ENG  Vol.6 No.13 , December 2014
Experimental Study and Thermodynamic Analysis of High Temperature Interactions between Boron Carbide and Liquid Metals
Abstract
Fabrication of MCCs (Metal Ceramic Composites) and ceramic brazing requires improved wetting properties are often absent in various ceramic/metals systems. This report summarizes a comprehensive study concerning the wetting properties of boron carbide in contact with non-reactive metals such as Cu, Au, Ag, and Sn. In order to improve wetting, three different reactive elements were added to the melts; Si, which has relatively high affinity to C, leads to SiC formation and changes the stoichiometric boron carbide composition (B4C) towards lower carbon content; Ti, which displays high affinity to B, leads to TiB2 formation and free carbon precipitation at the interface; and finally, Al, which forms borocarbide phases at the interface. It was found that Cu is unusual with respect to boron carbide compared the other non-reactive metals. The most important difference is its ability to dissolve ~25 at% of B, which makes B adequate as an additive to Cu in addition to Si, Ti, and Al. When boron was used as an alloying element, its effect on wetting behavior was attributed to altering the boron carbide composition in contact with boron-containing melts. It was concluded that the most important properties of boron carbide that affect wetting phenomena are the relatively low chemical stability and the existence of a wide composition range (B4C-B10C). The first property determines the possibility of boron carbide to react with liquid metals (by dissolution or formation of new phases) and the second offers an additional degree of freedom to improve its wetting by changing the composition of the ceramic phase.

Cite this paper
Aizenshtein, M. , Froumin, N. and Frage, N. (2014) Experimental Study and Thermodynamic Analysis of High Temperature Interactions between Boron Carbide and Liquid Metals. Engineering, 6, 849-868. doi: 10.4236/eng.2014.613079.
References

[1]   Halverson, D.C., Pyzik, A.J., Aksay, I.A. and Snowden, W.E. (1989) Processing of Boron Carbide-Aluminum Composites. Journal of the American Ceramic Society, 72, 775-780.
http://dx.doi.org/10.1111/j.1151-2916.1989.tb06216.x

[2]   Jung, J. and Kang, S. (2004) Advances in Manufacturing Boron Carbide-Aluminum Composites. Journal of the American Ceramic Society, 87, 47-54.
http://dx.doi.org/10.1111/j.1551-2916.2004.00047.x

[3]   Toptan, F., Kilicarslan, A., Karaaslan, A., Cigdem, M. and Kerti, I. (2010) Processing and Microstructural Characterisation of AA 1070 and AA 6063 Matrix B4Cp Reinforced Composites. Materials & Design, 31, S87-S91.
http://dx.doi.org/10.1016/j.matdes.2009.11.064

[4]   Lin, Q. and Sui, R. (2013) Wetting of B4C by Molten Ni at 1753 K. Journal of Alloys and Compounds, 556, 274-279.

[5]   Lin, Q. and Sui, R. (2013) Wetting of B4C by Molten Ni-Ti Alloys at 1753 K. Journal of Alloys and Compounds, 577, 37-43.
http://dx.doi.org/10.1016/j.jallcom.2013.04.164

[6]   Li, J.G. (1994) Wetting of Ceramic Materials by Liquid Silicon, Aluminium and Metallic Melts Containing Titanium and Other Reactive Elements: A Review. Ceramics International, 20, 391-412.

[7]   Eustathopoulos, N., Nicholas, M.G. and Devet, B. (1999) Wettability at High Temperatures. Pergamon Materials Series, Oxford.

[8]   Delannay, F., Froyen, L. and Deruyttere, A. (1986) The Wetting of Solids by Molten Metals and Its Relation to the Preparation of Metal-Matrix-Composites. Journal of Materials Science, 22, 1-16.
http://dx.doi.org/10.1007/BF01160545

[9]   Liu, G.W., Muolo, M.L., Valenza, F. and Passerone, A. (2010) Survey on Wetting of SiC by Molten Metals. Ceramics International, 36, 1177-1188.
http://dx.doi.org/10.1016/j.ceramint.2010.01.001

[10]   Marin, J., Olivares, L., Ordonez, S. and Martinez, V. (2003) Wetting of Silicon Carbide by Cu-Si Alloys. Materials Science Forum, 416-418, 487-492.
http://dx.doi.org/10.4028/www.scientific.net/MSF.416-418.487

[11]   Rado, C., Kalogeropoulou, S. and Eustathopoulos, N. (2000) Bonding and Wetting in Non Reactive Metal/SiC Systems: Weak or Strong Interfaces? Materials Science & Engineering: A, 276, 195-202.
http://dx.doi.org/10.1016/S0921-5093(99)00274-9

[12]   Froumin, N., Frage, N., Polak, M. and Dariel, M.P. (1997) Wettability and Phase Formation in the TiCx/Al System. Scripta Materialia, 37, 1263-1267.
http://dx.doi.org/10.1016/S1359-6462(97)00235-2

[13]   Kharlamov, A.I., Loichenko, S.V., Nizehenko, V.I., Kirllova, N.V. and Floka, L.I. (2001) Wetting of Hot-Pressed Aluminum Borides and Borocarbides by Molten Aluminum and Copper. Powder Metallurgy and Metal Ceramics, 40, 65-70.
http://dx.doi.org/10.1023/A:1011364023572

[14]   Muolo, M.L., Ferrera, E., Novakovic, R. and Passerone, A. (2003) Wettability of Zirconium Diboride Ceramics by Ag, Cu, and Their Alloys with Zr. Scripta Materialia, 48, 191-196.
http://dx.doi.org/10.1016/S1359-6462(02)00361-5

[15]   Muolo, M.L., Delasnte, A., Bassoli, M., Passerone, A. and Bellosi, A. (1998) Wettability of TiB2 Ceramics by Liquid Cu, and Ag-Cu Eutectic Alloys. Interfacial Science in Ceramic Joining, NATO ASI Series, 58, 87-94.

[16]   Aizenshtein, M., Froumin, N., Barth, P., Shapiro-Tsoref, E., Dariel, M.P. and Frage, N. (2007) How Does the Composition of Quasi-Stoichiometric Titanium Diboride Affect Its Wetting by Molten Cu and Au? Journal of Alloys and Compounds, 442, 375-378.
http://dx.doi.org/10.1016/j.jallcom.2006.06.117

[17]   Elliott, R.P. (1961) The Boron Carbon System. Final Technical Report ARF-2200-12. US Atomic Energy Commission, Chicago.

[18]   Beauvy, M. (1983) Stoichiometric Limits of Carbon-Rich Boron Carbide Phases. Journal of Less Common Metals, 90, 169-175.
http://dx.doi.org/10.1016/0022-5088(83)90067-X

[19]   Thevenot, F. (1990) Boron Carbide—A Comprehensive Review. Journal of the European Ceramic Society, 6, 205-225.
http://dx.doi.org/10.1016/0955-2219(90)90048-K

[20]   Naidich, Ju.V. (1981) The Wettability of Solids by Liquid Metals. Progress in Surface and Membrane Science, 14, 353-484.
http://dx.doi.org/10.1016/B978-0-12-571814-1.50011-7

[21]   Oden, L.L. and Gokcen, N.A. (1992) Cu-C and Al-Cu-C Phase Diagrams and Thermodynamic Properties of C in the Alloys from 1550°C to 2300°C. Metallurgical Transactions B, 23, 453-458.
http://dx.doi.org/10.1007/BF02649664

[22]   Massalski, T.B., Subramanian, P.R., Okamoto, H. and Kacprazak, L. (1990) Binary Alloy Phase Diagrams. 2nd Edition, ASM International, Materials Park.

[23]   Frage, N., Froumin, N., Aizenshtein, M. and Dariel, M.P. (2004) Interface Reaction in the B4C/(Cu-Si) System. Acta Materialia, 52, 2625-2635.
http://dx.doi.org/10.1016/j.actamat.2004.02.010

[24]   Froumin, N., Frage, N., Aizenshtein, M. and Dariel, M.P. (2003) Ceramic-Metal Interaction and Wetting Phenomena in the B4C/Cu System. Journal of the European Ceramic Society, 23, 2821-2828.
http://dx.doi.org/10.1016/S0955-2219(03)00294-2

[25]   Young, T. (1805) An Essay on the Cohesion of Fluids. Philosophical Transactions of the Royal Society of London, 95, 65-87.
http://dx.doi.org/10.1098/rstl.1805.0005

[26]   Dupré, M.A. (1869) Theories Mecanique de la Chaleur. Gauthier Villars, Imprimeur-Librarie, Paris.

[27]   Frage, N., Froumin, N. and Dariel, M.P. (2002) Wetting of TiC by Non-Reactive Liquid Metals. Acta Materialia, 50, 237-245.
http://dx.doi.org/10.1016/S1359-6454(01)00349-4

[28]   Seifert, H.J. and Aldinger, F. (2002) Phase Equilibria in the Si-B-C-N System. High Performance Non-Oxide Ceramics I. Structure and Bonding, 101, 1-58.
http://dx.doi.org/10.1007/3-540-45613-9_1

[29]   Hillert, M. (1988) Phase Equilibria, Fhase Diagram and Phase Transformation-Their Thermodynamic Basis. Cambridge University Press, Cambridge.

[30]   Tsoga, A., Ladas, S. and Nikolopoulos, P. (1997) Correlation between the Oxidation State of α-SiC and Its Wettability with Non-Reactive (Sn) or Reactive (Ni) Metallic Components and Their Binary Si-Alloy. Acta Materialia, 45, 3515-3525.
http://dx.doi.org/10.1016/S1359-6454(97)00044-X

[31]   Drevet, B., Kalogeropoulou, S. and Eustathopoulos, N. (1993) Wettability and Interfacial Bonding in Au-Si/SiC System. Acta Metallurgica et Materialia, 41, 3119-3126.
http://dx.doi.org/10.1016/0956-7151(93)90041-P

[32]   Gusev, A.I. (1997) Phase Equilibria in the Ternary System Titanium-Boron-Carbon: The Sections TiCy-TiB2 and B4Cy-TiB2. Journal of Solid State Chemistry, 133, 205-210.
http://dx.doi.org/10.1006/jssc.1997.7429

[33]   Frage, N., Froumin, N., Aizenshtein, M., Kutsenko, L., Fuks, D. and Dariel, M.P. (2005) Reactive Wetting in Titanium Carbide/Non-Reactive Metal Systems. Current Opinion in Solid State and Materials Science, 9, 189-195.
http://dx.doi.org/10.1016/j.cossms.2006.02.008

[34]   Aizenshtein, M., Froumin, N., Frage, N. and Dariel, M.P. (2005) Interface Interaction and Wetting Behavior in B4C/ (Me-Ti) Systems (Me=Cu, Ag, Sn and Au). Materials Science & Engineering: A, 395, 180-185.
http://dx.doi.org/10.1016/j.msea.2004.12.017

[35]   Kleppa, O.J. and Topor, L. (1985) Thermochemistry of Binary Liquid Gold Alloys: (Gold + Chromium), (Gold + Vanadium), (Gold + Titanium), and (Gold + Scandium) at 1379 K. Metallurgical Transactions A, 16A, 93-99.

[36]   Pan, W., Li, R.T., Chen, J., Sun, R.F. and Lian, J. (2000) Thermo-dynamic Properties of Ti in Ag-Ti Alloys. Materials Science & Engineering: A, 287, 72-77.
http://dx.doi.org/10.1016/S0921-5093(00)00821-2

[37]   Nikolaenko, I.V., Beloborodova, E.A., Batalin, G.I. and Zhuravlev, V.S. (1984) Heats of Dissolution of Titanium in Tin- Titanium Melts. Zhurnal Fizicheskoi Khimii, 58, 2873-2876.

[38]   Lin, Q.L., Shen, P., Qiu, F., Zhang, D. and Jiang, Q.C. (2009) Wetting of Polycrystalline B4C by Molten Al at 1173-1473 K. Scripta Materialia, 60, 960-963.
http://dx.doi.org/10.1016/j.scriptamat.2009.02.024

[39]   Heuzey, M.C. and Pelton, A.D. (1996) Critical Evaluation and Optimization of the Thermodynamic Properties of Liquid Tin Solutions. Metallurgical and Materials Transactions B, 27, 810-828.
http://dx.doi.org/10.1007/BF02915611

[40]   Ansara, I., Dinsdale, A.T. and Rand, M.H. (1998) Cost 507: Thermochemical Database for Light Metal Alloys. Vol. 2, Office for Official Publications of the European Communities, Luxembourg.

 
 
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