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 AMPC  Vol.4 No.3 , March 2014
Mechano-Synthesized Orthoferrite Starting from Wüstite Assisted by SPS
Abstract: Stoichiometric mixtures of FeO and Y2O3 were milled and heat treated to obtain yttrium iron garnet, Y3Fe5O12. Two types of heating systems were used: one, a spark plasma sintering machine and the second, an electrical oven. The magnetic properties of the resulting specimens have been analyzed and discussed as a function of the grain size and the particles’ morphology. The partial formation of garnet and orthoferrite phases was revealed on the obtained powder through microstructural analyses after 9 h of ball milling. The milled powders were transformed into the orthoferrite phase after the SPS-treatment at 700°C and 900°C. Magnetic-saturation studies revealed magnetic responses up to 12.7 emu/g for specimens SPS-treated at 700°C, whereas 2.1 emu/g for samples SPS-treated at 900°C. Conventionally treated specimens at 700°C developed 0.36 emu/g of magnetization, while 0.93 emu/g was registered for those treated at 900°C.
Cite this paper: Cortés-Escobedo, C. , Sánchez-De Jesus, F. , Bolarín-Miró, A. , Nowak, S. , Juárez-Camacho, E. , de la Torre, S. and Valenzuela, R. (2014) Mechano-Synthesized Orthoferrite Starting from Wüstite Assisted by SPS. Advances in Materials Physics and Chemistry, 4, 43-49. doi: 10.4236/ampc.2014.43007.
References

[1]   Ali, W.F.F.W., Othman, M., Ain, M.F. and Abdullah, N.S. (2013) Studies on the Formation of Yttrium Iron Garnet (YIG) through Stoichiometry Modification Prepared by Conventional Solid-State Method. Journal of the European Ceramic Society, 33, 1317-1324.
http://dx.doi.org/10.1016/j.jeurceramsoc.2012.12.016

[2]   Paesano Jr., A., Zanatta, S.C., de Medeiros, S.N., Cótica, L.F. and da Cunha, J.B. (2005) Mechanosynthesis of YIG and GdIG: A Structural and Mössbauer Study. Hyperfine Interactions, 161, 211-220.
http://dx.doi.org/10.1007/s10751-005-9193-1

[3]   Mergen, A. and Qureshi, A. (2008) Characterization of YIG Nanopowders by Mechanochemical Synthesis. Journal of Alloys and Compounds, 478, 741-744.
http://dx.doi.org/10.1016/j.jallcom.2008.11.133

[4]   Garskaite, E., Gibson, K., Leleckaite, A., Glaser, J., Niznansky, D., Kareiva, A. and Meyer, H.J. (2006) On the Synthesis and Characterization of Iron-Containing Garnets (Y3Fe5O12, YIG and Fe3Al5O12, IAG). Chemical Physics, 323, 204-210.
http://dx.doi.org/10.1016/j.chemphys.2005.08.055

[5]   Rashad, M.M., Hessien, M.M., El-Midany, A. and Ibrahim, I.A. (2008) Effect of Synthesis Conditions on the Preparation of YIG Powders via Co-Precipitation Method. Journal of Magnetism and Magnetic Materials, 321, 3752-3757.
http://dx.doi.org/10.1016/j.jmmm.2009.07.033

[6]   Rossol, F.C. (1970) Domain-Wall Mobility in Yttrium Orthoferrite. Physical Review Letters, 24, 1021-1023.
http://dx.doi.org/10.1103/PhysRevLett.24.1021

[7]   Didosyan, Y.S. and Hauser, H. (1998) Observation of Bloch Lines in Yttrium Orthoferrite. Physics Letters A, 238, 395-397. http://dx.doi.org/10.1016/S0375-9601(97)00757-3

[8]   Didosyan, Y.S. and Barash, V.Y. (1995) Faraday Effect in Yttrium Orthoferrite in the Range 1280 - 1600 nm. Journal of Magnetism and Magnetic Materials, 151, 207-210.
http://dx.doi.org/10.1016/0304-8853(95)00374-6

[9]   Rajendran, M. and Bhattacharya, A.K. (2006) Nanocrystalline Orthoferrite Powders: Synthesis and Magnetic Properties. Journal of the European Ceramic Society, 26, 3675-3679.
http://dx.doi.org/10.1016/j.jeurceramsoc.2006.01.008

[10]   Didosyan, Y.S., Hauser, H., Wolfmayr, H., Nicolics, J. and Fulmek, P. (2003) Magneto-Optical Rotational Speed Sensor. Sensors and Actuators A, 106, 168-171.
http://dx.doi.org/10.1016/S0924-4247(03)00158-4

[11]   Fernández-García, L., Suarez, M. and Menéndez, J.L. (2010) Synthesis of Mono and Multidomain YIG Particles by Chemical Coprecipitation or Ceramic Procedure. Journal of Alloys and Compounds, 495, 196-199.
http://dx.doi.org/10.1016/j.jallcom.2010.01.119

[12]   Zhang, W., Guo, C., Ji, R., Fang, C. and Zeng, Y. (2011) Low-Temperature Synthesis and Microstructure-Property Study of Single-Phase Yttrium Iron Garnet (YIG) Nanocrystals via a Rapid Chemical Coprecipitation. Materials Chemistry and Physics, 125, 646-651.
http://dx.doi.org/10.1016/j.matchemphys.2010.10.004

[13]   Hosseini Vajargah, S., Madaah Hosseini, H.R. and Nemati, Z.A. (2007) Preparation and Characterization of Yttrium Iron Garnet (YIG) Nanocrystalline Powders by Auto-Combustion of Nitrate-Citrate Gel. Journal of Alloys and Compounds, 430, 339-343.
http://dx.doi.org/10.1016/j.jallcom.2006.05.023

[14]   Vaqueiro, P., López-Quintela, M.A., Rivas, J. and Greneche, J.M. (1997) Annealing Dependence of Magnetic Properties in Nanostructured Particles of Yttrium Iron Garnet Prepared by Citrate Gel Process. Journal of Magnetism and Magnetic Materials, 169, 56-68.
http://dx.doi.org/10.1016/S0304-8853(96)00728-7

[15]   Guo, X.Z., Ravi, B.G., Devi, P.S., Hanson, J.C., Margolies, J., Gambino, R.J., Parise, J.B. and Sampath, S. (2005) Synthesis of Yttrium Iron Garnet (YIG) by Citrate-Nitrate Gel Combustion and Precursor Plasma Spray Processes. Journal of Magnetism and Magnetic Materials, 295, 145-154.
http://dx.doi.org/10.1016/j.jmmm.2005.01.007

[16]   Yang, Q., Zhang, H., Liu, Y., Wen, Q. and Jia, L. (2008) The Magnetic and Dielectric Properties of Microwave Sintered Yttrium Iron Garnet (YIG). Materials Letters, 62, 2647-2650.
http://dx.doi.org/10.1016/j.matlet.2008.01.040

[17]   Fu, Y., Lin, C., Tay, K. and Yao, Y. (2008) Yttrium Iron Garnet Ceramic Prepared from Microwave-Induced Combustion. Journal of Electroceramics, 21, 677-680.
http://dx.doi.org/10.1007/s10832-007-9270-8

[18]   Suryanarayana, C. (2004) Mechanical Alloying and Milling. Marcel Dekker, New York.
http://dx.doi.org/10.1201/9780203020647

[19]   Fernández-García, L., Suárez, M. and Menéndez, J.L. (2010) Low Temperature Spark Plasma Sintering of YIG Powders. Journal of Alloys and Compounds, 502, 132-135.
http://dx.doi.org/10.1016/j.jallcom.2010.04.117

[20]   Jacob, K.T. and Rajitha, G. (2012) Nonstoichiometry, Defects and Thermodynamic Properties of YFeO3, YFe2O4 and Y3Fe5O12. Solid State Ionics, 224, 32-40.
http://dx.doi.org/10.1016/j.ssi.2012.07.003

[21]   Veres, A., Noudem, J. G., Fourrez, S. and Bailleul, G. (2006) The Influence of Iron Substitution to Manganese on the Physical Properties of YMnO3. Solid State Sciences, 8, 137-141.
http://dx.doi.org/10.1016/j.solidstatesciences.2005.11.002

[22]   Cortés-Escobedo, C.A., Bolarín-Miró, A.M., Sánchez de Jesús, F., Valenzuela, R., Juárez Camacho, E.P. and Ammar, S. (2013) Y3Fe5O12 Prepared by Mechanosynthesis from Different Iron Sources. Advances in Materials Physics and Chemistry, 3, 41-46.
http://dx.doi.org/10.4236/ampc.2013.31A006

[23]   Benard, J. (1949) Recherches sur les variations de composition du protoxyde de fer. Bulletin de la Societé Chimique de France, 109-116.

[24]   Paton, M.G. and Maslen, E.N. (1965) A Refinement of the Crystal Structure of Yttria. Acta Crystallographica B, 19, 307-310.
http://dx.doi.org/10.1107/S0365110X65003365

[25]   Bonnet, M., Delapalme, A., Fuess, H. and Thomas, M. (1975) Refinement of the Structure of Yttrium Iron Garnet (YIG). A Case of Severe Extinction and Absorption. Acta Crystallographica Section B, 31, 2233-2240.
http://dx.doi.org/10.1107/S0567740875007315

[26]   Wu, A., Shen, H., Xu, J., Wang, Z., Jiang, L., Luo, L., Yuan, Sh., Cao, Sh. and Zang, H. (2012) Crystal Growth and Magnetic Property of YFeO3 Crystal. Bulletin of Materials Science, 35, 259-263.
http://dx.doi.org/10.1007/s12034-012-0278-6

[27]   Owen, E.A and Williams, G.I. (1948 A Low-Temperature X-Ray Camera. Journal of Scientific Instruments, 25, 440-444.

[28]   Blake, R.L., Hessevick, R.E., Zoltai, T. and Finger, L.W. (1966) Refinement of the Hematite Structure. American Mineralogist, 51, 123-129.

[29]   Gil, D.M., Navarro, M.C., Lagarrigue, M.C., Guimpel, J., Carbonio R.E. and Gómez, M.I. (2011) Synthesis and Structural Characterization of Perovskite YFeO3 by Thermal Decoposition of a Cyanocomplexprecursory[Fe(CN6)]·4H2O. Journal of Thermal Analysis and Calorimetry, 183, 889-896.
http://dx.doi.org/10.1007/s10973-010-1176-z

[30]   Danan, H., Herr, A. and Meyer, A.J.P. (1968) New Determinations of the Saturation Magnetization of Nickel and Iron. Journal of Applied Physics, 39, 669-670.
http://dx.doi.org/10.1063/1.2163571

 
 
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