MSCE  Vol.1 No.5 , October 2013
Synthesis, Characterization and Performance of a New Type of Alkylene Triphenyl Double Quaternary Phosphonium Salt
ABSTRACT
ByBimolecular Nucleophilic Substitution, four new types of alkylene triphenyl double quaternary phosphonium salt were synthesized respectively by using triphenylphosphine, 1,3-dibromopropane, 1,6-dibromohexane,1,10-dibromo- decane, 1,12-dibromododecane as raw materials and using DMAC as the solvent, under a certain temperature and reac- tion time. The productivity is 58% - 83%. The molecular structures of the products were characterized by IR, NMR and elemental analysis. The sterilizing effect of 1,6-hexylidene triphenyl double phosphonium bromide(HTDPB) and 1,12- dodecylidene triphenyl double phosphonium bromide(DoTDPB) was evaluated by using extinct dilution method.The experimental result shows that the sterilizing effect of DoTDPB is better than the effect of HTDPB under the same drug concentration and contact time. When the concentration of DoTDPB was 20 mg/L and the contact time was 0.5 h, the sterilizing rate of DoTDPB used to kill saprophytic bacteria (TGB), sulfate-reducing bacteria (SRB) and iron bacteria (IB) was 95.56%, 84% and 99.58% respectively.

Cite this paper
Wei, W. , Yuan, B. , Lv, S. , Liao, Q. and Huang, J. (2013) Synthesis, Characterization and Performance of a New Type of Alkylene Triphenyl Double Quaternary Phosphonium Salt. Journal of Materials Science and Chemical Engineering, 1, 61-65. doi: 10.4236/msce.2013.15013.
References
[1]   A. Kanazawa, T. Lkeda and T. Endo, “Synthesis and Antimicrobial Activity of Dimethyl- and Trimethyl-Substituted Phosphonium Salts with Alkyl Chains of Various Lengths,” Antimicrobial Agents and Chemotherapy, Vol. 38, No. 5, 1994, pp. 945-952. http://dx.doi.org/10.1128/AAC.38.5.945

[2]   J. Curtze, “Phosphonium Salts and Fungicidal Use,” US Patent No. 4,933,328, 1990.

[3]   D. Villemin, M. A. Didi and B. Makhoukhi, “Selective Synthesis of Mono or Diphosphonium Salts-Solvent Effect,” Letters in Organic Chemistry, Vol. 4, No. 7, 2007, pp. 509-511. http://dx.doi.org/10.2174/157017807782006272

[4]   Z.-W. Lou and X.-M. Shang, “Synthesis and Antitumor Activities of Sulfonated Triphenylphosphoniums,” Chinese Journal of Medicinal Chemistry, Vol. 10, No. 3, 2000, pp. 168-171.

[5]   SY/T 0532-2012, “Analysis Method of the Bacteria for Oilfield Injecting Water. Disappearing Dilution Method”.

[6]   GB 11893-1989, “Water Quality-Determination of Total Phosphorus-Ammonium Molybdate Spectrophotometric Method”.

 
 
Top