Alexandra Revina^*, Sergey Busev, Anatoly Kalinitchev, Michail Kuznetsov, Ardalion Ponomarev, Marina Lebedeva

Show more
Institute of Physical Chemistry and Electrochemistry, RAS, Moscow, Russia.
Show less

Abstract: The purpose of the investigation is the study of the physico-chemical properties and electro-catalytic characteristics of the Nafion and MF-4SK membranes with the author’s nanoparticles (A. Revina, 2008) incorporated into the perfluoro- sulphonated cationic membranes. An important advance in the creation of new nano-composite materials with poly-functional activity is the inclusion of nanoparticles of various metals (Pd, Pt, Ag) in these membranes. Polymer ion exchange membranes represent widely applicable materials in various areas of modern nanotechnologies. The obtained nanocomposites on the base of included nanoparticles have the perspective properties and polyfunctional activity for the applications.  

Keywords: UV-VIS Spectrophotometry; AFM; CVA-Measurements; Palladium Nanoparticles; Platinum Nanoparticles; Silver Nanoparticles; Perfluoro-Sulfonated Membranes; Nafion; MF-4SK Membrane

Cite this paper: Revina, A. , Busev, S. , Kalinitchev, A. , Kuznetsov, M. , Ponomarev, A. and Lebedeva, M. (2013) Nanoparticles of Palladium, Platinum and Silver:Incoporation into Perfluoro-Sulfonated Membrane MF-4SK and Ionic Nafion. Advances in Nanoparticles, 2, 280-286. doi: 10.4236/anp.2013.23038.

References

[1]   K. A. Mauritz and R. E. Moore, “State of Understanding of Nafion,” Chemical Reviews, Vol. 104, No. 10, 2004, pp. 4535-4586. doi:10.1021/cr0207123

[2]   A. K. Sahu, S. Pitchumani, P. Sridhar and A. K. Shukla, “Nafion and Modified-Nafion Membranes for Polymer Electrolyte Fuel Cells: An Overview,” Bulletin of Materials Science, Vol. 32, No. 3, 2009, pp. 285-294. doi:10.1007/s12034-009-0042-8

[3]   Y. L. Cao, X. L. Ding, H. C. Li, Z. G. Yi, X. F. Wang, J. J. Zhu and C. X. Kan, “Morphology-Controllable Noble Metal Nanoparticles: Synthesis, Optical Property and Growth Mechanism,” Acta Physico-chimica Sinica, Vol. 27, No. 6, 2011, pp. 1273-1286.

[4]   Yu. A. Dobrovolskii, A. V. Pisareva, L. S. Leonova and A. I. Karelin, “New Proton-Conducting Membrane for Fuel Cell and Gas Sensors,” Alternative Energy and Ecology, Vol. 12, No. 20, 2004, pp. 36-38.

[5]   T. K. Jain, M. Varshney and A. Maitra, “Structural Studies of Aerosol OT Reverse Micellar Agregates by FT-IR Spectroscopy,” Journal of Physical Chemistry, Vol. 93, No. 21, 1989, pp. 7409-7416. doi:10.1021/j100358a032

[6]   A. G. Dokuchaev, T. G. Myasoedova and A. A. Revina, “The Studying of Different Factors Effect on the Silver Aggregation Under γ-Radiation in the Reverse Micelle,” Chim. Vysokich Energii, Vol. 31, No. 5, 1997, pp. 353-357.

[7]   A. A. Revina, “Specimen of the nanostructural Metal Particles and the Method for Its Preparation,” RF Patent No 2322327, 2008.

[8]   T. K. Jain, M. Varshney and A. Maitra, “Determination of Size Parameters of Water-Aerosol OT-Oil Reverse Micelles from their Nuclear Magnetic Resonance Data,” Journal of Physical Chemistry, Vol. 88, No. 21, 1984, pp. 5122-5125. doi:10.1021/j150665a064

[9]   D. A. Tanasjuk, V. V. Zeitlin, A. A. Revina and V. I. Er makov, “Electroconductivity and Electrolysis in Reverse Micelles,” 2012.

[10]   N. A. Yashtulov, A. N. Bolshakova, A. A. Revina and V. R. Flid, “Metall-Polymer Nanocomposites Based on Platinum Nanoparticles for Chemical Fuel Cells,” Russian Chemical Bulletin, Vol. 60, No. 8, 2011, pp. 1-5. doi:10.1007/s11172-011-0235-3