AMPC  Vol.2 No.4 , December 2012
Aqueous Two Phase Extraction for the Recovery of 1,3-Propanediol from Its Aqueous Solutions
ABSTRACT
As the biodiesel production is rapidly enhanced, the crude glycerol, which is by-product of biodiesel processes, is state of surplus. 1,3-PDO (1,3-propanediol), a valuable monomer of poly(trimethylene terephthalate) (PTT), can be produced from the fermentation process using crude glycerin as a carbon source. For the economic biological production of 1,3-PDO, the low cost and high efficient separation processes is essential. In this study, aqueous two-phase system composed of various hydrophilic alcohols and salt was used as a primary separation step for 1,3-PDO. It was found that the aqueous two-phase systems are easily formed with decreasing of the polarity of alcohols. The extraction efficiency is proportional to the polarity of alcohols. In case of methanol or ethanol/K2HPO4, the extraction efficiency was more than 90%.  It was concluded that the aqueous two-phase extraction using methanol or ethanol/K2HPO4 can be applied  for the primary separation of 1,3-PDO  as an alternative to a conventional primary separation processes.

Cite this paper
M. Chung, Y. Ki Hong, H. Wook Lee and S. Park, "Aqueous Two Phase Extraction for the Recovery of 1,3-Propanediol from Its Aqueous Solutions," Advances in Materials Physics and Chemistry, Vol. 2 No. 4, 2012, pp. 154-157. doi: 10.4236/ampc.2012.24B040.
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