OJAppS  Vol.3 No.8 , December 2013
The Relative Viscosity of Concentrated Rubber Suspensions and Viscoelastic Modulus of 3D Сross-Linked Elastomers Filled with Solid Particles
ABSTRACT

For the first time, this paper describes the concentration dependence of the relative dynamic viscosity coefficient of rubber suspensions and the initial viscoelastic modulus of 3D cross-linked elastomers on the maximum volume filling with solid polydisperse particles. It allows to predict the rheological and mechanical properties of the polymer compositions being developed now. In this paper, we present the first experimental study of the pole of the concurrent lines of the concentration dependence in the coordinates of the linear form. The pole validates the invariant value of the constant of the developed equation and allows the experimental determination of the maximum volume filling of polymer binders filled with separate fractions or polydisperse mixtures. The results of the study are recommended for use in developing new polymer composite materials.


Cite this paper
A. Ermilov and E. Nurullaev, "The Relative Viscosity of Concentrated Rubber Suspensions and Viscoelastic Modulus of 3D Сross-Linked Elastomers Filled with Solid Particles," Open Journal of Applied Sciences, Vol. 3 No. 8, 2013, pp. 477-481. doi: 10.4236/ojapps.2013.38057.
References
[1]   L. E. Nielsen, “Mechanical Properties of Polymer and Polymer Composition,” Chemistry, 1978, p. 310.

[2]   J. R. Rutgers, “Relative Viscosity and Concentration,” Rheologica Acta, Vol. 2, No. 4, 1962, pp. 305-348. http://dx.doi.org/10.1007/BF01976051

[3]   H. Eilers, “Die Zahigkeiteinekonzentrieren Suspensionen,” Kolloid-Zeitschrift, Vol. 97, No. 3, 1941, pp. 313-317. http://dx.doi.org/10.1007/BF01503023

[4]   M. Mooney, “Rheology of Concentration Suspensions,” Journal of Colloid Science, Vol. 6, No. 2, 1951, pp. 162-156. http://dx.doi.org/10.1016/0095-8522(51)90036-0

[5]   J. S. Chong, E. B. Christiansen and A. D. Baer, “Rheological Properties of Concentration Suspensions,” Journal of Applied Polymer Science, Vol. 15, No. 8, 1971, pp. 2007-2024. http://dx.doi.org/10.1002/app.1971.070150818

[6]   R. Fedors, “Effect of Filler on the Mechanical Behaviour of Elastomers. Relationships between the Small Strain Modulus and the Type and Concentration of Filler,” Polymer, Vol. 20, No. 3, 1979, pp. 324-328. http://dx.doi.org/10.1016/0032-3861(79)90095-8

[7]   A. Einstein, “Viscosity of the Dilution Suspensions,” Kolloid-Zeitschrift, Vol. 27, No. 3, 1920, pp. 137-139. http://dx.doi.org/10.1007/BF01437675

[8]   A. S. Ermilov, E. M. Nurullaev and V. N. Alikin, “Waterproof Frost-Resistant Road Asphalt Coating,” Patent Number 2473581, Russian Federation, 2011.

[9]   A. S. Ermilov and A. M. Fedoseev, “Combinatorial-Multiplicative Method of Calculating the Limiting Filling of Composites with Solid Dispersed Components,” Journal of Applied Chemistry, Vol. 77, No. 7, 2004, pp. 1218-1220.

 
 
Top