JASMI  Vol.4 No.2 , June 2014
Compact Formulation of Redox Systems According to GATES/GEB Principles
ABSTRACT

The Generalized Electron Balance (GEB), together with charge balance and concentration balances, completes the set of equations needed for resolution of electrolytic redox systems. The general formulae for GEB were obtained according to Approach II to GEB, i.e., on the basis of the equation 2?f(O) ? f(H) obtained from elemental balances: f(H) for H, and f(O) for O. Equivalency of the Approach II and the Approach I to GEB was proved for an aqueous solution and a binary-solvent system. On this basis, a compact form of GEB was derived.


Cite this paper
Michałowska-Kaczmarczyk, A. and Michałowski, T. (2014) Compact Formulation of Redox Systems According to GATES/GEB Principles. Journal of Analytical Sciences, Methods and Instrumentation, 4, 39-45. doi: 10.4236/jasmi.2014.42006.
References
[1]   Michalowski, T., Toporek, M., Michalowska-Kaczmarczyk, A.M. and Asuero, A.G. (2013) New Trends in Studies on Electrolytic Redox Systems. Electrochimica Acta, 109, 519-531.
http://dx.doi.org/10.1016/j.electacta.2013.07.125

[2]   Michalowski, T., Michalowska-Kaczmarczyk, A.M. and Toporek, M. (2013) Formulation of General Criterion Distinguishing between Non-Redox and Redox Systems, Electrochimica Acta, 112, 199-211.
http://dx.doi.org/10.1016/j.electacta.2013.08.153

[3]   Michalowska-Kaczmarczyk, A.M. and Michalowski, T. (2013) Comparative Balancing of Non-Redox and Redox Electrolytic Systems and Its Consequences. American Journal of Analytical Chemistry, 4, 46-53.
http://dx.doi.org/10.4236/ajac.2013.410A1006

[4]   Michalowski, T. (2011) Application of GATES and MATLAB for Resolution of Equilibrium, Metastable and Non-Equilibrium Electrolytic Systems, Chapter 1, 1-34. In: Michalowski, T., Ed., Applications of MATLAB in Science and Engineering, InTech.
http://www.intechopen.com/books/show/title/applications-of-matlab-in-science-and-engineering.

[5]   Michalowski, T., Pilarski, B., Asuero, A.G. and Michalowska-Kaczmarczyk, A.M. (2014) Modeling of Acid-Base Properties in Binary-Solvent Systems, Chapter 9.4. In: Wypych, G., Ed., Handbook of Solvents (2nd Edition), in print.

[6]   Michalowski, T. (2001) Calculations in Analytical Chemistry with Elements of Computer Programming (in Polish) PK, Cracow. http://suw.biblos.pk.edu.pl/resourceDetails&rId=3974

[7]   Michalowski, T. and Lesiak, A. (1994) Formulation of Generalized Equations for Redox Titration Curves. Chemia Analityczna (Warsaw), 13, 623-637.

[8]   Michalowski, T., Rymanowski, M. and Pietrzyk, A. (2005) Non-Typical Bronsted’s Acids and Bases. Journal of Chemical Education, 82, 470-472. http://dx.doi.org/10.1021/ed082p470

[9]   Mancinelli, R., Sodo, A., Bruni, F., Ricci, M.A. and Soper, A.K. (2009) Influence of Concentration and Anion Size on Hydration of H+ Ions and Water Structure. Journal of Physical Chemistry B, 113, 4075-4080.
http://suw.biblos.pk.edu.pl/resourceDetails&rId=3974
http://dx.doi.org/10.1021/jp805220j


[10]   Michalowski, T. (1994) Calculation of pH and Potential E for Bromine Aqueous Solutions. Journal of Chemical Education, 71, 560-562. http://dx.doi.org/10.1021/ed071p560 .

[11]   http://www.allposters.pl/-sp/Commuter-Card-Game-Saturday-Evening-Post-Cover-March-15-1947-plakaty_i8290036_.htm

[12]   Asuero, A.G. and Michalowski, T. (2011) Comprehensive Formulation of Titration Curves Referred to Complex Acid-Base Systems and Its Analytical Implications. Critical Reviews in Analytical Chemistry, 41, 151-187.
http://dx.doi.org/10.1080/10408347.2011.559440

[13]   Michalowski, T. and Asuero, A.G. (2012) New Approaches in Modelling the Carbonate Alkalinity and Total Alkalinity. Critical Reviews in Analytical Chemistry, 42, 220-244.
http://dx.doi.org/10.1080/10408347.2012.660067

 
 
Top