OPJ  Vol.3 No.4 A , August 2013
Synthesis and Optical Investigations on (Ba,Sr)TiO3 Borosilicate Glasses Doped with La2O3
ABSTRACT

In this research paper we are reporting synthesis, structural and optical investigations of barium strontium titanate borosilicate glasses with addition of La2O3. Glasses were synthesized by conventional rapid melt quench method. Infrared absorption spectra, for various (Ba,Sr)TiO3 borosilicate glass samples having glass system 64[(Ba1-xSrx)TiO3]-35[2SiO2-B2O3]-5[K2O]-1[La2O3] (x = 0.3, 0.5, 0.6, 0.8 and 1.0), were recorded over a continous spectral range from 450 - 4000 cm-1. IR spectra were analyzed to determine and differentiate the various vibrational modes in the structural changes. Raman spectroscopy of all glass samples were also carried out wavenumber range form 200 - 1500 cm-1. These two complementary spectroscopic techniques revealed that the network structure of the studied glasses is mainly based on BO3, pentaborate groups linked to BO4 tetrahedra and units placed in different structural groups, the BO3 units  are dominanting. The recorded IR and Raman spectra of different glasses are used to clarify the optical properties of the prepared glass samples correlating with their structure and compositions. UV-Vis spectroscopy was carried out in range of 200 - 800 nm. The optical band gap was found between 2.023 - 3.320 eV.


Cite this paper
C. Gautam and A. Yadav, "Synthesis and Optical Investigations on (Ba,Sr)TiO3 Borosilicate Glasses Doped with La2O3," Optics and Photonics Journal, Vol. 3 No. 4, 2013, pp. 1-7. doi: 10.4236/opj.2013.34A001.
References
[1]   M. Yamane and Y. Asahara, “Glasses for Photonics,” Cambridge University Press, Cambridge, 2000. doi:10.1017/CBO9780511541308

[2]   A. Abou Shama and F. H. El-Batal, “Structural Analysis of Glassy Lead Borate Containing MoO3 in Relation to Its Optical Properties,” Egyptian Journal of Solids, Vol. 29, No. 1, 2006, pp. 49-67.

[3]   S. Hsu, “Separation Sciences Research and Product Development,” Mallinckrodt Baker Division, Mallinckrodt, Inc.

[4]   L. A. Lyon, C. D. Keating, A. P. Fox, B. E. Baker, H. Lin, S. R. Nicewarner, S. P. Mulvaney and M. J. Natan, “Raman Spectroscopy,” Analytical Chemistry, Vol. 70, No. 12, 1998, pp. 341R-361R. doi:10.1021/a1980021p

[5]   B. Schrader, “Inferared and Raman Spectroscopy,” John Wiley and Sons, London, 1995. doi:10.1002/9783527615438

[6]   J. R. Ferraro and J. S. Jiomek, “Introductory Group Theory and Its Applications to Molecular Structure,” Plenum Press, New York, 1969. doi:10.1007/978-1-4615-4821-8

[7]   D. L. Rouseau, R. P. Bauman and S. P. S. Porto, “Normal Mode Determination in Crystals,” Journal of Raman Spectroscopy, Vol. 10, No. 1, 1981, pp. 253-290. doi:10.1002/jrs.1250100152

[8]   A. M. Efimov, “Quantitative IR Spectroscopy: Applications to Studying Glass Structure and Properties,” Journal of Non-Crystalline Solids, Vol. 203, 1996, pp. 1-11. doi:10.1016/0022-3093(96)00327-4

[9]   R. E. Youngman and J. W. Zwanziger, “On the Formation of Tetracoordinate Boron in Rubidium Borate Glasses,” Journal of the American Chemical Society, Vol. 117, No. 4, 1995, pp. 1397-1402. doi:10.1021/ja00109a026

[10]   R. E. Youngman and J. W. Zwanziger, “Network Modification in Potassium Borate Glasses: Structural Studies with NMR and Raman Spectroscopies,” Journal of Physical Chemistry, Vol. 100, No. 41, 1996, pp. 16720-16728. doi:10.1021/jp961439+

[11]   C. R. Gautam, D. Kumar and O. Parkash, “IR Study of Pb-Sr Titanate Borosilicate Glasses,” Bulletin of Materials Science, Vol. 33, No. 2, 2010, pp. 145-148. doi:10.1007/s12034-010-0020-1

[12]   C. R. Gautam, D. Kumar, P. Singh and O. Parkash, “Study of Impedance Spectroscopy of Ferroelectric (Pb,Sr)TiO3 Glass Ceramic System with Addition of La2O3,” ISRN Spectroscopy, Vol. 2012, 2012, pp. 1-11. doi:10.5402/2012/410583

[13]   C. R. Gautam, Prabhakar Singh, D. Kumar and O. Parkash, “Synthesis, I R, Crystallization and Dielectric Study of (Pb,Sr)TiO3 Borosilicate Glass Ceramics,” Bulletin of Material Science, 2013 (in Press). doi:10.1007/s12034-013-0489-5

[14]   C. R. Gautam, A. K. Yadav, V. K. Mishra and K. Vikram, “Synthesis, IR and Raman Spectroscopic Studies of (Ba, Sr)TiO3 Borosilicate Glasses With Addition of La2O3,” Open Journal of Inorganic Non-metallic Materials, Vol. 2, 2012, pp. 47-54.

[15]   C. R. Gautam, A. K. Yadav and P. Singh, “Synthesis, Crystallization and Microstructural Study of Perovskite (Ba,Sr)TiO3 Borosilicate Glass Ceramic Doped With La2O3,” Materials Research Innovations, Vol. 17, No. 3, 2013, pp. 148-153. doi:10.1179/1433075X12Y.0000000045

[16]   E. A. Davis and N. F. Mott, “Conduction in Non-Crystalline Systems V,” Philosophical Magazine, Vol. 22, No. 179, 1970, pp. 903-922. doi:10.1080/14786437008221061

[17]   B. Eraiah, “Optical Properties of Samarium Doped Zinc-Tellurite Glasses,” Bulletin of Material Science, Vol. 29, No. 4, 2006, pp. 375-378. doi:10.1007/BF02704138

[18]   A. Venktaraman, V. A. Hiremath, S. K. Date and S. D. Kulkarni, “A New Combustion Route to γ-Fe2O3 Synthesis,” Bulletin of Material Science, Vol. 24, No. 6, 2001, pp. 617-621. doi:10.1007/BF02704010

[19]   P. G. Bray, “Interaction of Radiation with Solids,” Plenum, New York, 1967.

[20]   R. V. Adams and R. W. Douglas, “Infrared Studies on Various Samples of Fused Silica with Special Reference to the Bands Due to Water,” Journal of the Society of Glass Technology, Vol. 43, 1959, pp. 147-158.

[21]   H. Dunken and R. H. Doremus, “Short Time Reactions of a Na2O-CaO-SiO2 Glass With Water and Salt Solutions,” Journal of Non-Crystalline Solids, Vol. 92, No. 1, 1987, pp. 61-72. doi:10.1016/S0022-3093(87)80359-9

[22]   R. D. Husung and R. H. Doremus, “Infrared Transmission Spectra of Four Silicate Glasses before and after Exposure to Water,” Journal of Materials Research, Vol. 5, No. 10, 1990, pp. 2209-2217. doi:10.1557/JMR.1990.2209

[23]   G. Ramadevudu, S. R. L. Srinivasa, M. S. A. Hameed and M. C. Narasimha, “FTIR and Some Physical Properties of Alkaline Earth Borate Glasses Containing Heavy Metal Oxides,” International Journal of Engineering Science and Technology, Vol. 3, No. 9, 2011, pp. 6998-7005.

[24]   N. A. Ghoneim, H. A. El Batal, N. Abdel Shafi and M. H. Azooz, “Synthesis and Characterization of Cadmium Doped Lead-Borate Glasses,” Proceeding of the Egyptian Conference of Chemistry, Cairo, 1996, p. 162.

[25]   F. M. Ezz Eldin, N. A. E. L. Alaily, F. A. Khalifa and H. A. E. L. Batal, “In Fundamental of Glass Science and Technology,” 3rd E.S.G. Conference Germany: Verlag Der Deutschen Lastechnischen Gesellschaft, 1995.

[26]   A. S. Tenny and J. J. Wong, “Vibrational Spectra of Vapor Deposited Binary Borosilicate Glasses,” Chemical Physics, Vol. 56, No. 11, 1972, pp. 5516-5523.

[27]   H. Doweidar, M. A. A. Zeid and G. M. El-Damrawy, “Effect of Gamma Radiation and Thermal Treatment on Some Physical Properties of ZnO-PbO-B2O3 Glasses,” Journal of Physics D, Vol. 24, No. 12, 1991, pp. 2222-2228. doi:10.1088/0022-3727/24/12/015

[28]   M. Pal and B. Roy, “Structural Characterization of Borate Glasses Containing Zinc and Manganese Oxides,” Journal of Modern Physics, Vol. 2, No. 9, 2011, pp. 1062-1066. doi:10.4236/jmp.2011.29129

[29]   K. El-Egili, “Infrared Studies of Na2O-B2O3-SiO2 and Al2O3-Na2O-B2O3-SiO2 Glasses,” Physica B, Vol. 325, 2003, pp. 340-348. doi:10.1016/S0921-4526(02)01547-8

[30]   C. N. Santos, D. D. Meneses, P. Echegut, D. R. Neuville, A. C. Hernandes and A. Ibanez, “Structural, Dielectric, and Optical Properties of Yttrium Calcium Borate Glasses,” Applied Physics Letters, Vol. 94, 2009, pp. 151901-151903. doi:10.1063/1.3115796

[31]   H. Li, Y. Su, L. Li and D. M. Strachan, “Raman Spectroscopic Study of Gadolinium (III) in Sodium-Aluminoborosilicate Glasses,” Journal of Non-Crystalline Solids, Vol. 292, No. 1-3, 2001, pp. 167-176.

[32]   R. K. Brow, D. R. Tallant and G. L. Turner, “Polyhedral Arrangements in Lanthanum Aluminoborate Glasses,” Journal of the American Ceramic Society, Vol. 80, No. 5, 1997, pp. 1239-1244. doi:10.1111/j.1151-2916.1997.tb02970.x

[33]   W. Kern and R. C. Heim, “Chemical Vapor Deposition of Silicate Glasses for Use with Silicon Devices: II. Film Properties,” Journal of The Electrochemical Society, Vol. 117, No. 4, 1970, pp. 568-573. doi:10.1149/1.2407573

[34]   B. N. Meera and J. Ramakrishna, “Raman Spectral Studies of Borate Glasses,” Journal of Non-Crystalline Solids, Vol. 159, No. 1, 1993, pp. 1-21. doi:10.1016/0022-3093(93)91277-A

[35]   K. Suzuki and K. Kijima, “Optical Band Gap of Barium Titanate Nanoparticles Prepared by RF-Plasma Chemical Vapor Deposition,” Japanese Journal of Applied Physics, Vol. 44, 2005, pp. 2081-2082. doi:10.1143/JJAP.44.2081

[36]   H. B. George, C. Vira, C. Stehle, et al., “A Structural Analysis of the Physical Properties of Bismuth and Lead Based Glasses,” Physics and Chemistry of Glasses, Vol. 40, No. 6, 1999, pp. 326-332.

[37]   G. Sharma, K. S. Thind, M. Arora, H. Singh, Manupriya and L. Gerward, “Optical Properties of Heavy Metal Oxide Glasses before and after g-Irradiation,” Physica Status Solidi A, Vol. 204, 2007, pp. 591-601. doi:10.1002/pssa.200622124

[38]   D. Singh, K. Singh, G. Singh, M. Priya, S. Mohan, M. Arora and G. Sharma, “Optical and Structural Properties of ZnO-PbO-B2O3 and ZnO-PbO-B2O3-SiO2 Glasses,” Journal of Physics: Condensed Matter, Vol. 20, No. 7, 2008, pp. 75228-75233.

 
 
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