AMPC  Vol.3 No.5 , September 2013
Thermodynamic Aspects of the Graphene/Graphane/Hydrogen Systems: Relevance to the Hydrogen On-Board Storage Problem
ABSTRACT
The present analytical review is devoted to the current problem of thermodynamic stability and related thermodynamic characteristics of the following graphene layers systems: 1) double-side hydrogenated graphene of composition CH (theoretical graphane) (Sofo et al. 2007) and experimental graphane (Elias et al. 2009); 2) theoretical single-side hydrogenated graphene of composition CH; 3) theoretical single-side hydrogenated graphene of composition C2H (graphone); 4) experimental hydrogenated epitaxial graphene, bilayer graphene and a few layers of graphene on SiO2 or other substrates; 5) experimental and theoretical single-external side hydrogenated single-walled carbon nanotubes, and experimental hydrofullerene C60H36; 6) experimental single-internal side hydrogenated (up to C2H or CH composition) graphene nanoblisters with intercalated high pressure H2 gas inside them, formed on a surface of highly oriented pyrolytic graphite or epitaxial graphene under the atomic hydrogen treatment; and 7) experimental hydrogenated graphite nanofibers-multigraphene with intercalated solid H2 nano-regions of high density inside them, relevant to solving the problem of hydrogen on-board storage (Nechaev 2011-2012).

Cite this paper
Y. Nechaev and T. Veziroglu, "Thermodynamic Aspects of the Graphene/Graphane/Hydrogen Systems: Relevance to the Hydrogen On-Board Storage Problem," Advances in Materials Physics and Chemistry, Vol. 3 No. 5, 2013, pp. 255-280. doi: 10.4236/ampc.2013.35037.
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