Regeneration of the Catalysts by Supercritical Fluid Extraction
Author(s)
Farid M. Gumerov,
Ayrat A. Sagdeev,
Rustam F. Gallyamov,
Albina T. Galimova,
Kamil A. Sagdeev
Affiliation(s)
Federal State Budgetary Educational Institution of Higher Professional Education “Kazan National Research Technological University”, Kazan, Russia. Nizhnekamsk Chemical Technological Institute (Branch Institute) of the Kazan National Research Technological University, Nizhnekamsk, Russia.
Federal State Budgetary Educational Institution of Higher Professional Education “Kazan National Research Technological University”, Kazan, Russia. Nizhnekamsk Chemical Technological Institute (Branch Institute) of the Kazan National Research Technological University, Nizhnekamsk, Russia.
ABSTRACT
The decontaminating of catalysts nickel on kieselguhr, activated aluminum oxide and palladium catalyst LD-265 agent’s nature was analyzed. The possibility of catalyst’s regeneration was examined using supercritical CO2 extraction. Regeneration of coked catalysts was carried out at 70oC and 150oC in the pressure range 10 - 30 MPa by pure and modified supercritical CO2. Methanol and dimethylsulfoxide were used as modifiers (co-solvents) of supercritical CO2. The kinetics of supercritical CO2 regeneration process was studied. The activity of regenerated catalysts was measured.
Cite this paper
Gumerov, F. , Sagdeev, A. , Gallyamov, R. , Galimova, A. and Sagdeev, K. (2014) Regeneration of the Catalysts by Supercritical Fluid Extraction. International Journal of Analytical Mass Spectrometry and Chromatography, 2, 1-14. doi: 10.4236/ijamsc.2014.21001.
Gumerov, F. , Sagdeev, A. , Gallyamov, R. , Galimova, A. and Sagdeev, K. (2014) Regeneration of the Catalysts by Supercritical Fluid Extraction. International Journal of Analytical Mass Spectrometry and Chromatography, 2, 1-14. doi: 10.4236/ijamsc.2014.21001.
References
[1] Gumerov, F.M., Sabirzyanov, A.N. and Gumerova, G.I. (2000) Sub- and Supercritical Fluids in Polymer. Science, Kazan, 328 p. [2] Bilalov, T.R., Gumerov, F.M., Gabitov, F.R., Fyodorov, G.I., Kharlampidi, K.E. and Sagdeev, A.A. (2009) Supercriti- cal Carbon Dioxide Assisted Synthesis and Regeneration of Palladium Catalyst. Supercritical Fluids: Theory and Practice, 4, 34-52. [3] Gallyamov, R.F., Sagdeev, A.A., Gumerov, F.M. and Gabitov, F.R. (2010) Regeneration of “Nickel on Kieselguhr” Catalyst Using Supercritical Carbon Dioxide. Supercritical Fluids: Theory and Practice, 5, 40-51. [4] Bogdan, V.I., Koklin, A.E. and Kazansky, V.B. (2006) Regeneration of Deactivated Palladium Catalyst of Selective Acetylene Hydrogenation by Supercritical CO2. Supercritical Fluids: Theory and Practice, 1, 5-12. [5] Cansell, F. and Petitet, J.-P. (1995) Fluides supercritiques et materiaux. LIMHP CNRS, Paris, 327 p. [6] Johnston, K.P. (1989) New Direction in Supercritical Fluid Science and Technology. Journal of the American Chemical Society, 406, 1-12. http://dx.doi.org/10.1021/bk-1989-0406.ch001 [7] Apparatus for Studying the Solubility of Substances Using Supercritical Fluids. Useful Model Patent RF No.133012 published on October 10, 2013. [8] State Standard (GOST) 8136-85 Activated Alumina. [9] Galimova, A.T., Sagdeev, A.A. and Gumerov, F.M. (2013) Izvestiya vyshih uchebnuh zavedeny. Seriya Khimiya i khimicheskaya tekhnologiya, 56, 65-68. [10] Galimova, A.T., Sagdeev, A.A. and Gumerov, F.M. (2013) The Solubility of the Acetophenon and Methylphenylcarbinol in Supercritical Carbon Dioxide. Vestnik Kazanskogo Tekhnologicheskogo Universiteta, 16, 296-298. [11] Sagdeev, K.A., Gallyamov, R.F., Sagdeev, A.A. and Gumerov, F.M. (2013) Regeneration of Palladium Selective Hy- drogenation Catalyst by Supercritical Fluid Extraction Process. Vestnik Kazanskogo Tekhnologicheskogo Universiteta, 16, 20-23.
[1] Gumerov, F.M., Sabirzyanov, A.N. and Gumerova, G.I. (2000) Sub- and Supercritical Fluids in Polymer. Science, Kazan, 328 p. [2] Bilalov, T.R., Gumerov, F.M., Gabitov, F.R., Fyodorov, G.I., Kharlampidi, K.E. and Sagdeev, A.A. (2009) Supercriti- cal Carbon Dioxide Assisted Synthesis and Regeneration of Palladium Catalyst. Supercritical Fluids: Theory and Practice, 4, 34-52. [3] Gallyamov, R.F., Sagdeev, A.A., Gumerov, F.M. and Gabitov, F.R. (2010) Regeneration of “Nickel on Kieselguhr” Catalyst Using Supercritical Carbon Dioxide. Supercritical Fluids: Theory and Practice, 5, 40-51. [4] Bogdan, V.I., Koklin, A.E. and Kazansky, V.B. (2006) Regeneration of Deactivated Palladium Catalyst of Selective Acetylene Hydrogenation by Supercritical CO2. Supercritical Fluids: Theory and Practice, 1, 5-12. [5] Cansell, F. and Petitet, J.-P. (1995) Fluides supercritiques et materiaux. LIMHP CNRS, Paris, 327 p. [6] Johnston, K.P. (1989) New Direction in Supercritical Fluid Science and Technology. Journal of the American Chemical Society, 406, 1-12. http://dx.doi.org/10.1021/bk-1989-0406.ch001 [7] Apparatus for Studying the Solubility of Substances Using Supercritical Fluids. Useful Model Patent RF No.133012 published on October 10, 2013. [8] State Standard (GOST) 8136-85 Activated Alumina. [9] Galimova, A.T., Sagdeev, A.A. and Gumerov, F.M. (2013) Izvestiya vyshih uchebnuh zavedeny. Seriya Khimiya i khimicheskaya tekhnologiya, 56, 65-68. [10] Galimova, A.T., Sagdeev, A.A. and Gumerov, F.M. (2013) The Solubility of the Acetophenon and Methylphenylcarbinol in Supercritical Carbon Dioxide. Vestnik Kazanskogo Tekhnologicheskogo Universiteta, 16, 296-298. [11] Sagdeev, K.A., Gallyamov, R.F., Sagdeev, A.A. and Gumerov, F.M. (2013) Regeneration of Palladium Selective Hy- drogenation Catalyst by Supercritical Fluid Extraction Process. Vestnik Kazanskogo Tekhnologicheskogo Universiteta, 16, 20-23.