AMPC  Vol.3 No.7 , November 2013
An Approach on the Hydrogen Absorption in Carbon Black after Gamma Irradiation
Abstract: In this work, different samples of an industrial carbon black are used to study the hydrogen intake from an over pressurized atmosphere and its changes due to alteration of its level of crystallinity produced by γ-irradiation. The monitoring of the hydrogen adsorption was made by means of thermogravimetric analysis and by measurements of some electrical parameters as the Seebeck coefficient. X-ray diffraction shows that the irradiation diminishes the level of crystalline perfection. These results show interesting possibilities to use carbon black as cheap hydrogen absorbers.  
Cite this paper: A. Madroñero, M. Culebras, A. Cantarero, C. Gómez, C. Mota, J. Amo and J. Robla, "An Approach on the Hydrogen Absorption in Carbon Black after Gamma Irradiation," Advances in Materials Physics and Chemistry, Vol. 3 No. 7, 2013, pp. 295-298. doi: 10.4236/ampc.2013.37040.

[1]   S. Jaybhaye, M. Sharon, D. Sathiyamoorthy and K. Dasgupta, “Semiconducting Carbon Nanofibers and Hydrogen Storage,” Synthesis and Reactivity in Inorganic, MetalOrganic, and Nano-Metal Chemistry, Vol. 37, No. 6, 2007, pp. 473-476.

[2]   B. Panella, M. Hirscher and S. Roth, “Hydrogen Adsorption in Different Carbon Nanostructures,” Carbon, Vol. 43, No. 10, 2005, pp. 2209-2214.

[3]   M. Molina-Sabio and F. Rodríguez-Reinoso, “Role of Chemical Activation in the Development of Carbon Porosity,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 241, No. 1, 2004, pp. 15-25.

[4]   A. Rejifu, H. Noguchi, T. Ohba, H. Kanoh, F. Rodriguez-Reinoso and K. Kaneko, “Adsorptivities of Extremely High Surface Area Activated Carbon Fibres for CH4 and H2,” Adsorption Science and Technology, Vol. 27, No. 9, 2009, pp. 877-881.

[5]   F. Banhart, “Irradiation Effects in Carbon Nanostructures,” Report on Progress in Physics, Vol. 62, No. 8, 1999, pp. 1181-1221.

[6]   V. Skakalova, U. Dettlaff-Weglikowska and S. Roth, “Gamma-Irradiated and Functionalized Single Wall Nanotubes,” Diamond and Related Materials, Vol. 13, No. 2, 2004, pp. 296-298.

[7]   E. Papirer, S. Li, H. Balard and J. Jagiello, “Surface Energy and Adsorption Energy Distribution Measurements on Some Carbon Blacks,” Carbon, Vol. 29, No. 8, 1991, pp. 1135-1143.

[8]   A. Ansón, J. Jagiello, J. B. Parra, M. L. Sanjuán, Ana M. Benito, W. K. Maser and M. T. Martinez, “Porosity, Surface Area, Surface Energy, and Hydrogen Adsorption in Nanostructured Carbons,” Journal of Physical Chemistry B, Vol. 108, No. 40, 2004, pp. 15820-15826.

[9]   J. de Boor and V. Schmidt, “Complete Characterization of Thermoelectric Materials by a Combined Van der Pauw Approach,” Advanced Materials, Vol. 22, No, 38 2010, pp. 4303-4307.

[10]   M. M. K. Salem, P. Braeuer, M. V. Szombathely, M. Heuchel, P. Harting, K. Quitzsch and M. Jaroniec, “Thermodynamics of High-Pressure Adsorption of Argon, Nitrogen, and Methane on Microporous Adsorbents,” Langmuir, Vol. 14, No. 12, 1998, pp. 3376-3389.

[11]   P. Malbrunot, D. Vidal, J. Vermesse, R. Chahine and T. K. Bose, “Adsorption Measurements of Argon, Neon, Krypton, Nitrogen and Methane on Activated Carbon Up to 650 MPa,” Langmuir, Vol. 8, No. 2, 1992, pp. 577-580.

[12]   V. Jiménez, A. Ramírez-Lucas, P. Sánchez, J. L. Valverde and A. Romero, “Hydrogen Storage in Different Carbon Materials: Influence of the Porosity Development by Chemical Activation,” Applied Surface Science, Vol. 258, No. 7, 2012, pp. 2498-2509.

[13]   J. I. Langford and A. J. C. Wilson, “Scherresr after Sixty Years: An Survey and Some New Results in the Determination of Crystalline Size,” Journal of Applied Cristallography, Vol. 11, No. 2, 1978, pp. 102-113.

[14]   Z. Xu, L. Chen, L. Liu, X. Wu and L. Chen, “Structural Changes in Multi-Walled Carbon Nanotubes Caused by γ-Ray Irradiation,” Carbon, Vol. 49, No. 1, 2011, pp. 350-351.

[15]   C. Marliere, P. Poncharal, L. Vaccarini and A. Zahab, “Effect of Gas Adsorption on the Electrical Properties of Single Walled Carbon Nanotubes Mats,” International Materials Reviews, Vol. 593, 2000, pp. 173-176.