JEP  Vol.5 No.17 , December 2014
Evaluation of Some Radioactive Materials and Heavy Metals in Marine Environment of Alexandria Coastline, Egypt
Abstract: The present work is carried out to obtain quantitative information of some natural radioactive materials and heavy metals in water and sediment samples along the Alexandria Coastline, as a step to construct the baseline map of the background radioactivity level in the Egyptian environment and also as a base data to assess the future physicochemical changes of surface coastal water and sediment in the studied area. The distribution of natural gamma emitting radionuclides such as 238U, 232Th and 40K has been established by gamma spectrometry. The results show that the area of Alexandria coast is affected by the existence of high back-ground radiation from the Rashid coast at the eastern side which has high levels of radioisotope concentrations due to black sand deposits which are dominant in this area. The absorbed dose rate (D, nGy·h-1), annual effective dose equivalent, external hazard index (Hex) and representative level index (Ir) of the investigated radioactive materials were calculated. The concentration of Pb2+, Cd2+, Ni2+, Mn2+, Cu2+, Co2+, Zn2+ and Cr3+ ions has been determined using Atomic Absorption Spectroscopy. The total dissolved solids (TDS) in water samples ranged from 33,000 mg/l to 42,000 mg/l, the salinity ranged from 37.9% to 40.5% and pH ranged from 7.6 to 7.9. Some of the sediment quality guidelines are calculated and they are the metal pollution index (MPI), the contamination factor (CF), degree of contamination (Cdeg), and Pollution load index (PLI).
Cite this paper: Atta, E. and Zakaria, K. (2014) Evaluation of Some Radioactive Materials and Heavy Metals in Marine Environment of Alexandria Coastline, Egypt. Journal of Environmental Protection, 5, 1618-1629. doi: 10.4236/jep.2014.517153.

[1]   Ibrahiem, N.M., Abd El Ghani, A.H., Shawky, E.M., Ashraf, E.M. and Farouk, M.A. (1993) Measurement of Radioactivity Levels in Soil in the Nile Delta and Middle Egypt. Health Physics, 64, 620-627.

[2]   Ibrahiem, N.M., Shawky, S. and Amer, H.A. (1995) Radioactivity Levels in Lake Nasser Sediments. Applied Radiation and Isotopes, 46, 297-299.

[3]   Hu, Q.H., Weng, J.Q. and Wang, J.S. (2010) Sources of Anthropogenic Radionuclides in the Environment: A Review. Journal of Environmental Radioactivity, 101, 426-437.

[4]   Hong, C. and Haux, C. (2008) Binding and Detoxification of Heavy Metals in Lower Vertebrates with Reference to Metallothionein. Comparative Biochemistry and Physiology: Part C, 100, 137.

[5]   Wang, J.J., Wang, C.J., Laiand, S.Y. and Lin, Y.M. (1998) Radioactivity Concentrations of 137Cs and 40K in Basidiomycetes Collected in Taiwan. Applied Radioactivity and Isotopes, 49, 29-34.

[6]   Shobier, A.H., Abdel Ghani, S.A. and Shreadah, M.A. (2011) Distribution of Total Mercury in Sediments of Four Semi-Enclosed Basins along the Mediterranean Coast of Alexandria. Egyptian Journal of Aquatic Research, 37, 1.

[7]   Yu, R.L., Yuan, X., Zhao, Y.H., Hu, G.R. and Tu, X.L. (2008) Heavy Metal Pollution in Intertidal Sediments from Quanzhou Bay, China. Journal of Environmental Sciences, 20, 664-669.

[8]   DeForest, D., Brix, K. and Adams, W. (2011) Assessing Metal Bioaccumulation in Aquatic Environments: The Inverse Relationship between Bioaccumulation Factors, Trophic Transfer Factors and Exposure Concentration. Aquatic Toxicology, 84, 236.

[9]   Fu, F. and Wang, Q. (2011) Removal of Heavy Metal Ions from Wastewaters: A Review. Journal of Environmental Management, 92, 407.

[10]   United Nations Scientific Committee on the Effects of Atomic Radiation (2000) Sources, Effects and Risks of Ionizing Radiation, Report to the General Assembly, with Annexes. United Nations, New York.

[11]   Oliveira Ribeiro, C.A., Schatzmann, M., Silva de Assis, H.C., Silva, P.H., Pelletier, E. and Akaishi, F.M. (2002) Evaluation of Tributyltin Subchronic Effects in Tropical Freshwater Fish (Astyanax bimaculatus, Linnaeus, 1758). Ecotoxicology and Environmental Safety, 51, 161-167.

[12]   Damek-Proprawa, M. and Sawicka-Kapusta, K. (2003) Damage to the Liver, Kidney and Testis with Reference to Burden of Heavy Metals in Yellow-Necked Mice from Areas around Steelworks and Zinc Smelters in Poland. Toxicology, 186, 1-10.

[13]   Hosono, T., Su, C., Delinom, R., Umezawa, Y., Toyota, T., Kaneko, S. and Taniguchi, M. (2011) Decline in Heavy Metal Contamination in Marine Sediments in Jakarta Bay, Indonesia Due to Increasing Environmental Regulations. Estuarine, Coastal and Shelf Science, 92, 297-306.

[14]   (1986) Annual Book of American Society for Testing and Materials. Soil Sampling. Vol. 11, 1.

[15]   APHA (American Public Health Association) (1995) Standard Methods for the Examination of Water and Waste Water. 19th Edition, Washington DC.

[16]   Perin, G., Fabris, R., Manente, S., Rebello Wagener, A., Hamacher, C. and Scotto, S. (1997) A Five-Year Study on the Heavy Metal Pollution of Guanabara Bay Sediments (Rio de Janeiro, Brazil) and Evaluation of the Metal Bioavailability by Means of Geochemical Speciation. Water Research, 31, 3017-3028.

[17]   IAEA. International Atomic Energy Agency (2004) Sediment Distribution Coefficients and Concentration Factors for Biota in the Marine Environment. Technical Report Series, International Atomic Energy Agency, Vienna.

[18]   Papaefthymiou, H. and Psichoudaki, M. (2008) Natural Radioactivity Measurements in the City of Ptolemais (Northern Greece). Journal of Environmental Radioactivity, 99, 1011-1017.

[19]   Keyser, R.M. (1995) Characterization and Applicability of Low-Background Germanium Detectors. Technical Note, EG&G ORTEC, Oak Ridge.

[20]   Hayumbu, P., Zaman, M.B., Lubaba, N.C.H., Munsanje, S.S. and Muleya, D. (1995) Natural Radioactivity in Zambian Building Materials Collected from Lusaka. Journal of Radioanalytical and Nuclear Chemistry, 199, 229-238.

[21]   Tarazona, J.V., Munoz, M.J., Carbonell, G., Carballo, M., Ortiz, J.A. and Castano, A. (1991) A Toxicological Assessment of Water Pollution and Its Relationship to Aquaculture in Algeciras Bay, Cadiz, Spain. Archives of Environmental Contamination and Toxicology, 20, 480-487.

[22]   Mohapatra, S.P. (1988) Distribution of Heavy Metals in Polluted Creek Sediment. Environmental Monitoring and Assessment, 10, 157-163.

[23]   Seshan, B.R.R., Natesan, U. and Deepthi, K. (2010) Geochemical and Statistical Approach for Evaluation of Heavy Metal Pollution in Core Sediments in Southeast Coast of India. International Journal of Environmental Science & Technology, 7, 291-306.

[24]   Loska, K., Cebula, J., Pelczar, J., Wiechua, D. and Kwapulinski, J. (1997) Use of Enrichment, and Contamination Factors Together with Geoaccumulation Indexes to Evaluate the Content of Cd, Cu, and Ni in the Rybnik Water Reservoir in Poland. Water, Air, and Soil Pollution, 93, 347-365.

[25]   Hakanson, L. (1980) An Ecological Risk Index for Aquatic Pollution Control a Sedimentological Approach. Water Research, 14, 975-1001.

[26]   Tomlinson, D.C., Wilson, J.G., Harris, C.R. and Jeffrey, D.W. (1980) Problems in Assessment of Heavy Metal Levels in the Estuaries and the Formation of Pollution Index. Helgolander Meeresuntersuchungen, 33, 566-575.

[27]   Chakravarty, M. and Patgiri, A.D. (2009) Metal Pollution Assessment in Sediments of the Dikrong River, NE India. Journal of Human Ecology, 27, 63-67.

[28]   Papachristodoulou, C.A., Assimakopoulos, P.A., Patronis, N.E. and Loannides, K.G. (2003) Use of HPGe γ-Ray Spectrometry to Assess the Isotopic Composition of Uranium in Soils. Journal of Environmental Radioactivity, 64, 195-203.

[29]   IAEA (2004) Predisposal Management of Organic Radioactive Waste. Technical Reports Series No. 427, Vienna.

[30]   United Nations Scientific Committee on the Effects of Atomic Radiation (2000) Sources, Effects and Risks of Ionizing Radiation, Report to the General Assembly, with Annexes. United Nations, New York.