Farid M. Gumerov, Ayrat A. Sagdeev, Rustam F. Gallyamov, Albina T. Galimova, Kamil A. Sagdeev

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Federal State Budgetary Educational Institution of Higher Professional Education “Kazan National Research Technological University”, Kazan, Russia.
Nizhnekamsk Chemical Technological Institute (Branch Institute) of the Kazan National Research Technological University, Nizhnekamsk, Russia.
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Abstract: The decontaminating of catalysts nickel on kieselguhr, activated aluminum oxide and palladium catalyst LD-265 agent’s nature was analyzed. The possibility of catalyst’s regeneration was examined using supercritical CO2 extraction. Regeneration of coked catalysts was carried out at 70oC and 150oC in the pressure range 10 - 30 MPa by pure and modified supercritical CO2. Methanol and dimethylsulfoxide were used as modifiers (co-solvents) of supercritical CO2. The kinetics of supercritical CO2 regeneration process was studied. The activity of regenerated catalysts was measured.

Keywords: Nickel on Kieselguhr Catalyst; Activated Aluminum Oxide; Palladium Catalyst LD-265; Supercritical Carbon Dioxide; Regeneration

Cite this paper: Gumerov, F. , Sagdeev, A. , Gallyamov, R. , Galimova, A. and Sagdeev, K. (2014) Regeneration of the Catalysts by Supercritical Fluid Extraction. International Journal of Analytical Mass Spectrometry and Chromatography, 2, 1-14. doi: 10.4236/ijamsc.2014.21001.

References

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[3]   Gallyamov, R.F., Sagdeev, A.A., Gumerov, F.M. and Gabitov, F.R. (2010) Regeneration of “Nickel on Kieselguhr” Catalyst Using Supercritical Carbon Dioxide. Supercritical Fluids: Theory and Practice, 5, 40-51.

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[7]   Apparatus for Studying the Solubility of Substances Using Supercritical Fluids. Useful Model Patent RF No.133012 published on October 10, 2013.

[8]   State Standard (GOST) 8136-85 Activated Alumina.

[9]   Galimova, A.T., Sagdeev, A.A. and Gumerov, F.M. (2013) Izvestiya vyshih uchebnuh zavedeny. Seriya Khimiya i khimicheskaya tekhnologiya, 56, 65-68.

[10]   Galimova, A.T., Sagdeev, A.A. and Gumerov, F.M. (2013) The Solubility of the Acetophenon and Methylphenylcarbinol in Supercritical Carbon Dioxide. Vestnik Kazanskogo Tekhnologicheskogo Universiteta, 16, 296-298.

[11]   Sagdeev, K.A., Gallyamov, R.F., Sagdeev, A.A. and Gumerov, F.M. (2013) Regeneration of Palladium Selective Hy- drogenation Catalyst by Supercritical Fluid Extraction Process. Vestnik Kazanskogo Tekhnologicheskogo Universiteta, 16, 20-23.