian Journal of Physical Chemistry B, 3, 23-30. [11] Gumerov, F.M., Sagdeev, A.A., Gallyamov, R.F., Galimova, A.T. and Sagdeev, K.A. (2014) Regeneration of the Catalysts by Supercritical Fluid Extraction. International Journal of Analytical Mass Spectrometry and Chromatography, 2, 1-14. [12] Sagdeev, K.A., Sagdeev, A.A. Gumerov, F.M. and Gallyamov, R.F. (2014) Investigation of the Process of Regeneration Alyuminium-Palladium Catalyst by Supercritical Fluid Extraction. Proceedings of the Universities. Series: Chemistry and Chemical Technology, 8, 64-67. [13] Garrido, G.I., Patcas, F.C., Upper, G., Turk, M., Yilmaz, S. and Kraushaar-Czarnetzki, B. (2008) Supercritical Deposition of Pt on SnO2-Coated Al2O3 Foams: Phase Behaviour and Catalytic Performance. Applied Catalysis A: General, 338, 58-65. http://dx.doi.org/10.1016/j.apcata.2007.12.019 [14] Gopalan, A.S., Wai, C.M. and Jacobs, H.K. (2003) Supercritical Carbon Dioxide. Separations and Processes. ACS Symposium Series 860, American Chemical Society, Washington DC, 479. [15] Amirhanov, D.G., Gumerov, F.M., Sagdeev, A.A. and Galimova, A.T. (2014) Solutes in the Supercritical Fluid Media. Otechestvo, Kazan, 264 R. [16] Bilalov, T.R. and Gumerov, F.M. (2011) The Manufacturing Processes and Catalyst Regeneration, Thermodynamic Basis of Production Processes and Regeneration of Palladium Catalysts Using Supercritical Carbon Dioxide. LAP LAMBERT Academic Publishing GmbH & Co. KG., Dudweiler Landstr, 153 p. [17] Kharash, M.S., Seyler, R.C. and Mayo, F.R. (1938) Co?rdination Compounds of Palladous Chloride. Journal of the American Chemical Society, 60, 882-884. http://dx.doi.org/10.1021/ja01271a035 [18] Mukhopadhyay, M. (2000) Natural Extracts Using Supercritical Carbon Dioxide. CRC Press, Boca Raton, 339 p. http://dx.doi.org/10.1201/9781420041699 [19] Gumerov, F.M., Farakhov, M.I., Khayrutdinov, V.F., Gabitov, F.R., Zaripov, Z.I., Khabriyev, I.S. and Akhmetzyanov, T.R. (2014) Impregnation of Crushed Stone with Bitumenous Compounds Using Propane Butane Impregnation Process Carried out in Supercritical Fluid Conditions. American Journal of Analytical Chemistry, 5, 945-956.