OJPChem  Vol.3 No.1 , February 2013
Synthesis and Characterization of Polyvinyl Chloride Chemically Modified by Amines

The reactions of poly vinyl chloride (PVC) with different aliphatic amines in Tetra Hydro Furan, THF, have been studied. These reactions led to the formation of new polymers (PVC-L) which were characterized by spectroscopic methods (Infra Red, IR and Uv-Visible spectrophotometry). Composite of the new polymers were prepared and their optical activities in the region (200 - 400 nm) were studied. The optical data analyzed and interpreted using the theory of phonon assisted direct electronic transition.

Cite this paper
A. Ameer, M. Abdallh, A. Ahmed and E. Yousif, "Synthesis and Characterization of Polyvinyl Chloride Chemically Modified by Amines," Open Journal of Polymer Chemistry, Vol. 3 No. 1, 2013, pp. 11-15. doi: 10.4236/ojpchem.2013.31003.
[1]   S. Zhu, Y. Zhang, Y. Zhang and C. Zhang, “Effect of CaCO3/LiCO3 on the HCl Generation of PVC during Combustion,” Polymer Testing, Vol. 2, No. 5, 2003, pp. 539-543. doi:10.1016/S0142-9418(02)00150-2

[2]   F. Gong, M. Feng, C. Zhao, S. Zhang and M. Yang, “Thermal Properties of Poly(vinyl Chloride)/Montmorillonite Nanocomposites,” Polymer Degradation and Stability, Vol. 84, No. 2, 2004, pp. 289-294. doi:10.1016/j.polymdegradstab.2003.11.003

[3]   M. Pan, X. Shi, X. Li, H. Hu and L. Zhang, “Morphology and Properties of PVC/Clay Nanocomposites via in Situ Emulsion Polymerization,” Journal of Applied Polymer Science, Vol. 94, No. 1, 2004, pp. 277-286. doi:10.1002/app.20896

[4]   A. B. Shehata, M. A. Hassan and N. A. Darwish, “Kaolin Modified with Resin-Iron Chelate as Flame Retardant System for polypropylene,” Journal of Applied Polymer Science, Vol. 92, No. 5, 2004, pp. 3119-3125. doi:10.1002/app.20226

[5]   Y. Chen, Y. Song, Y. Zhang, and J.-P. Lang, “A Tricobalt(II) Coordination Polymer Incorporating in Situgenerated 5-Methyltetrazolate Ligands,” Inorganic Chemistry Communications, Vol. 11, No. 5, 2008, pp. 572-575. doi:10.1016/j.inoche.2008.02.015

[6]   B. Gustafsson, B. Hakansson and S. Jagner, “Complexes between Copper(I) Chloride and Polydentate Aromatic Amines,” Inorganica Chimica Acta, Vol. 350, No. 4, 2003, pp. 209-214. doi:10.1016/S0020-1693(02)01548-7

[7]   Z. Genhua and C. Pan, “Preparation of Star Polymers Based on Polystyrene or Poly(styrene-b-N-isopropyl acrylamide) and Divinylbenzene via Reversible AdditionFragmentation Chain Transfer Polymerization,” Polymer, Vol. 46, No. 8, 2005, pp. 2802-2810. doi:10.1016/j.polymer.2005.01.071

[8]   E. Yousif, A. Hameed and E. Bakir, “Synthesis and Photochemical Study of Poly(vinyl chloride)-1,3,4-oxadiazole and 1,3,4-Thiadiazole,” Journal of Al-Nahrain University(Science), Vol. 10, No. 1, 2007, pp. 7-12.

[9]   S. Aliwi, E. Yousif and A. Otaiwi, “Synthesis and Photochemical Study of Some Metal Complexes of Poly(vinyl chloride)-2-mercapto-5-phenyl 1,3,4-oxadiazole,” Iraqi Journal of Polymers, Vol. 10, No. 1, 2005, pp. 53-64.

[10]   V. Reddy, Q. Zhu, L. Mai1 and W. Chen, “Optical, Electrical and Discharge Profiles for (PVC+NaIO4) Polymer Electrolytes,” Journal of Applied Electrochemistry, Vol. 36, No. 9, 2006, pp. 1051-1056. doi:10.1007/s10800-006-9158-3

[11]   Y. Al-Ramadin, “Optical Properties of Poly(vinyl Chloride)/Poly(ethylene Oxide) Blend,” Optical Materials, Vol. 14, No. 4, 2000, pp. 287-290. doi:10.1016/S0925-3467(00)00007-0

[12]   J. Tauc, “Amorphous and Liquid Semiconductor,” Plenum Press, London, New York, 1974. doi:10.1007/978-1-4615-8705-7

[13]   M. Youssif, A. Bahgat and A. Ali, “Ac Magnetic Susceptibility Technique for the Characterization of High Temperature Superconductors,” Egyptian Journal of Solids, Vol. 23, No. 2, 2000, pp. 231-250.

[14]   N. Mott and E. Davis, “Electronic Process in Non-Crystalline Materials,” 2nd Clarendon Press, Oxford, 1979, pp. 458-465.

[15]   B. John, “Polyvinyl Chloride,” Wikipeddia, Free Encyclopedia, Chapman & Hall Ltd., New York, 2009.

[16]   E. Yousif, O. Hassan, A. Otaiwi and Y. Farina, “Studying the Conductivity of Poly(vinyl Chloride) Using 2-Thioacetic Acid Benzothiazole Complexes as Additives by Measuring Forbidden Energy Gap,” Iraqi Journal of Polymers, Vol. 12, 2008, pp. 5-78.

[17]   E. Yousif, M. Abdul Nabi and S. Aliwi, “Optical Properties Modification of Polystyrene Films by 2N-salicylidene-5-(p-nitro phenyl)-1,3,4-thiadiazole Complexes,” Journal of Al-Nahrain University, Vol. 8, 2005, pp. 2226.

[18]   M. Abdul Nabi, E. Yousif, A. Alwash and Y. Farina, “Optical Properties Modification of Poy(vinyl Chloride) Using Complexes of 2-Amino-5(2-acetyloxyphenyl)-1,3, 4-thiadiazole,” Iraqi Journal of Polymers, Vol. 13, 2009, pp. 27-63.

[19]   Y. Al-Daeif, E. Yousif and M. A. Nabi, “Synthesis of New Polymers Derived from Poly(vinyl Chloride) and Study Their Optical Properties,” Journal of Al-Nahrain University, Vol. 15, No. 2, 2012, pp. 79-83.