ANP  Vol.2 No.4 , November 2013
Dye-Sensitized Solar Cell with Fluorinated Gel Electrolyte: Effect of TiO2 Particle Size on Performance
ABSTRACT

We fabricated dye-sensitized solar cells including fluorinated gel electrolyte and studied about the relationship between the performance of the solar cells and the aggregation state of TiO2 nano-particles on electrodes. As for the performance of the cell, the I-V characteristics were measured under irradiation. The combination of TiO2 nanoparticles with different size plays an important role in bringing unevenness to realize a large surface area, which is critical for the high performance of the cells.


Cite this paper
Kyokane, J. and Ohmukai, M. (2013) Dye-Sensitized Solar Cell with Fluorinated Gel Electrolyte: Effect of TiO2 Particle Size on Performance. Advances in Nanoparticles, 2, 318-322. doi: 10.4236/anp.2013.24043.
References
[1]   B. O’Regan and M. Grtazel, “A Low-Cost, High-Efficiency Solar Cell Based on Dye-Sensitized Colloidal TiO2 Films,” Nature, Vol. 353, No. 1991, pp. 737-740.
http://dx.doi.org/10.1038/353737a0

[2]   M. K. Nazeeruddin, A. Kay, I. Rodicio, R. H. Baker, E. Mueller, P. Liska, N. Vlachopoulos and M. Grtazel, “Conversion of Light to Electricity by Cis-X2bis(2,2'-bipyridyl-4,4'-dicarboxylate)ruthenium(II) Charge-Transfer Sensitizers (X = Cl-, Br-, I-, CN-, and SCN-) on Nanocrystalline Titanium Dioxide Electrodes,” Journal of the American Chemistry Society, Vol. 115, No. 14, 1993, pp. 6382-6390. http://dx.doi.org/10.1021/ja00067a063

[3]   B. Li, L. Wang, B. Kang, P. Wang and Y. Qiu, “Review of Recent Progress in Solid-Satate Dye-Sensitized Solar Cells,” Solar Energy Materials and Solar Cells, Vol. 90, No. 5, 2006, pp. 549-573.
http://dx.doi.org/10.1016/j.solmat.2005.04.039

[4]   M. Grtazel, “Recent Advances in Sensitized Mesoscopic Solar Cells,” Accounts of Chemical Research, Vol. 42, No. 11, 2009, pp. 1788-1798.
http://dx.doi.org/10.1021/ar900141y

[5]   Y .Chiba, A. Islam, Y. Watanabe, R. Komiya, N. Koide and L. Han, “Dye-Sensitized Solar Cells with Conversion Efficiency of 11.1%,” Japanese Journal of Applied Physics, Vol. 45, 2006, pp. L638-L640.
http://dx.doi.org/10.1143/JJAP.45.L638

[6]   Y. H. Lai, C. Y. Lin, J. G. Chen, C. C. Wang, K. C. Huang, K. Y. Liu, K. F. Lin, J. J. Lin and K. C. Ho, “Enhancing the Performance of Dye-Sensitized Solar Cells by Incorporating Nanomica Platelets in Gel Electrolyte,” Solar Energy Materials and Solar Cells, Vol. 94, No. 4, 2010, pp. 668-674.
http://dx.doi.org/10.1016/j.solmat.2009.11.027

[7]   S. Murai, S. Mikoshiba and S. Hayase, “Influence of Alkyl Dihalide Gelators on Solidification of Dye-Sensitized Solar Cells,” Solar Energy Materials and Solar Cells, Vol. 91, No. 18, 2007, pp. 1707-1712.
http://dx.doi.org/10.1016/j.solmat.2006.12.018

[8]   T. C. Wei, C. C. Wan and Y. Y. Wang, “Preparation and Characterization of a Micro-Porous Polymer Electrolyte with Cross-Linking Network Structure for Dye-Sensitized Solar Cell,” Solar Energy Materials and Solar Cells, Vol. 91, No. 20, 2007, pp. 1892-1897.
http://dx.doi.org/10.1016/j.solmat.2007.07.005

[9]   J. Kyokane, K. Shima and H. Sawada, “Electrical Properties of Fluorinated Gel Electrolytes Using High Ionic Conducting Solution and Its Application to Secondary Battery,” Thin Solid Films, Vol. 438-439, 2003, pp. 257261. http://dx.doi.org/10.1016/S0040-6090(03)00794-6

[10]   X. Wu, L. Wang and Y. Qiu, “In Situ Synthesis of Mesoporous TiO2 Anatase Films and Their Photovoltaic Performance in Dye Sensitized Solar Cells,” Japanese Journal of Applied Physics, Vol. 45, 2006, pp. L1149-L1151. http://dx.doi.org/10.1143/JJAP.45.L1149

[11]   T. V. Nguyen, H. C. Lee and O. B. Yang, “The Effect of Pre-Thermal Treatment of TiO2 Nano-Particles on the Performances of Dye-Sensitized Solar Cells,” Solar Energy Materials and Solar Cells, Vol. 90, No. 7-8, 2006, pp. 967-981.
http://dx.doi.org/10.1016/j.solmat.2005.06.001

[12]   K. M. Lee, V. Suryanarayanan and K. C. Ho, “A Study on the Electron Transport Properties of TiO2 Electrodes in Dye-Sensitized Solar Cells,” Solar Energy Materials and Solar Cells, Vol. 91, No. 15-16, 2007, pp. 1416-1420.
http://dx.doi.org/10.1016/j.solmat.2007.03.007

[13]   M. Murayama, E. Yamazaki, N. Nishikawa, N. Hashimoto and T. Mori, “Low-Temperature Fabrication of TiO2 Necking Electrode by Sol-Gel Method and Its Application to Dye-Sensitized Solar Cell,” Japanese Journal of Applied Physics, Vol. 45, 2006, pp. 7917-7921.
http://dx.doi.org/10.1143/JJAP.45.7917

[14]   S. Uchida, M. Tomiha, N. Masaki, A. Miyazawa and H. Takizawa, “Preparation of TiO2 Nanocrystalline Electrode for Dye-Sensitized Solar Cells by 28GHz Microwave Irradiation,” Solar Energy Materials and Solar Cells, Vol. 81, No. 1, 2004, pp. 135-139.
http://dx.doi.org/10.1016/j.solmat.2003.08.020

[15]   G. Mincuzzi, L. Vesce, A. Reale, A. D. Carlo and T. M. Brown, “Efficient Sintering of Nanocrystalline Titanium Dioxide Films for Dye Solar Cells via Raster Scanning Laser,” Applied Physics Letters, Vol. 95, No. 10, 2009, Article ID: 103312. http://dx.doi.org/10.1063/1.3222915

[16]   L. N. Lewis, J. L. Spivack, S. Gasaway, E. D. Williams, J. Y. Gui, V. Manivannan and O. P. Siclovan, “A Novel UV-Mediated Low-Temperature Sintering of TiO2 for Dye-Sensitized Solar Cells,” Solar Energy Materials and Solar Cells, Vol. 90, No. 7-8, 2006, pp. 1041-1051.
http://dx.doi.org/10.1016/j.solmat.2005.05.019

[17]   J. Halme, J. Saarinen and P. Lund, “Spray Deposition and Compression of TiO2 Nanoparticle Films for Dye-Sensitized Solar Cells on Plastic Substrates,” Solar Energy Materials and Solar Cells, Vol. 90, No. 7-8, 2006, pp. 887-899. http://dx.doi.org/10.1016/j.solmat.2005.05.013

[18]   S. M. A. Fateminia, R. Y. Rad, T. Ebadzadeh and S. Ghashghai, “Effect of Dispersing Media on Microstructure of Electrophoretically Deposited TiO2 Nanoparticles in Dye-Sensitized Solar Cells,” Applied Surface Science, Vol. 257, No. 20, 2011, pp. 8500-8505.
http://dx.doi.org/10.1016/j.apsusc.2011.05.002

[19]   L. J. Diguna, M. Murakami, A. Sato, Y. Kumagai, T. Ishihara, N. Kobayashi, Q. Shen and T. Toyoda, “Photoacoustic and Photoelectrochemical Characterization of Inverse Opal TiO2 Sensitized with CdSe Quantum Dots,” Japanese Journal of Applied Physics, Vol. 45, 2006, pp. 5563-5568. http://dx.doi.org/10.1143/JJAP.45.5563

[20]   B. Ma, F. Luo, L. Wang, X. Wu, C. Zhan and Y. Qiu, “Structure and Morphology of Nanosized PbS on TiO2 Nanoporous Film in Dye-Sensitized Solar Cells,” Japanese Journal of Applied Physics, Vol. 46, 2007, pp. 7745-7748. http://dx.doi.org/10.1143/JJAP.46.7745

[21]   C. Wen, K. Ishikawa, M. Kishima and K. Yamada, “Effects of Silver Particles on the Photovoltaic Properties of Dye-Sensitized TiO2 Thin Films,” Solar Energy Materials and Solar Cells, Vol. 61, No. 4, 2000, pp. 339-351.
http://dx.doi.org/10.1016/S0927-0248(99)00117-8

[22]   S. Chappel and A. Zaban, “Nanoporous SnO2 Electrodes for Dye-Sensitized Solar Cells Improved Cell Performance by the Synthesis of 18 nm SnO2 Colloids,” Solar Energy Materials and Solar Cells, Vol. 71, No. 2, 2002, pp. 141-152.
http://dx.doi.org/10.1016/S0927-0248(01)00050-2

[23]   W. P. Tai, K. Inoue and J. H. Oh, “Ruthenium Dye-Sensitized SnO2/TiO2 Coupled Solar Cells,” Solar Energy Materials and Solar Cells, Vol. 71, No. 4, 2002, pp. 553-557.
http://dx.doi.org/10.1016/S0927-0248(01)00140-4

[24]   W. P. Tai, “Photoelectrochemical Properties of Ruthenium Dye-Sensitized Nanocrystalline SnO2:TiO2 Solar Cells,” Solar Energy Materials and Solar Cells, Vol. 76, No. 1, 2003, pp. 65-73.
http://dx.doi.org/10.1016/S0927-0248(02)00250-7

[25]   S. Rani, P. Suri, P. K. Shishodia and R. M. Mehra, “Synthesis of Nanocrystalline ZnO Powder via Sol-Gel Route for Dye-Sensitized Solar Cells,” Solar Energy Materials and Solar Cells, Vol. 92, No. 12, 2008, pp. 1639-1645.
http://dx.doi.org/10.1016/j.solmat.2008.07.015

[26]   F. Vera, R. Schrebler, E. Munoz, C. Suarez, P. Cury, H. Gomez, R. Cordova, R. E. Marotti and E. A. Dalchiele, “Preparation and Characterization of Eosin Band Erythrosine J-Sensitized Nanostructured NiO Thin Film Photocathodes,” Thin Solid Films, Vol. 490, No. 2, 2005, pp. 182-188. http://dx.doi.org/10.1016/j.tsf.2005.04.052

[27]   Y, Saito, S. Kambe, T. Kitamura, Y. Wada and S. Yanagida, “Morphology Control of Mesoporous TiO2 Nanocrystalline Films for Performance of Dye-Sensitized Solar Cells,” Solar Energy Materials and Solar Cells, Vol. 83, No. 1, 2004, pp. 1-13.
http://dx.doi.org/10.1016/j.solmat.2004.02.010

 
 
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