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 AJAC  Vol.5 No.14 , October 2014
Impregnation of Crushed Stone with Bitumenous Compounds Using Propane/Butane Impregnation Process Carried out in Supercritical Fluid Conditions
Abstract: An efficient technology of impregnation of carbonate crushed stone by oil-product based on SCF-impregnation process usage with propane/butane solvent was developed. Regular impregnation throughout the volume of crushed stone sample is achieved. As a result of the appliance of proposed technology, the humidity of the treated crushed stone samples decreased down to 0.54%.
Cite this paper: Gumerov, F. , Farakhov, M. , Khayrutdinov, V. , Gabitov, F. , Zaripov, Z. , Khabriyev, I. and Akhmetzyanov, T. (2014) Impregnation of Crushed Stone with Bitumenous Compounds Using Propane/Butane Impregnation Process Carried out in Supercritical Fluid Conditions. American Journal of Analytical Chemistry, 5, 945-956. doi: 10.4236/ajac.2014.514102.
References

[1]   Salihov, M.G., Bashirov, D.M., Gatiyatullin, M.H., Baronova, L.G. and Pushkin, E.A. (2001) Method of Preparation of Black Gravel. R.F. Patent No. 2200717.

[2]   Gaidar, S.M., Konova, M.M. and Gromov, E.V. (2011) Method of Preparation of Black Gravel. R.F. Patent No. 2461522.

[3]   Solovyov, M.V., Hozin, V.G. and Fomin, A.Y. (2013) Hardening of Road Stone Materials Molten Sulfur. News KAFU, 2, 263-267.

[4]   Muhlёnov, I.P., Dopkina, E.I., Deryuzhina, V.I. and Soroko, V.E. (1989) Tehnolologiy Acatalysts. Leningrad, Ed., Chemistry, 272 p.

[5]   Asplund, S. (1996) Coke Formation and Its Effect on Internal Mass Transfer and Selectivity in Pd-Catalised Acetylene Hydrogenation. Journal of Catalysis, 158, 267-278.
http://dx.doi.org/10.1006/jcat.1996.0026

[6]   Bilalov, T.R. and Gumerov, F.M. (2011) The Manufacturing Processes and Catalyst Regeneration/Thermodynamic Basis of Production Processes and Regeneration of Palladium Catalysts Using Sverhkritiches-One Dioxide. LAP LAMBERT Academic Publishing GmbH & Co. KG., Dudweiler Landstr., Germany, 153 p.

[7]   Gumerov, F.M., Sabirzyanov, A.N. and Gumerova, G.I. (2000) Sub- and Supercritical Fluids in Polymer. Science, Kazan, 328 p.

[8]   Bilalov, T.R., Gumerov, F.M., Gabitov, F.R., Fyodorov, G.I., Kharlampidi, K.E. and Sagdeev, A.A. (2009) Supercritical Carbon Dioxide Assisted Synthesis and Regeneration of Palladium Catalyst. Supercritical Fluids: Theory and Practice, 4, 34-52.

[9]   Chernyshev, A.K., Gumerov, F.M. and Tsvetinsky, G.N. (2013) Carbon Dioxide. Galley Print, Moscow, 903 p.

[10]   Garrido, G.I., Patcas, F.C., Upper, G., Turk, M., Yilmaz, S. and Kraushaar-Czarnetzki, B. (2008) Super-critical Deposition of Pt on SnO2-Coated Al2O3 Foams: Phase Behaviour and Catalytic Performance. Applied Catalysis A: General, 338, 58-65.
http://dx.doi.org/10.1016/j.apcata.2007.12.019

[11]   Liao, S.K. and Chang, P.S. (2012) Literatures on Dyeing Technique of Supercritical Fluid Carbon Dioxide. American Journal of Analytical Chemistry, 3, 923-930.
http://dx.doi.org/10.4236/ajac.2012.312A122

[12]   van der Kraan, M., Fernandez, M.V. and Woerlee, G.F. (2007) Dyeing of Natural and Synthetic Textiles in Supercritical Carbon Dioxide with Disperse Reactive Dyes. The Journal of Supercritical Fluids, 40, 470-476.
http://dx.doi.org/10.1016/j.supflu.2006.07.019

[13]   Guzel, B. and Akgerman, A. (2000) Mordant Dyeing of Wool by Supercritical Processing. Journal of Supercritical Fluids, 18, 247-252.
http://dx.doi.org/10.1016/S0896-8446(00)00065-6

[14]   Gastiger, M., van Oost, H., Eymard, P. and Masson, D. (1995) Impregnation des bois en phase supercritique in Fluidessupercritiques et materiaux. AIPFS, Publ., Nancy, 301-340.

[15]   Lucas, S., Gonzalez, E., Calvo, M.P., Palencia, C., Alonso, E. and Cocero, M.J. (2007) Super-critical CO2 Impregnation of Radiata Pine with Organic Fungicides. Effect of Operating Conditions and Two-Parameters Modeling. Journal of Supercritical Fluids, 40, 462-469.
http://dx.doi.org/10.1016/j.supflu.2006.08.003

[16]   Iversen, S.B., Larsen, T., Henriksen, O. and Felsvang, K. (2003) The World’s First Commercial Supercritical Wood Treatement Plant. Proceedings of the 6th International Symposium on Supercritical Fluids, Versailles, 28-30 April 2003, 445-450.

[17]   Ikonnikov, V.K., Dobrodskaya, T.V., Romaschenkova, N.D., Sirotin, S.A., Dobrusina, S.A. and Podgornaja, N.I. (2010) Development of Technology for Mass Media Processing Paper-Based Using the Carbon Dioxide to Ensure Their Long-Term Preservation. Supercritical Fluids, Theory and Practice, 5, 43-59.

[18]   Fernandes, J., Kjellow, A.W. and Henriksen, O. (2012) Modeling and Optimization of the Supercritical Wood Impregnation Process: Focus on Pressure and Temperature. Proceedings of the 10th International Symposium on Supercritical Fluids, San Francisco, 13-16 May 2012.

[19]   Cansell, F. and Petitet, J.P. (1995) Fluidessupercritiques et materiaux. LIMHP CNRS, Paris, 327 p.

[20]   Garrabos, Y., Le Neindre, В., Subra, P., Cansell, F. and Pommier, C. (1992) Fluides critiques et gravite, fluidеs supercritiques et materiaux. Annales de Chimie, 17, 55-90.

[21]   Bork, M. (1998) Supercritical Fluid Dyeing of Synthetic Fibres. Proceeding of the 5th Meeting and Natural Products Processing, Nice, 23-25 March 1998, 387-391.

[22]   Shim, J.J., Choi, J.H., Ju, J.H., Son, B.K., Ahn, J.M., Kim, B.H. and Kim, K.S. (2003) Dyeing of Polyester, Aramid, and Polypropylene Fibers in Supercritical CO2. Proceedings of the 6th International Symposium on Supercritical Fluids, Versailles, 28-30 April 2003.

[23]   Bach, E., Schmidt, A., Cleve, E. and Schollmeyer, E. (2003) Treatement of Textiles in CO2-Potentialities and Limitations. Proceedings of the 6th International Symposium on Supercritical Fluids, Versailles, 28-30 April 2003.

[24]   Kay, W.B. (1970) Vapor-Liquid Equilibrium Relations of Binary Systems. The Propane-n-Alkane Systems. n-Butane and n-Pentane. Journal of Chemical and Engineering Data, 15, 46-52.
http://dx.doi.org/10.1021/je60044a026

[25]   Beránek, P. and Wichterle, I. (1981) Vapour-Liquid Equilibria in the Propane-n-Butane System at High Pressures. Fluid Phase Equilibria, 6, 279-282.
http://dx.doi.org/10.1016/0378-3812(81)85010-8

[26]   Juntarachat, N., Bello, S., Privat, R. and Jaubert, J.N. (2013) Validation of a New Apparatus Using the Dynamic for Determining the Critical Properties of Binary Gas/Gas Mixtures. Journal of Chemical and Engineering Data, 58, 671-676.
http://dx.doi.org/10.1021/je301209u

[27]   State Standard (GOST) 20448-90. Liquefied Hydrocarbon Gases Fuel for Domestic Consumption.

[28]   Hansen, C.M. (2000) Hansen Solubility Parameters. CRC Press, London, 205 p.

[29]   Gupta, R.B. and Shim, J.J. (2007) Solubility in Supercritical Carbon Dioxide. CRC Press, Boca Raton, 909 p.

[30]   Amirhanov, D.G., Gumerov, F.M., Sagdeev, A.A. and Galimov, A.T. (2014) Solutes in the Supercritical Fluid Media. Otechestvo, Kazan, 264 p.

[31]   Popov, V.K. (2013) Physico-Chemical Processes in Supercritical Fluids and Functionalization of Materials. Ph.D. Dissertation, MSU, 78 p.

[32]   McHugh, M.A. and Krukonis, V.J. (1994) Super-critical Fluids Extraction: Principles and Practice. 2nd Edition, Butterworth-Heinemann, Oxford, 507 p.

[33]   Mukhopadhyay, M. (2000) Natural Extracts Using Supercritical Carbon Dioxide. CRC Press, Boca Raton, 339 p.
http://dx.doi.org/10.1201/9781420041699

[34]   State Standard (GOST) 8267-93. Rubble and Gravel from Dense Rocks for Construction Work. Specifications.

[35]   A Method of Producing Non-Oxidized Bitumen. RF Patent No. 2371468.

[36]   Sultans, F.M. and Khairutdinov, I.R. (2001) Modern Processes of Propane and Propane-Butane Deasphalting. Refining and Petrochemicals: Coll. Nauchn. Works IPNHP AN RB, 51-56.

[37]   State Standard (GOST) 8269.0-97. Rubble and Gravel from Dense Rocks and Industrial Waste Products for the Construction Work. Methods for Physical and Mechanical Tests.

[38]   Patent Application No. 2014118199/03.

 
 
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