JEP  Vol.4 No.8 , August 2013
Determination of Different Trace Heavy Metals in Ground Water of South West Bank/Palestine by ICP/MS

Heavy metal contamination of the groundwater of south West Bank in Palestine was assessed. The groundwater samples were analyzed for different trace heavy metals (Tl, Pb, Bi, Cr, Mn, Co, Ni, Cu, Zn, Mo, Ag, and Cd), and Al content by ICP/MS. This study was conducted to determine the water quality of ground water which is used for drinking in the study area. Water samples from ten groundwater wells were obtained in four different dates of the year (October 2012, November 2012, March 2013, and April 2013). Three water samples were obtained from each well for each sampling date. A total of 120 water samples were collected from the ten wells. The samples were analyzed for their pH, electrical conductivity, total dissolved solids, and different trace metals content. The pH, electrical conductivity, and total dissolved solids of all water samples were found to be within the US Environmental protection Agency limits. Results showed that Pb, Al, Cr, Co, Ni, Cu, Zn, and Mo were detected in all water samples analyzed in this study, while Tl, Bi, Mn, Ag, and Cd were detected in 80%, 88%, 90%, 75%, and 95% of the water samples analyzed in this study, respectively. In general, 93% of all samples analyzed contained one or more of the 13 metals studied each in varying concentration. Furthermore, results showed that the concentration of Cr, Mn, Ni, Cu, Zn, and Mo is within the allowed WHO limits in drinking water. However the concentration of Pb Cd, and Al are found to be higher than the allowed WHO limits in 40%, 8%, and 33% of the water samples analyzed in this study, respectively. Statistical analyses showed that concentrations of the metals studied in this study vary significantly between the ten ground water wells, indicating that the wells analyzed in this study is different from each other in terms of heavy metal content. Additionally, from the statistical results obtained, it was found that there is a significant difference in the concentration of the metals in each well for the four sampling times (October 2012, November 2012, March 2013, and April 2013), denoting that metal concentration in the wells vary significantly with sampling time. The results obtained from this study suggest a possible risk to the population of the study area given the toxicity of these metals, and the fact that for many people in the study area, ground water is a main source of their water supply.

Cite this paper: H. Malassa, M. Al-Qutob, M. Al-Khatib and F. Al-Rimawi, "Determination of Different Trace Heavy Metals in Ground Water of South West Bank/Palestine by ICP/MS," Journal of Environmental Protection, Vol. 4 No. 8, 2013, pp. 818-827. doi: 10.4236/jep.2013.48096.

[1]   M. A. Momodu and C. A. Anyakora, “Heavy Metal Contamination of Ground Water: The Surulere Case Study,” Research Journal Environmental and Earth Sciences, Vol. 2, No. 1, 2010, pp. 39-43.

[2]   J. K. Vodela, J. A. Renden, S. D. Lenz, W. H. Mchel Henney and B. W. Kemppainen, “Drinking Water Contaminants,” Poultry Science, Vol. 76, No. 11, 1997, pp. 1474-1492.

[3]   J. E. Marcovecchio, S. E. Botte and R. H. Freije, “Heavy Metals, Major Metals, Trace Elements”. In: L. M. Nollet, Ed., Handbook of Water Analysis, 2nd Edition, CRC Press, London, 2007, pp. 275-311.

[4]   A. T. Batayneh, “Heavy Metals in Water Springs of the Yarmouk Basin, North Jordan and Their Potentiality in Health Risk Assessment,” International Journal of the Physical Sciences, Vol. 5, No. 7, 2010, pp. 997-1003.

[5]   N. Abderahman and Y. Abu-Rukah, “An Assessment Study of Heavy Metal Distribution within Soil in Upper Course of Zarqa River Basin/Jordan,” Environmental Geology, Vol. 49, No. 8, 2006, pp. 1116-1124. doi:10.1007/s00254-005-0154-4

[6]   I. Adekunle, M. Adetunji, A. Gbadebo and O. Banjoko, “Assessment of Groundwater Quality in a Typical Rural Settlement in Southwest Nigeria,” International Journal of Environmental Research and Public Health, Vol. 4, No. 4, 2007, pp. 307-318. doi:10.3390/ijerph200704040007

[7]   C. Chen, C. Kao, C. Chen and C. Dong, “Distribution and Accumulation of Heavy Metals in the Sediments of Kaohsiung Harbor, Taiwan,” Chemosphere, Vol. 66, No. 8, 2007, pp. 1431-1440. doi:10.1016/j.chemosphere.2006.09.030

[8]   D. J. Ferner, “Toxicity and Heavy Metals,” eMedicine Journal, Vol. 2, No. 5, 2001, p. 1.

[9]   D. Dupler, “Heavy Metal Poisoning,” In: J. L. Longe, Ed., Gale Encyclopedia of Alternative Medicine, Gale Group, Farmington Hills, 2001, pp. 2054-2057.

[10]   T. A. Laniyan, O. O. Kehinde Phillips and L. Elesha “Hazards of Heavy Metal Contamination on the Groundwater around a Municipal Dumpsite in Lagos, Southwestern Nigeria,” International Journal of Engineering & Technology, Vol. 11, No. 1, 2011, pp. 61-69.

[11]   O. T. Oyeku and A. O. Eludoyin, “Heavy Metal Contamination of Groundwater Resources in a Nigerian Urban Settlement,” African Journal of Environmental Science and Technology, Vol. 4, No. 4, 2010, pp. 201-214.

[12]   O. Momot and B. Synzynys, “Toxic Aluminium and Heavy Metals in Groundwater of Middle Russia: Health Risk Assessment,” International Journal of Environmental Research and Public Health, Vol. 2, No. 2, 2005, pp. 214-218. doi:10.3390/ijerph2005020003

[13]   M. A. Iqbal and S. G. Gupta, “Studies on Heavy Metal Ion Pollution of Ground Water Sources as an Effect of Municipal Solid Waste Dumping,” African Journal of Basic & Applied Sciences, Vol. 1 No. 5-6, 2009, pp. 117-122.

[14]   B. Rajappa, “Monitoring of Heavy Metal Concentration in Groundwater of Hakinaka Taluk, India,” Contemporary Engineering Sciences, Vol. 3, No. 4, 2010, pp. 183-190.

[15]   A. Alomary, “Determination of Trace Metals in Drinking Water in Irbid City-Northern Jordan,” Environmental Monitoring and Assessment, Vol. 185, No. 2, 2013, pp. 1969-1975. doi:10.1007/s10661-012-2680-3

[16]   R. Gutierrez, H. Rubio-Arias, R. Quintana, J. Ortega and M. Gutierrez, “Heavy Metals in Water of the San Pedro River in Chihuahua, Mexico and Its Potential Health Risk,” International Journal of Environmental Research and Public Health, Vol. 5, No. 2, 2008, pp. 91-98. doi:10.3390/ijerph5020091

[17]   D. Kar, P. Sur, S. Mandal, et al., “Assessment of Heavy Metal Pollution in Surface Water,” International Journal of Environmental Science and Technology Vol. 5, No. 4, 2008, pp. 119-124.

[18]   C. Voica, M. H. Kovacs, A. Dehelean, D. Ristoiu and A. Iordache, “ICP-MS Determinations of Heavy Metals in Surface Waters from Transylvania,” Romanian Journal of Physics., Vol. 57, No. 6-7, 2012, pp. 1184-1193.

[19]   I. Ismail and I. Mat Saleh, “Analysis of Heavy Metals in Water and Fish (Tilapia sp.) Samples from Ttasik Mutiara, Puchong,” The Malaysian Journal of Analytical Sciences, Vol. 16, No. 3, 2012, pp. 346-352.

[20]   UNEP, “Desk Study on the Environment in the Occupied Palestinian Territories,” United Nations Environment Programme, Nairobi, 2003.

[21]   M. Ghanem and N. Samhan, “Groundwater Pollution Assessment in Tulkarem Area, Palestine,” Journal of Earth Sciences and Geotechnical Engineering, Vol. 2, No. 4, 2012, pp. 1-16.

[22]   M. Ghanem, S. Samhan, E. Carlier and A. Wasim, “Groundwater Pollution Due to Pesticides and Heavy Metals in North West Bank,” Journal of Environmental Protection, Vol. 2, No. 4, 2011, pp. 429-434. doi:10.4236/jep.2011.24049

[23]   Y. El-Nahhal, “Contamination of Groundwater with Heavy Metals in Gaza Strip,” 10th International Water Technology Conference, Alexandria, 2006, pp. 1139-1150.

[24]   “Environmental Profile for the West Bank, Vol. 3: Hebron District,” Applied Research Institute, Jerusalem, 1995.

[25]   A. Abed and S. Wishahi, “Geology of Palestine: The West Bank and Gaza Strip. Palestin,” Palestine Hydrology Group, Ramallah, 1999.

[26]   F. M. Anayah and M. N. Almasri, “Trends and Occurrences of Nitrate in the Groundwater of the West Bank, Palestine,” Applied Geography, Vol. 29, No. 4, 2009, pp. 588-601. doi:10.1016/j.apgeog.2009.01.004

[27]   PHG, “Water For Life,” Water, Sanitation and Hygiene Monitoring Program (WaSH MP), 2007/2008.

[28]   APHA (American Public Health Association), “Standard Methods for the Examination of Water and Wastewater,” 20th Edition, Washington DC, 1998, p. 1294.

[29]   WHO, “Total Dissolved Solids In drinking water,” Background Document for Development of WHO Guidelines for Drinking Water Quality (WHO/SDE/WSH/03.04/16),” 2003.

[30]   IPCS, “Thallim International Program on Chemical Safety, Environmental Health Criteria: 182,” WHO, Geneva, 1996.

[31]   A. A. Adepoju-Bello, O. O. Ojomolade, G. A. Ayoola and H. A. B. Coker, “Quantitative Analysis of Some Toxic Metals in Domestic Water Obtained from Lagos Metropolis,” Nigerian Journal of Pharmacy, Vol. 42, No. 1, 2009, pp. 57-60.

[32]   M. T. Bakare-Odunola, “Determination of Some Metallic Impurities Present in Soft Drinks Marketed In Nigeria,” The Nigerian Journal of Pharmaceutical Research, Vol. 4, No. 1, 2005, pp. 51-54.

[33]   O. Adeyemi, O. B. Oloyede and A. T. Oladiji, “Physicochemical and Microbial Characteristics of Leachate Contaminated Ground Water,” Asian Journal of Biochemistry, Vol. 2, No. 5, 2007, pp. 343-348. doi:10.3923/ajb.2007.343.348

[34]   I. O. Igwilo, O. J. Afonne, U. J. Maduabuchi and O. E. Orisakwe, “Toxicological Study of the Anam River in Otuocha, Anambra State, Nigeria,” Archives of Environmental & Occupational Health, Vol. 61, No. 5, 2006, pp. 205-208. doi:10.3200/AEOH.61.5.205-208

[35]   M. B. Chang, C. H. Jen, H. T. Wu and H. Y. Lin, “Investigation on the Emission Factors and Removal Efficiencies of Heavy Metals from MSW Incinerators in Taiwan,” Waste Management & Research, Vol. 21, No. 3, 2003, pp. 218-224. doi:10.1177/0734242X0302100305

[36]   Directive 2000/76/EC of the European Parliament and the Council, 4 December 2000, on the Incineration of Waste.

[37]   M. J. Quina, R. C. Santos, J. C. M. Bordado and R. M. Quinta Ferreira, “Characterization of Air Pollution Control Residues Produced in a Municipal Solid Waste Incinerator in Portugal,” Journal of Hazardous Materials, Vol. 152, No. 2, 2008, pp. 853-869. doi:10.1016/j.jhazmat.2007.07.055

[38]   BREF, “Integrated Pollution Prevention and Control-Reference Document on the Best Available Techniques for Waste Incineration,” European Commission, 2006.