Effects of Ion Doping on the Optical Properties of Dye-Sensitized Solar Cells
Affiliation(s)
1 College of Chemistry and Chemical Engineering, Northeast Petroleum University, Qaqing, China. 2 Daqing Oilfield Engineering Co. Ltd., Qaqing, China.
1 College of Chemistry and Chemical Engineering, Northeast Petroleum University, Qaqing, China. 2 Daqing Oilfield Engineering Co. Ltd., Qaqing, China.
ABSTRACT
Dye-sensitized solar cells (DSC) play a leading role in the third generation photovoltaics due to their low cost, easy fabrication process, high conversion efficiency and good stability. As a media of dye adsorption, electron transport, and electrolyte diffusion, the nanocrystalline semiconductor photoanode plays a key role during light-to-electricity conversion in DSC. This paper studies the influence of different ions doping and different concentration of ion doping on the electrical and optical properties of DSC, through the photoelectric property test of DSC. We learn that Zn2+ doped TiO2 photoanode is the best. At the same time there was an optimum doping concentration which was 0.05% (mole fraction).
Dye-sensitized solar cells (DSC) play a leading role in the third generation photovoltaics due to their low cost, easy fabrication process, high conversion efficiency and good stability. As a media of dye adsorption, electron transport, and electrolyte diffusion, the nanocrystalline semiconductor photoanode plays a key role during light-to-electricity conversion in DSC. This paper studies the influence of different ions doping and different concentration of ion doping on the electrical and optical properties of DSC, through the photoelectric property test of DSC. We learn that Zn2+ doped TiO2 photoanode is the best. At the same time there was an optimum doping concentration which was 0.05% (mole fraction).
Cite this paper
Gu, D. , Zhu, Y. , Xu, Z. , Wang, N. and Zhang, C. (2014) Effects of Ion Doping on the Optical Properties of Dye-Sensitized Solar Cells. Advances in Materials Physics and Chemistry, 4, 187-193. doi: 10.4236/ampc.2014.410022.
Gu, D. , Zhu, Y. , Xu, Z. , Wang, N. and Zhang, C. (2014) Effects of Ion Doping on the Optical Properties of Dye-Sensitized Solar Cells. Advances in Materials Physics and Chemistry, 4, 187-193. doi: 10.4236/ampc.2014.410022.
References
[1] O’Regn, B. and Gratzel, M. (1991) A Low-Cost High Efficiency Solar Cell Based on Dye-Sensitized Colloidal TiO2 Films. Nature, 353, 737-740.
http://dx.doi.org/10.1038/353737a0 [2] Gratzel, M. (2005) Solar Energy Conversion by Dye-Sensitized Photo-Voltaic Cells. Inorganic Chemistry, 44, 6841-6851.
http://dx.doi.org/10.1021/ic0508371 [3] Gra1tze, M. (2004) Conversion of Sunlight to Electric Power by Nanocrystalline Dye-Sensitized Solar Cells. Journal of Photochemistry and Photobiology A: Chemistry, 164, 3-14.
http://dx.doi.org/10.1016/j.jphotochem.2004.02.023 [4] Gratzel, M. (2003) Dye-Sensitized Solar Cells. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 4, 145-153.
http://dx.doi.org/10.1016/S1389-5567(03)00026-1 [5] Burschka, J., Pellet, N., Moon, S.-J., et al. (2013) Sequential Deposition as a Route to High-Performance Perovskite-Sensitized Solar Cells. Nature, 499, 316-319.
http://dx.doi.org/10.1038/nature12340 [6] Van De Lagemaat, J. and Frank, A.J. (2001) Nonthermalized Electron Transport in Dye-Sensitized Nanocrystalline TiO2 Films; Transient Photocurrent and Random Walk Modeling Studies. The Journal of Physical Chemistry B, 105, 11194-11205.
http://dx.doi.org/10.1021/jp0118468 [7] Asxhi, R., Morikxwx, T., Ohwxki, T., et al. (2001) Visible-Light Photocatalysis Innitrogen Doped Titanium Oxides. Science, 293, 269-271.
http://dx.doi.org/10.1126/science.1061051 [8] Konstantinova, E.A., Kokorin, A.I., Lips, K., Sakthivel, S. and Kisch, H. (2009) EPR Study of the Illumination Effect on Properties of Paramagnetic Centers in Nitrogen-Doped TiO2 Active in Visible Light Photocatalysis. Applied Magnetic Resonance, 35, 421-427.
http://dx.doi.org/10.1007/s00723-009-0173-5 [9] Menzies, D.B. and Dai, Q. (2007) Modifcation of Mesoporous TiO2 Electrodes by Surface Treatment with Titanium (IV), Indium (III) and Zirconium (IV) Oxideprecursors: Preparation, Characterization and Photovoltaic Performance in Dye-Sensitized Nanocrystalline Solar Cells. Nanotechnology, 18, 125608-125618.
http://dx.doi.org/10.1088/0957-4484/18/12/125608 [10] Zhang, C.N. and Dai, S. (2011) Charge Recombination and Band-Edge Shift in the Dye-Sensitized Mg2+-Doped TiO2 Solar Cells. The Journal of Physical Chemistry C, 115, 16418-16424.
http://dx.doi.org/10.1021/jp2024318 [11] Tian, H.J., Hu, L.H., Zhang, C.N., Liu, W.Q., Huang, Y., Mo, L., Guo, L., Sheng, J. and Dai, S.Y. (2010) Retarded Charge Recombination in Dye-Sensitized Nitrogen-Doped TiO2 Solar Cells. Journal of Physical Chemistry C, 114, 1627-1632.
http://dx.doi.org/10.1021/jp9103646 [12] Du1rr, M., Rosselli, S., Yasuda, A. and Nelles, G. (2006) Band-Gap Engineering of Metal Oxides for Dye-Sensitized Solar Cells. Journal of Physical Chemistry B, 110, 21899-21902.
http://dx.doi.org/10.1021/jp063857c [13] Ito, S., Murakami, T.N., Comte, P., Liska, P., Gratzel, C., Nazeeruddin, M.K. and Gratzel, M. (2008) Fabrication of Thin Film Dye Sensitized Solar Cells with Solar to Electric Power Conversion Efficiency over 10%. Thin Solid Films, 516, 4613-4619.
http://dx.doi.org/10.1016/j.tsf.2007.05.090 [14] Alias, S.S. and Mohamad, A.A. (2014) Synthesis of Zinc Oxide by Sol-Gel Method for Photoelectrochemical Cells. Springer Briefs in Materials, Springer, Berlin. [15] Innocenzi, P., Zub, Y.L. and Kessler, V.G. (2008) Sol-Gel Methods for Materials Processing. NATO Science for Peace and Security Series C: Environmental Security. [16] Hocevar, M., Krasovec, U.O., Berginc, M., Drazic, G., Hauptman, N. and Topic, M. (2008) Development of TiO2 Pastes Modified with Pechini Sol-Gel Method for High Efficiency Dye-Sensitized Solar Cell. Journal of Sol-Gel Science and Technology, 48, 156-162. [17] Pandey, R.N., Chandra Babu, K.S. and Srivastava, O.N. (1996) High Conversion Efficiency Photoelectrochemical Solar Cells. Progress in Surface Science, 52, 125-192.
http://dx.doi.org/10.1016/0079-6816(96)00009-3
[1] O’Regn, B. and Gratzel, M. (1991) A Low-Cost High Efficiency Solar Cell Based on Dye-Sensitized Colloidal TiO2 Films. Nature, 353, 737-740.
http://dx.doi.org/10.1038/353737a0 [2] Gratzel, M. (2005) Solar Energy Conversion by Dye-Sensitized Photo-Voltaic Cells. Inorganic Chemistry, 44, 6841-6851.
http://dx.doi.org/10.1021/ic0508371 [3] Gra1tze, M. (2004) Conversion of Sunlight to Electric Power by Nanocrystalline Dye-Sensitized Solar Cells. Journal of Photochemistry and Photobiology A: Chemistry, 164, 3-14.
http://dx.doi.org/10.1016/j.jphotochem.2004.02.023 [4] Gratzel, M. (2003) Dye-Sensitized Solar Cells. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 4, 145-153.
http://dx.doi.org/10.1016/S1389-5567(03)00026-1 [5] Burschka, J., Pellet, N., Moon, S.-J., et al. (2013) Sequential Deposition as a Route to High-Performance Perovskite-Sensitized Solar Cells. Nature, 499, 316-319.
http://dx.doi.org/10.1038/nature12340 [6] Van De Lagemaat, J. and Frank, A.J. (2001) Nonthermalized Electron Transport in Dye-Sensitized Nanocrystalline TiO2 Films; Transient Photocurrent and Random Walk Modeling Studies. The Journal of Physical Chemistry B, 105, 11194-11205.
http://dx.doi.org/10.1021/jp0118468 [7] Asxhi, R., Morikxwx, T., Ohwxki, T., et al. (2001) Visible-Light Photocatalysis Innitrogen Doped Titanium Oxides. Science, 293, 269-271.
http://dx.doi.org/10.1126/science.1061051 [8] Konstantinova, E.A., Kokorin, A.I., Lips, K., Sakthivel, S. and Kisch, H. (2009) EPR Study of the Illumination Effect on Properties of Paramagnetic Centers in Nitrogen-Doped TiO2 Active in Visible Light Photocatalysis. Applied Magnetic Resonance, 35, 421-427.
http://dx.doi.org/10.1007/s00723-009-0173-5 [9] Menzies, D.B. and Dai, Q. (2007) Modifcation of Mesoporous TiO2 Electrodes by Surface Treatment with Titanium (IV), Indium (III) and Zirconium (IV) Oxideprecursors: Preparation, Characterization and Photovoltaic Performance in Dye-Sensitized Nanocrystalline Solar Cells. Nanotechnology, 18, 125608-125618.
http://dx.doi.org/10.1088/0957-4484/18/12/125608 [10] Zhang, C.N. and Dai, S. (2011) Charge Recombination and Band-Edge Shift in the Dye-Sensitized Mg2+-Doped TiO2 Solar Cells. The Journal of Physical Chemistry C, 115, 16418-16424.
http://dx.doi.org/10.1021/jp2024318 [11] Tian, H.J., Hu, L.H., Zhang, C.N., Liu, W.Q., Huang, Y., Mo, L., Guo, L., Sheng, J. and Dai, S.Y. (2010) Retarded Charge Recombination in Dye-Sensitized Nitrogen-Doped TiO2 Solar Cells. Journal of Physical Chemistry C, 114, 1627-1632.
http://dx.doi.org/10.1021/jp9103646 [12] Du1rr, M., Rosselli, S., Yasuda, A. and Nelles, G. (2006) Band-Gap Engineering of Metal Oxides for Dye-Sensitized Solar Cells. Journal of Physical Chemistry B, 110, 21899-21902.
http://dx.doi.org/10.1021/jp063857c [13] Ito, S., Murakami, T.N., Comte, P., Liska, P., Gratzel, C., Nazeeruddin, M.K. and Gratzel, M. (2008) Fabrication of Thin Film Dye Sensitized Solar Cells with Solar to Electric Power Conversion Efficiency over 10%. Thin Solid Films, 516, 4613-4619.
http://dx.doi.org/10.1016/j.tsf.2007.05.090 [14] Alias, S.S. and Mohamad, A.A. (2014) Synthesis of Zinc Oxide by Sol-Gel Method for Photoelectrochemical Cells. Springer Briefs in Materials, Springer, Berlin. [15] Innocenzi, P., Zub, Y.L. and Kessler, V.G. (2008) Sol-Gel Methods for Materials Processing. NATO Science for Peace and Security Series C: Environmental Security. [16] Hocevar, M., Krasovec, U.O., Berginc, M., Drazic, G., Hauptman, N. and Topic, M. (2008) Development of TiO2 Pastes Modified with Pechini Sol-Gel Method for High Efficiency Dye-Sensitized Solar Cell. Journal of Sol-Gel Science and Technology, 48, 156-162. [17] Pandey, R.N., Chandra Babu, K.S. and Srivastava, O.N. (1996) High Conversion Efficiency Photoelectrochemical Solar Cells. Progress in Surface Science, 52, 125-192.
http://dx.doi.org/10.1016/0079-6816(96)00009-3