AMPC  Vol.2 No.4 , December 2012
Jet Plasma-Chemical Reactor for the Conversion of Methane: the Use of Clustering
ABSTRACT

The research results of processes proceeding in supersonic jets of light hydrocarbons, activated by an electron beam are presented. It is shown, that condensation suppressed at activation by electrons in the initial stage of condensation. The developed condensation conditions mode leads to increasing of a part of heavy corpuscles in activated stream and not only owing to stimulation of condensation but because of formation of heavy hydrocarbonic molecules.


 


Cite this paper
A. Korobeishchikov, M. Khodakov and V. Kalyada, "Jet Plasma-Chemical Reactor for the Conversion of Methane: the Use of Clustering," Advances in Materials Physics and Chemistry, Vol. 2 No. 4, 2012, pp. 146-149. doi: 10.4236/ampc.2012.24B038.
References
[1]   Huang Jian, Suib S. L. Dimerization of Methane through Microwave Plasmas // J. Phys. Chem., 1993. Vol. 97. P. 9403-9407.

[2]   Eliasson B., Kogelschatz U., Killer E. Hydrogenation of Carbon Dioxide and Oxidation of Methane in an Electrical Discharge // Proc. 11th World Hydrogen Energy Conference, Stuttgart, Germany, 1996. P. 2449-2459.

[3]   Fincke J.R., Anderson R.P., Hyde T.A.. Plasma Pyrolysis of Methane to Hydrogen and Carbon Black // Ind. Eng. Chem. Res., 2002. Vol. 41. P. 1425-1435.

[4]   Kozlov K.V., Michel P., Wagner H.-E. Synthesis of organic compounds from CH4-CO2 - mixtures in barrier discharges with different dielectric materials // 14th Internat. Symp. on Plasma Chemistry, 1999. Vol. IV. P. 1849-1854.

[5]   Kazuhisa Murata, Yoji Ushijima. A method of hydrogen producing // Patent JP No. 2767390 on 06/18/1998.

[6]   Eliasson Baldur, Zhang Kui, Kogelschatz Ulrich. Synthesis of hydrocarbon fuel using electric discharge // Patent EP No. 1038855 on 27/09/2000..

[7]   Medvedev Yu.V., Remnev G.E., Smetanin V.I. The method of conversion of light hydrocarbons in the heavier // RF patent No. 2149884 on 01/06/1999.

[8]   Sirotkina E.E., Kudryashev S.V., Ryabov A.Yu. A method of producing isomeric structure hydrocarbons // RF patent No. 2123992 on 27/12/1998.

[9]   Czernichowski Piotr, Czernichowski Albin. Conversion of hydrocarbons using the moving electric arcs in the presence of water vapor and / or carbon dioxide // Patent FR No. 2758317 on 17/07/1998.

[10]   Sharafutdinov R.G., Karsten V.M., Polisan A.A. The method of homogeneous and heterogeneous reactions with the use of plasma // RF Patent No. 2200058 on 10/03/2003.

[11]   Sharafutdinov R.G., Karsten V.M., Khmel S.Ya. et al. Epitaxial silicon films deposited at high rates by gas-jet electron beam plasma CVD // Surface and Coatings Technology, 2003. Vol. 174 –175. P. 1178–1181.

[12]   R. G. Sharafutdinov, A. E. Zarvin, V. Zh. Madirbaev, V. V. Gagachev, and G. G. Gartvich. Hydrogen production from methane in electron-beam-generated plasma // Technical Physics Letters. 2005. Vol. 31. No. 8. P. 641-643.

[13]   V. A. Vinokurov, R. G. Sharafutdinov, Yu. I. Tychkov Plasma-chemical processing of natural gas // Chemistry and Technology of Fuels and Oils. 2005. Vol. 41. No. 2. P. 112-115.

[14]   A. E. Zarvin, V. Zh. Madirbaev, N. G. Korobeishchikov, G. G. Gartvich, and R. G. Sharafutdinov. Effect of small methane and monosilane additives on clustering in pulse supersonic argon jets // Tech. Phys. 2005. Vol. 50. P. 1444-1450.

[15]   V. Zh. Madirbaev, A. E. Zarvin. Ion-cluster excitation of atomic argon levels in molecular gas mixtures // Vestnik Novosibirsk State University. Series: Physics. 2007. Vol. 2. Issue 1. P. 36-43.

[16]   N. G. Korobeishchikov, A. E. Zarvin, V. Zh. Madirbaev and R. G. Sharafutdinov. Condensation of argon, monosilane and their mixture in a pulse free jet // Plasma Chem. Plasma Proc. 2005. Vol. 25. P. 319-349.

[17]   A. E. Zarvin, N. G. Korobeishchikov, V. V. Kalyada, V. Zh. Madirbaev. Formation of mixed clusters in a pulsed helium - oxygen - isoprene supersonic jet // Eur. Phys. J. D. 2008. Vol. 49. P. 101-110.

 
 
Top