The quality of surface water is rapidly changing due to climatic variations, natural processes, and anthropogenic activities. The objectives of this study were to classify and analyze the surface water quality of 12 major rivers of Alberta on the basis of 17 parameters during the period of five years (i.e., 2004-2008) using principal component analysis (PCA), total exceedance model and clustering technique. Seven major principal components (PCs) with variability of about 89% were identified. These PCs were the indicators of watershed geology, mineralization and anthropogenic activities related to land use/cover. The seven dominant parameters revealed from the seven PCs were total dissolved solids (TDS), true color (TC), pH, iron (Fe), fecal coliform (FC), dissolved oxygen (DO), and turbidity (TUR). The normalized data of dominant parameters were used to develop a model for obtaining total exceedance. The exceedance values acquired from the total exceedance model were used to determine the patterns for the development of five clusters. The performance of the clusters was compared with the classes obtained in Canadian Water Quality Index (CWQI). Cluster 1, cluster 2, cluster 3, cluster 4 and cluster 5 showed agreements of 85.71%, 83.54%, 90.22%, 80.74%, and 83.40% with their respective CWQI classes on the basis of the data for all rivers during 2004-2008.The water quality was deteriorated in growing season due to snow melting. This methodology could be applied to classify the raw surface water quality, analyze the spatio-temporal trends and study the impacts of the factors affecting the water quality anywhere in the world.
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T. Akbar, Q. Hassan and G. Achari, "Clusterization of Surface Water Quality and Its Relation to Climate and Land Use/Cover," Journal of Environmental Protection, Vol. 4 No. 4, 2013, pp. 333-343. doi: 10.4236/jep.2013.44040.
 S. Mahapatra and S. Mitra, “Managing Land and Water under Changing Climatic Conditions in India: A Critical Perspective,” Journal of Environmental Protection, Vol. 3, No. 9, 2012, pp. 1054-1062.
 A. García-Reiriz, J. Magallanes, M. Vracko, J. Zupan, S. Reich and D. Cicerone, “Multivariate Chemometric Analysis of a Polluted River of a Megalopolis,” Journal of Environmental Protection, Vol. 2, No. 7, 2011, pp. 903-914. doi:10.4236/jep.2011.27103
 B. Toth, D. R. Corkal, D. Sauchyn, G. V. D. Kamp and E. Pietroniro, “The Natural Characteristics of the South Saskatchewan River Basin: Climate, Geography and Hydrology,” Prairie Forum, Vol. 34, No. 1, 2009, pp. 95-127.
 Z. Zhu, K. Broersma and A. Mazumder, “Impacts of Land Use, Fertilizer and Manure Application on the Stream Nutrient Loadings in the Salmon River Watershed, South-Central British Columbia, Canada,” Journal of Environmental Protection, Vol. 3 No. 8, 2012, pp. 809-822.
 Canadian Council of Ministers of the Environment (CCME), “Canadian Water Quality Index 1.0 Technical Report and User’s Manual,” Canadian Environmental Quality Guidelines Water Quality Index Technical Subcommittee, Gatineau, 2001.
 I. Eneji, A. Onuche and R. Sha’Ato, “Spatial and Temporal Variation in Water Quality of River Benue, Nigeria,” Journal of Environmental Protection, Vol. 3, No. 8, 2012, pp. 915-921. doi:10.4236/jep.2012.328106
 Y. Singh and M. Kumar, “Interpretation of Water Quality Parameters for Villages of Sanganer Tehsil, by Using Multivariate Statistical Analysis,” Journal of Water Resource and Protection, Vol. 2, No. 10, 2010, pp. 860-863.
 H. Razmkhah, A. Abrishamchi and A. Torkian, “Evaluation of Spatial and Temporal Variation in Water Quality by Pattern Recognition Techniques: A Case Study on Jajrood River (Tehran, Iran),” Journal of Environmental Management, Vol. 91, No. 4, 2010, pp. 852-860.
 S. de Rosemond, D. C. Duro and M. Dubé, “Comparative Analysis of Regional Water Quality in Canada Using the Water Quality Index,” Environmental Monitoring and Assessment, Vol. 156, No. 1-4, 2009, pp. 223-240.
 F. Akbal, L. Gürel, T. Bahadür, I. Gürel, G. Bakan and H. Büyükgüngor, “Multivariate Statistical Techniques for the Assessment of Surface Water Quality at the Mid-Black Sea Coast of Turkey,” Water, Air, & Soil Pollution, Vol. 216, No. 1-4, 2011, pp. 21-37.
 V. Furtula, H. Osachoff, G. Derksen, H. Juahir, A. Colodey and P. Chambers, “Inorganic Nitrogen, Sterols and Bacterial Source Tracking as Tools to Characterize Water Quality and Possible Contamination Sources in Surface Water,” Water Research, Vol. 46, No. 4, 2012, pp. 1079-1092. doi:10.1016/j.watres.2011.12.002
 L. Kaufman and P. J. Rousseeuw, “Finding Groups in Data—An Introduction to Cluster Analysis,” John Wiley & Sons Inc., New York, 1990.
 N. A. Gabellone, L. Solari, M. Claps and N. Neschuk, “Chemical Classification of the Water in a Lowland River Basin (Salado River, Buenos Aires, Argentina) Affected by Hydraulic Modifications,” Environmental Geology, Vol. 53, No. 6, 2008, pp. 1353-1363.
 P. K. Srivastava, S. Mukherjee, M. Gupta and S. K. Singh, “Characterizing Monsoonal Variation on Water Quality Index of River Mahi in India Using Geographical Information System,” Water Quality, Exposure, and Health, Vol. 2, No. 3-4, 2011, pp. 193-203.
 C. Ren, C. Li, K. Jia, S. Zhang, W. Li and Y. Cao, “Water Quality Assessment for Ulansuhai Lake Using Fuzzy Clustering and Pattern Recognition,” Chinese Journal of Oceanology and Limnology, Vol. 26, No. 3, 2008, pp. 339-344. doi:10.1007/s00343-008-0339-2
 T. A. Akbar and R. A. Akbar, “Pesticide Health Risk Mapping and Sensitivity Analysis of Parameters in Groundwater Vulnerability Assessment,” Clean—Soil, Air, Water, 2013. doi:10.1002/clen.201200232
 T. A. Akbar and H. Lin, “GIS based ArcPRZM-3 Model for Bentazon Leaching towards Groundwater,” Journal of Environmental Sciences, Vol. 22, No. 12, 2010, pp. 1854-1859. doi:10.1016/S1001-0742(09)60331-4
 D. J. Downing and W. W. Pettapiece, “Natural Regions and Subregions of Alberta, Natural Regions Committee,” Government of Alberta, Alberta, 2006.
 Health Canada, “Guidelines for Canadian Drinking Water Quality,” Federal-Provincial-Territorial Committee on Drinking Water of the Federal-Provincial-Territorial Committee on Health and the Environment, 2010.
 Ontario Drinking Water Standards, “Technical Support Document for Ontario Drinking Water Standards, Objectives and Guidelines,” Ministry of the Environment, Drinking Water Ontario, Government of Ontario, Toronto, 2006.
 Alberta Environment and Sustainable Resource Development, “Alberta River Water Quality Index: Objectives, Water Data,” Environment and Water, Government of Alberta, Ottawa, 2011.
 National Aeronautics and Space Administration (NASA), “MODIS/Terra Land Cover Type Yearly L3 Global 1km SIN Grid V004, Land Cover Product, MOD12Q1, LP DAAC User Services,” US Geological Survey, Center for Earth Resources Observation and Science (EROS), Sioux Falls, 2004.
 N. S. Sekhon, Q. K. Hassan and R. W. Sleep, “Evaluating Potential of MODIS-Based Indices in Determining “Snow Gone,” Stage Over Forest-Dominant Regions,” Remote Sensing, Vol. 2, No. 5, 2010, pp. 1348-1363.
 T. A. Akbar, Q. K. Hassan and G. Achari, “A Methodology for Clustering Lakes in Alberta on the Basis of Water Quality Parameters,” Clean—Soil, Air, Water, Vol. 39, No. 10, 2011, pp. 916-924. doi:10.1002/clen.201100050
 U. C. Panda, S. K. Sundaray, P. Rath, B. B. Nayak and D. Bhatta, “Application of Factor and Cluster Analysis for Characterization of River and Estuarine Water Systems— A Case Study: Mahanadi River (India),” Journal of Hydrology, Vol. 331, No. 3-4, 2006, pp. 434-445.
 A.-M. Anderson, “River Water Quality of Battle River,” Water Sciences Branch, Water Management Division, Natural Resources Service, Alberta Environment, Edmonton, 1999.
 B. B. Wolfe, T. L. Karst-Riddoch, R. I. Hall, T. W. D. Edwards, M. C. English, R. Palmini, S. McGowan, P. R. Leavitt and S. R. Vardy, “Classification of Hydrological Regimes of Northern Floodplain Basins (Peace-Athabasca Delta, Canada) from Analysis of Stable Isotopes (18O, 2H) and Water Chemistry,” Hydrological Processes, Vol. 21, No. 2, 2007, pp. 151-168. doi:10.1002/hyp.6229
 J. Bruneau, D. R. Corkal, E. Pietroniro, B. Toth and G. V. D. Kamp, “Human Activities and Water Use in the South Saskatchewan River Basin,” Prairie Forum, Vol. 34, No. 1, 2009, pp. 129-152.
 A. Sosiak and J. Dixon, “Impacts on Water Quality in the Upper Elbow River,” Water Science and Technology, Vol. 53, No. 10, 2006, pp. 309-316. doi:10.2166/wst.2006.326
 F. J. Wrona, J. Carey, B. Brownlee and E. McCauley, “Contaminant Sources, Distribution and Fate in the Athabasca, Peace and Slave River Basins, Canada,” Journal of Aquatic Ecosystem Stress and Recovery, Vol. 8, No. 1, 2000, pp. 39-51. doi:10.1023/A:1011487605757
 P. Mitchell, “Water quality of the North Saskatchewan River in Alberta,” Surface Water Assessment Branch, Technical Services and Monitoring Division, Alberta Environmental Protection, Edmonton, 1994.