MSA  Vol.4 No.11 , November 2013
New Route for Novel Polycarboxylic Starch Hybrid
ABSTRACT

Starch was polymerized with methacrylic acid (MAA) to different magnitudes of poly (MAA) using potassium persulphate/sodium thiosulphate redox initiation system. The polymerization products are referred to as composite. The latter consists of poly (MAA)-starch graft copolymer, poly (MAA) in the form of homopolymer, oxidized starch brought about under the influence of the initiator and intact starch. At this end, the composite, the copolymer, and the untreated (native) starch were subjected to carboxymethylation under different conditions and the rheological properties of these starchbased on products before and after carboxymethylation examined. Results obtained disclosed that the susceptibility of these products toward carboxymethylation follows the order: native starch > Copolymer > composite. Meanwhile, these products exhibit non-Newtonian thixotropic behavior before carboxymethylation; and their rheology signifies the order: Composite > copolymer > native starch whereas after carboxymethylation these products are characterized by non-Newtonian Pseudoplastic behavior. For a given rate of shear, the apparent viscosity follows the order: native starch > composite > copolymer > carboxymethyl composite > carboxymethyl starch > carboxymethyl copolymer, in contrast with pseudoplasticity which reveals an opposite order. It was also shown that the apparent viscosity increases by increasing poly (MAA) in the copolymer and composite and that redrying of the copolymer and the composite after normal precipitation and drying causes a considerable enhancement in the apparent viscosity of these products.


Cite this paper
A. Hebeish, A. Mousa, M. Ramadan and A. Saleh, "New Route for Novel Polycarboxylic Starch Hybrid," Materials Sciences and Applications, Vol. 4 No. 11, 2013, pp. 695-703. doi: 10.4236/msa.2013.411087.
References
[1]   R. L. Whistler, “History and Future Expectations of Starch Uses,” In: R. L. Whistler, J. N. BeMiller and E. F. Paschall, Eds., Starch Chemistry and Technology, 2nd Edition, Academic Press, London, 1984.

[2]   J. R. Daniel, “Starch and Other Polysaccharides,” Ullmann’s Encyclopaedia of Industrial Chemistry, Vol. 25, 1994, pp. 1-63.

[3]   O. B. Wurzburg, “Converted Starches,” In: O. B. Wurzburg, Ed., Modified Starches: Properties and Uses, CRC Press, Florida, 1987.

[4]   I. Abdel-Thalouth, L. H. Hana and A. A. Hebeish, “Oxidation of Carboxymethyl Starch with Sodium Hypochlorite,” Textile Research Journal, Vol. 37, 1977, pp. 209-211.

[5]   A. Hebeish, M. H. El-Rafie, A. Higazy and M. Ramadan, “Synthesis, Characterization and Properties of Polyacrylamide-Starch Composites,” Starch-Starke, Vol. 48, No. 5, 1996 , pp. 175-179.

[6]   A. Hebeish, M. H. El-Rafie, A. Higazy and M. A. Ramadan, “Preparation and Characterization of Water Soluble Poly(AA-)-Starch Composite,” Al-Azhar Bulltien of Science, Vol. 6, No. 1 ,1995, pp. 789-793.

[7]   A. Hebeish, A. Waly, M. H. El-Rafie and M. A. ElSheikh, “Synthesis and Characterization of New Polymeric Materials Based on Water Soluble Starch Composites,” The 213th National Meeting, San Francisco, 1997.

[8]   A. Hebeish, I. Khalil and A. Hashem, “Carboxymethylation of Starch and Oxidized Starche,” Starch/Starke, Vol. 42, No. 5, 1990, pp. 185-191.
http://dx.doi.org/10.1002/star.19900420506

[9]   O. B. Wurzbrg, “Cross Linked Starches in Modified Starches Properties and Uses,” In: O. B. Wurzburg, Ed., CRC Press, Florida, 1987.

[10]   A. Hebeish, M. K. Beliakova and A. Bayazeed, “Improved Synthesis of Poly(Maa)-Starch Graft Copolymers,” Journal of Applied Polymer Science, Vol. 68, No. 10, 1998, pp. 1709-1715.
http://dx.doi.org/10.1002/(SICI)1097-4628(19980606)68:10<1709::AID-APP21>3.0.CO;2-Q

[11]   A. Hebeish and I. Khalil, “Characterization of the Reaction Products for Starch and Acrylonitrile,” Starch/Starke, Vol. 40, No. 3, 1988, pp. 104-107.

[12]   A. Hebeish, M. H. El-Rafie, A. Higazy and M. A. Ramadan, “Poly(Acrylic Acid)-Starch Composites. A Key for Improving Sizeability and Desizeability of Starch from Cotton Textiles,” Starch/Starke, Vol. 44, 1992, pp. 101-107. http://dx.doi.org/10.1002/star.19920440305

 
 
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