The Mechanical Properties of the System and Training Zr59Nb5Cu18Ni8AL10 Bulk Metallic Glasses
ABSTRACT
In the present work, the glass formation of Zr59Nb5Cu18Ni8Al10 (numbers indicate at %) alloy with diameter of 2 mm was prepared through water-cooled copper mold casting and in a ribbon form by the single roller melt-spinning method. This study is primarily devoted to evaluating the results obtained with the two methods of the development. The thermal stability was evaluated by differential scanning calorimetry (DSC) at a heating rate of 10℃/mn. The characteristic data of the bulk metallic glass are presented, including glass transition temperature (Tg) and crystallization temperature (Tx). The microstructure and constituent phases of the alloy composite have been analyzed by using X-ray diffraction, and observed by Scanning Electron Microscopy (SEM). The mechanical properties of bulk Zr59Nb5Cu18Ni8Al10 were alloy measured by compression tests at room temperature.
In the present work, the glass formation of Zr59Nb5Cu18Ni8Al10 (numbers indicate at %) alloy with diameter of 2 mm was prepared through water-cooled copper mold casting and in a ribbon form by the single roller melt-spinning method. This study is primarily devoted to evaluating the results obtained with the two methods of the development. The thermal stability was evaluated by differential scanning calorimetry (DSC) at a heating rate of 10℃/mn. The characteristic data of the bulk metallic glass are presented, including glass transition temperature (Tg) and crystallization temperature (Tx). The microstructure and constituent phases of the alloy composite have been analyzed by using X-ray diffraction, and observed by Scanning Electron Microscopy (SEM). The mechanical properties of bulk Zr59Nb5Cu18Ni8Al10 were alloy measured by compression tests at room temperature.
Cite this paper
N. Chakri, B. Bendjemil and M. Baricco, "The Mechanical Properties of the System and Training Zr59Nb5Cu18Ni8AL10 Bulk Metallic Glasses," Advances in Chemical Engineering and Science, Vol. 3 No. 4, 2013, pp. 274-277. doi: 10.4236/aces.2013.34034.
N. Chakri, B. Bendjemil and M. Baricco, "The Mechanical Properties of the System and Training Zr59Nb5Cu18Ni8AL10 Bulk Metallic Glasses," Advances in Chemical Engineering and Science, Vol. 3 No. 4, 2013, pp. 274-277. doi: 10.4236/aces.2013.34034.
References
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http://dx.doi.org/10.1063/1.1872214 [10] Y. J. Huang, J. Shen, J. F. Sun and X. B. Yu, “A New Ti-Zr-Hf-Cu-Ni-Si-Sn Bulk Amorphous Alloy with High Glass-Forming Ability,” Journal of Alloys and Compounds, Vol. 427, No. 1-2, 2007, pp. 171-175.
http://dx.doi.org/10.1016/j.jallcom.2006.03.006 [11] X. F. Wu, Z. Y. Suo, Y. Si, L. K. Meng and K. Q. Qiu, “Bulk Metallic Glass Formation in a Ternary Ti-Cu-Ni Alloy System,” Journal of Alloys and Compounds, Vol. 452, No. 2, 2008, pp. 268-272.
http://dx.doi.org/10.1016/j.jallcom.2006.11.010 [12] H. M. Fu, H. F. Zhang, H. Wang and Z. Q. Hu, “Cu-Based Bulk Amorphous Alloy with Larger Glass-Forming Ability and Supercooled Liquid Region,” Journal of Alloys and Compounds, Vol. 458, No. 1-2, 2008, pp. 390-393. http://dx.doi.org/10.1016/j.jallcom.2007.03.114 [13] Yu V. Milman, B. A. Galanov and S. I. Chugunova, “Plasticity Characteristic Obtained Through Hardness Measurement,” Acta Metallurgica et Materialia, Vol. 41, No. 9, 1993, p. 2523.
[1] P. Duwez, R. H. Willens and W. Klement, “Metastable Electron Compound in Ag-Ge Alloys,” Journal of Applied Physics, Vol. 31, No. 6, 1960, p. 1137.
http://dx.doi.org/10.1063/1.1735778 [2] J. Shen, Q. J. Chen, J. F. Sun, H. B. Fan and G. Wang, “Exceptionally High Glass-Forming Ability of an FeCo-CrMoCBY Alloy,” Applied Physics Letters, Vol. 86, No. 15, 2005, Article ID: 151907.
http://dx.doi.org/10.1063/1.1897426 [3] Q. K. Jiang, X. P. Nie, Y. G. Li, Y. Jin, Z. Y. Chang, X. M. Huang and J. Z. Jiang, “Ni-Free Zr-Based Bulk Metallic Glasses with critical Diameter above 20 mm,” Journal of Alloys and Compounds, Vol. 443, No. 1-2, 2008, pp. 191-194. http://dx.doi.org/10.1016/j.jallcom.2007.04.188 [4] A. Peker and W. L. Johnson, “A Highly Processable Metallic Glass: Zr41.2Ti13.8Cu12.5Ni10.0Be22.5,” Applied Physics Letters, Vol. 63, No. 17, 1993, p. 2342.
http://dx.doi.org/10.1063/1.110520 [5] H. Choi-Yim, D. H. Xu and W. L. Johnson, “Ni-Based Bulk Metallic Glass Formation in the Ni-Nb-Sn and Ni-Nb-Sn-X (X = B,Fe,Cu) Alloy Systems,” Applied Physics Letters, Vol. 82, No. 7, 2003, pp. 1030-1031.
http://dx.doi.org/10.1063/1.1544434 [6] S. J. Pang, C. H. Shek, K. Asami, A. Inoue and T. Zhang, “Formation and Corrosion Behaviour of Glassy Ni-Nb-Ti-Zr-Co(Cu),” Proceeding of the 12th International Symposium on Metastable and Nano-Materials, Original Reseach Article J. Alloys Compd., Vol. 434-435, 2007, pp. 240-243. [7] X. K. Xi, D. Q. Zhao, M. X. Pan, W. H. Wang, Y. Wu and J. J. Lewandowski, “Fracture of Brittle Metallic Glasses: Brittleness or Plasticity,” Physical Review Letters, Vol. 94, No. 12, 2005, Article ID: 125510.
http://dx.doi.org/10.1103/PhysRevLett.94.125510 [8] N. Nishiyama and A. Inoue, “Direct Comparison between Critical Cooling Rate and Some Quantitative Parameters for Evaluation of Glass-Forming Ability in Pd-Cu-Ni-P Alloys,” Materials Transactions, Vol. 43, No. 8, 2002, pp. 1913-1917. http://dx.doi.org/10.2320/matertrans.43.1913 [9] F. Q. Guo, H. J. Wang, S. J. Poon and G. J. Shiflet, “Ductile Titanium-Based Glassy Alloy Ingots,” Applied Physics Letters, Vol. 86, No. 9, 2005, Article ID: 091907.
http://dx.doi.org/10.1063/1.1872214 [10] Y. J. Huang, J. Shen, J. F. Sun and X. B. Yu, “A New Ti-Zr-Hf-Cu-Ni-Si-Sn Bulk Amorphous Alloy with High Glass-Forming Ability,” Journal of Alloys and Compounds, Vol. 427, No. 1-2, 2007, pp. 171-175.
http://dx.doi.org/10.1016/j.jallcom.2006.03.006 [11] X. F. Wu, Z. Y. Suo, Y. Si, L. K. Meng and K. Q. Qiu, “Bulk Metallic Glass Formation in a Ternary Ti-Cu-Ni Alloy System,” Journal of Alloys and Compounds, Vol. 452, No. 2, 2008, pp. 268-272.
http://dx.doi.org/10.1016/j.jallcom.2006.11.010 [12] H. M. Fu, H. F. Zhang, H. Wang and Z. Q. Hu, “Cu-Based Bulk Amorphous Alloy with Larger Glass-Forming Ability and Supercooled Liquid Region,” Journal of Alloys and Compounds, Vol. 458, No. 1-2, 2008, pp. 390-393. http://dx.doi.org/10.1016/j.jallcom.2007.03.114 [13] Yu V. Milman, B. A. Galanov and S. I. Chugunova, “Plasticity Characteristic Obtained Through Hardness Measurement,” Acta Metallurgica et Materialia, Vol. 41, No. 9, 1993, p. 2523.