JBM  Vol.2 No.5 , July 2014
Characterization and Synthesis through Fast Phase-Transfer of Oil-Soluble Double-Coordinated Tea-Polyphenols Arsenic
ABSTRACT
Fast phase-transferring was adopted in ethanol solution at the condition of n (oil-soluble tea pol-yphenol): N (As3﹢) = 2:1, 4:1, 6:1, pH = 4.0, temperature 40°C - 45°C, action period of 15 h to compose the target, of which the productivity was 59%, UV was 267.50, 218.00, 220.50 nm, FTIR was 6291, 34158.6, 2850.2, 1708.2; 1457.3; 1370.4, 1224.2, 1144.0, 760.5 cm﹣1, fluorescence value λmax = 257, 591.1, 593.7, 590.3, 591.0, 591.5, XRD λ/nm is 3.6974, 4.186, 12.0762, 15.4747, 1H-NMRδ = 0.782, 1.193, 1.483 - 1.586, 1.959 - 2.184, 2.479, 3.116, 3.970 - 3.981, 5.231 - 5.753, 6.537 - 7.300. Finally it was ascertained through XRD as double-coordinated polycrystal compound.

Cite this paper
Zhou, W. , Chen, Y. and Zhang, L. (2014) Characterization and Synthesis through Fast Phase-Transfer of Oil-Soluble Double-Coordinated Tea-Polyphenols Arsenic. Journal of Biosciences and Medicines, 2, 34-41. doi: 10.4236/jbm.2014.25004.
References
[1]   Li, H. and Liu, Y.M. (2004) Tea Polyphenols and Metal Compound Structure-Activity Relationship. Master Degree Thesis, Sichuan University, Chengdu.

[2]   Bushman, J.L. (1998) Green Tea and Cancer in Human: A Review of The-literature. Nutrition and Cancer, 31, 151-159.
http://dx.doi.org/10.1080/01635589809514697

[3]   Szoboszlai, N., Polgi, Z., Mihucz, V.G., et al. (2009) Recent Trends in Total Reflection X-Ray Fluorescence Spectrometry for Biological Applications. Analytica Chimica Acta, 633, 1-18.
http://dx.doi.org/10.1016/j.aca.2008.11.009

[4]   Valcárcel, M., Arce, L. and Rios, A. (2001) Coupling Continuous Separation Techniques to Capillary Electrophoresis. Journal of Chromatography A, 924, 3-30.
http://dx.doi.org/10.1016/S0021-9673(01)00898-6

[5]   Stahl, W., van den Berg, H., Arthur, J., et al. (2002) Bioavailability and Metabolism. Molecular Aspects of Medicine, 23, 39-100.
http://dx.doi.org/10.1016/S0098-2997(02)00016-X

[6]   Schifferle, R.E. (2005) Nutrition and Periodontal Disease. Dental Clinics of North America, 49, 595-610.
http://dx.doi.org/10.1016/j.cden.2005.03.008

[7]   Salvador, A., Chisvert, A., Carre, A.S., et al. (2007) Analysis of Cosmetic Products. Publisher Elsevier, Amsterdam, 475-487.

[8]   Russo, G.L. (2007) Ins and Outs of Dietary Phytochemicals in Cancer Chemoprevention. Biochemical Pharmacology, 74, 533-544.
http://dx.doi.org/10.1016/j.bcp.2007.02.014

[9]   De Groot, A. and Dommisse, R. (1995) Advantages of Long-Range-INEPT Measurements for Structure Determination of Catechin Esters. Bulletin of Magnetic Resonnance, 17, 242-243.

[10]   Wang, S.X. and Wang, L.X. (2000) Characteristics of Oil-Soluble Tea Polyphenols and Application of. Tea Science and Technology, 3, 17-18.

[11]   Zhou, W.F. (2007) Tea Polyphenol Selenium Complexes: Synthesis and Structure Characterization of. Fine Chemical Industry, 3, 248-260.

[12]   Huang, H.N., Li, A.Z., Weng, L.N., et al. (2007) Tea Polyphenol Manganese Synthesis, Characterization and Complexation and Induction of Apoptosis in Tumor Cells. Chemical Journal of Chinese Universities, 6, 1072-1076.

[13]   Yang, R.F., Zhang, C.S. and Hao, S.H. (2003) Medical Research on Nutrition of Trace Element Arsenic. Medicine, 9, 12-14.

[14]   Xie, H.F. (2001) Arsenic on Human Diversity. Foreign Medical Health, 28, 265-269.

[15]   Cao, R.Y., Qian, Z.Y. and Liu, J.J. (2003) The Treatment of Leukemia “Offbeat” Flower of Small Dose of Arsenic Treatment—APL. Chinese Prescription Medicine, 6, 72-73.

[16]   An, Y. (2006) Arsenic Carcinogenesis Mechanism. Chinese Journal of Control of Endemic Diseases, 11, 271-274.

[17]   Zhou, W.F. and He, Q.S. (2008) Irreversible Phase Transfer Method for the Synthesis of Tea Polyphenols and Spectra of Arsenic. Fine Chemical Industry, 4, 347-350.

[18]   Mainardi, T., Kapoor, S. and Bielory, L. (2009) Complementary and Alternative Medicine Herbs, Phytochemical Sandvitamin Sand the Irimmuno Logic Effects. Journal of Allergy and Clinical Immunology, 123, 283-294.
http://dx.doi.org/10.1016/j.jaci.2008.12.023

[19]   Liska, D., Lyon, M. and Jones, D.S. (2006) Detoxification and Biotrans Formation Alimbalances Explore. Science and Healing, 2, 122-140.

[20]   Kohlmeier, M. (2003) Minerals and Trace Elements Nutrient Metabolism. Academic Press, London, 643-768.

[21]   Li, B.H., Wang, G.H., Jia, J.X., et al. (2002) Study of Spectro Fluorometric Determination of Race Germanium with Phenyl fluorine. Chemical Research and Application, 14, 242-244.

 
 
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